Development of an alternative process to conventional toxic chromic acid anodization (CAA) with equivalent corrosion resistance is a challenging task. The present invention provides a chromate free process for the manufacture of corrosion resistant sealed anodized coating for long term corrosion resistance of aerospace grade aluminum alloy. This method includes the steps of cleaning, chemical etching, anodizing in Tartaric-Sulphuric acid electrolyte followed by dipping the specimen in the sealing bath containing at least two water soluble either Mn and Mo or Mn and V oxyanions as corrosion inhibitors and a sufficient amount of alkali metal ion based nitrates at a temperature range between 60 and 80° C. for about 20 to 40 minutes at a pH range of 7 to 9. The sealed anodic coatings developed from this invention showed improved corrosion resistance in neutral 5% NaCl fog environment for greater than 2000 h of exposure. The sealed anodic coatings developed by this invention also showed self-healing protection in NaCl environment.

A method for washing a car/vehicle/transportation device and a method for washing a braking device of a car/vehicle/transportation device are disclosed. The methods include spraying a detergent composition for washing automobiles, two-wheeled vehicles, bicycles, construction equipment, farm equipment, aircraft, railroad cars, ships, and/or various other types of car/vehicle/transportation devices, thereby washing the car/vehicle/transportation device or the braking device, wherein the detergent composition includes (Z)-1-chloro-3,3,3-trifluoropropene and HFE-type nonflammable fluorinated-type solvent, mass % ratio thereof ((Z)-1-chloro-3,3,3-trifluoropropene/HFE-type nonflammable fluorinated-type solvent) being within a range that is 30/70 to 99/1.

A method for washing a car/vehicle/transportation device and a method for washing a braking device of a car/vehicle/transportation device are disclosed. The methods include spraying a detergent composition for washing automobiles, two-wheeled vehicles, bicycles, construction equipment, farm equipment, aircraft, railroad cars, ships, and/or various other types of car/vehicle/transportation devices, thereby washing the car/vehicle/transportation device or the braking device, wherein the detergent composition includes (Z)-1-chloro-3,3,3-trifluoropropene and HFE-type nonflammable fluorinated-type solvent, mass % ratio thereof ((Z)-1-chloro-3,3,3-trifluoropropene/HFE-type nonflammable fluorinated-type solvent) being within a range that is 30/70 to 99/1.

Methods for cleaning surfaces are provided. Such a method may comprise contacting a surface with a fluid comprising a compound of Formula I for a period of time; and removing the fluid from the surface, thereby providing a cleaned surface. Vapor phase degreasing systems for cleaning a surface of a component are also provided. Such a system may comprise a boil sump comprising liquid comprising a compound of Formula I; and a holder configured to hold a component in a vapor formed from the liquid.

The present invention provides a solvent composition that can inhibit corrosion of a metal, a cleaning method using the solvent composition, and a method for producing an article provided with a coating film. The solvent composition of the present invention comprises 1-chloro-2,3,3-trifluoropropene and a specified second component, and is characterized in that the proportion of the total amount of the content of the second component to the sum of the content of 1-chloro-2,3,3-trifluoropropene and the total amount of the content of the second component is from 0.0001 to 1.0 mass %.

Disclosed are compositions comprising 90 to 99 weight percent trans-1,2-dichloroethylene, from 0.1 to 8 weight percent methylperfluoroheptene ethers and from 0.5 to 2.0 weight percent of a fluorocarbon selected from the group consisting of Z-1,1,1,4,4,4-hexafluoro-2-butene, 1,3,4,4,4-pentafluoro-3-trifluoromethy-1-butene, 1,1,1,4,4,5,5,5-octafluoro-2-pentene, perfluorobutyl methyl ether, perflurobutyl ethyl ether, perfluoroisopropylmethyl ether, perfluoroethyl isopropyl ketone, heptafluorocyclopentane, and E-1,1,1-trifluoro-3-chloro-2-propene, wherein the composition is non-flamable. The disclosure further provides a method for removing residue from a surface of an article comprising: (a) contacting the article with a composition comprising a composition of MPHE, trans-1,2-dichloroethylene and a fluorocarbon selected from the group consisting of Z-1,1,1,4,4,4-hexafluoro-2-butene, 1,3,4,4,4-pentafluoro-3-trifluoromethy-1-butene, 1,1,1,4,4,5,5,5-octafluoro-2-pentene, perfluorobutyl methyl ether, perflurobutyl ethyl ether, perfluoroisopropylmethyl ether, perfluoroethyl isopropyl ketone, heptafluorocyclopentane, and E-1,1,1-trifluoro-3-chloro-2-propene; and (b) recovering the surface from the composition.

Disclosed are compositions comprising 90 to 99 weight percent trans-1,2-dichloroethylene, from 0.1 to 8 weight percent methylperfluoroheptene ethers and from 0.5 to 2.0 weight percent of a fluorocarbon selected from the group consisting of Z-1,1,1,4,4,4-hexafluoro-2-butene, 1,3,4,4,4-pentafluoro-3-trifluoromethy-1-butene, 1,1,1,4,4,5,5,5-octafluoro-2-pentene, perfluorobutyl methyl ether, perflurobutyl ethyl ether, perfluoroisopropylmethyl ether, perfluoroethyl isopropyl ketone, heptafluorocyclopentane, and E-1,1,1-trifluoro-3-chloro-2-propene, wherein the composition is non-flamable. The disclosure further provides a method for removing residue from a surface of an article comprising: (a) contacting the article with a composition comprising a composition of MPHE, trans-1,2-dichloroethylene and a fluorocarbon selected from the group consisting of Z-1,1,1,4,4,4-hexafluoro-2-butene, 1,3,4,4,4-pentafluoro-3-trifluoromethy-1-butene, 1,1,1,4,4,5,5,5-octafluoro-2-pentene, perfluorobutyl methyl ether, perflurobutyl ethyl ether, perfluoroisopropylmethyl ether, perfluoroethyl isopropyl ketone, heptafluorocyclopentane, and E-1,1,1-trifluoro-3-chloro-2-propene; and (b) recovering the surface from the composition.

A nonflammable solvent composition, a method of cleaning an article, and a method of depositing a material on a substrate are disclosed. The nonflammable solvent composition includes a fluorocyclopentane in which 3 to 9 hydrogen atoms have each been replaced by a fluorine atom; trans-1,2-dichloroethylene (t-DCE); and at least one organic compound, such as a C.sub.2-C.sub.6 alcohol, a C.sub.1-C.sub.6 alkane, and a C.sub.3-C.sub.6 cycloalkane. Amounts of the fluorocyclopentane, t-DCE, and the organic compound in the nonflammable composition are selected so that the composition is an azeotrope or is azeotrope-like. The method of cleaning an article includes contacting the article with the nonflammable composition via vapor degreasing or wet cleaning. The method of depositing a material on a substrate includes dissolving the material in the nonflammable solvent composition, applying the composition containing the material to the substrate, and evaporating the composition from the substrate.

An azeotrope-like mixture consisting essentially of chlorotrifluoropropene and at least one component selected from the group consisting of pentane, hexane, methanol, and trans-1,2-dichloroethene.

The present disclosure provides a degreasing apparatus which may be made at least partially, or substantially, of at least one plastic material, for use with solvents having relatively low boiling points that are chemically compatible with plastic materials, such as 1233zd (1-chloro-3,3,3-trifluoro-propene, CF.sub.3CH═CHCl). Plastic degreasing apparatuses may comprise a tank comprising a side wall and a bottom wall, a partition coupled to a lower portion of the tank, dividing the tank into an immersion sump and a vaporizing sump, a heating element located within the vaporizing sump, and a condensing element positioned above the lower portion, wherein at least one of the side wall, the bottom wall, and the partition is made of a plastic material.