An emulsified liquid composition is disclosed comprising a hydrophobic phase, an emulsifying composition of a protonated amide and a protonated amine having defined carbon to nitrogen atom molar ratios and water. The compositions optionally comprise at least one of a defoamer, a coalescent agent, a preservative, a co-emulsifier, chain extender, crosslinker and a rheology modifier. The compositions are useful for application to induce hydrophobicity to inorganic, organic or fiber based materials without undesirable backwetting or re-wetting effects.

An emulsified liquid composition is disclosed comprising a hydrophobic phase, an emulsifying composition of a protonated amide and a protonated amine having defined carbon to nitrogen atom molar ratios and water. The compositions optionally comprise at least one of a defoamer, a coalescent agent, a preservative, a co-emulsifier, chain extender, crosslinker and a rheology modifier. The compositions are useful for application to induce hydrophobicity to inorganic, organic or fiber based materials without undesirable backwetting or re-wetting effects.

Provided is a composition for the treatment of fibers, such as PAN precursor fibers. The finish composition includes a polysiloxane; an emulsifier; water; and a dicarboxylic acid having a pK.sub.a from 1 to 4, and boiling point from 200 to 400° C. The dicarboxylic acid may have the following formula: ##STR00001##
where R.sub.1 is absent or a saturated or unsaturated, linear or branched, aromatic substituted or unsubstituted, hydrocarbon group; Y.sub.1 and Y.sub.2 are independently hydrogen, nitrogen, oxygen, sulfur, phosphorus, C.sub.1-C.sub.6 alkyl group, or an alkoxy group; and X.sub.1 and X.sub.2 are independently one or more hydrogen atoms, a metal, a quaternary amine, or a hydrocarbon group having up to 6 carbon atoms, the hydrocarbon group being an alkyl group, an alkylene group, or an aromatic group, which may be branched or linear, and may optionally have one or more heteroatoms selected from the group consisting of nitrogen, oxygen, sulfur and phosphorus.

Provided is a composition for the treatment of fibers, such as PAN precursor fibers. The finish composition includes a polysiloxane; an emulsifier; water; and a dicarboxylic acid having a pK.sub.a from 1 to 4, and boiling point from 200 to 400° C. The dicarboxylic acid may have the following formula: ##STR00001##
where R.sub.1 is absent or a saturated or unsaturated, linear or branched, aromatic substituted or unsubstituted, hydrocarbon group; Y.sub.1 and Y.sub.2 are independently hydrogen, nitrogen, oxygen, sulfur, phosphorus, C.sub.1-C.sub.6 alkyl group, or an alkoxy group; and X.sub.1 and X.sub.2 are independently one or more hydrogen atoms, a metal, a quaternary amine, or a hydrocarbon group having up to 6 carbon atoms, the hydrocarbon group being an alkyl group, an alkylene group, or an aromatic group, which may be branched or linear, and may optionally have one or more heteroatoms selected from the group consisting of nitrogen, oxygen, sulfur and phosphorus.

Carbon nanotube threads are coated with a coating solution such as dimethylformamide (DMF), ethylene glycol (EG), polyethylene glycol (PEG), PEG200 (PEG with a average molecular weight of approximately 200 grams per mole (g/mol)), PEG400 (PEG with a average molecular weight of approximately 400 g/mol), dimethyl sulfide (DMS 100 cP), HP1632, poly(methylhydrosiloxane), polyalkylene glycol, (3-aminopropyl)trimethoxysilane, hydride functional siloxane 0 resin, platinum (0) -1,3-divinyl-1,1,3,3-tetramethyl-disiloxane, moisture in air, acetic acid, water, poly(dimethylsiloxane) hydroxy terminated, (3-glycidyloxypropyl)-trimethoxysilane or a combination thereof. The coated carbon nanotubes may be used to stitch in a Z-direction into a composite such as a polymer prepreg to strengthen the composite. The stitching may occur using a sewing machine.

A composition to be used for providing permanent hydrophilic finishing of textile fibers and textile products made thereof consists of at least one anionic surfactant based on a neutralized phosphoric acid ester of a fatty alcohol having at least 12 C-atoms in a proportion of 25 to 80 weight percent, a non-ionic consistency enhancer in a proportion of 10 to 50 weight percent, a hydrophilically modified polyalkylsiloxane in a proportion of 3 to 35 weight percent and a hydrotropic dispersion additive in a proportion of 0 to 5 weight percent, each based on the total weight of the composition. The composition is preferably present as a granulate and has a melting point of at least 45° C.

To provide surface-modified fibers and reinforcing fibers that are capable of enhancing the adhesiveness to rubber, without the use of resorcinol and formaldehyde, and a molded article using the same. Surface-modified fibers include fibers, and a surface-modifying layer covering at least a part of a surface of the fibers, and have a solid surface zeta potential on a surface of the surface-modifying layer of −20.0 to 30.0 mV.

There is provided a method of treating textile fibres including: a) providing a polymeric precursor including a diallyl amide cationic compound and a corresponding counter ion; b) either (i) coating the textile fibres with the polymeric precursor and polymerising the polymeric precursor to form a polymeric coating, or (ii) polymerising the polymeric precursor and contacting the polymerised polymeric precursor with the textile fibres to form a polymeric coating on the textile fibres. There is also provided a composite structure including a polymeric coating formed from the polymeric precursors of the present invention.

There is provided a method of treating textile fibres including: a) providing a polymeric precursor including a diallyl amide cationic compound and a corresponding counter ion; b) either (i) coating the textile fibres with the polymeric precursor and polymerising the polymeric precursor to form a polymeric coating, or (ii) polymerising the polymeric precursor and contacting the polymerised polymeric precursor with the textile fibres to form a polymeric coating on the textile fibres. There is also provided a composite structure including a polymeric coating formed from the polymeric precursors of the present invention.

A cooling agent composition contains a 2,2,6-trimethylcyclohexanecarboxylic acid derivative represented by the following general formula (1). The symbol * represents an asymmetric carbon atom. X represents NH, N(ZAr.sup.2), O or S, Z represents a single bond or an alkylene group having 1 to 3 carbon atoms which may have a substituent, Ar.sup.2 represents an aryl group having 6 to 20 carbon atoms which may have a substituent or an aromatic heterocyclic group having 2 to 15 carbon atoms which may have a substituent. Y each independently represents a methylene group which may have a substituent, and n represents an integer of 0 to 3. Ar.sup.1 represents an aryl group having 6 to 20 carbon atoms which may have a substituent or an aromatic heterocyclic group having 2 to 15 carbon atoms which may have a substituent. ##STR00001##