The present invention relates to an amorphous alloy corresponding to the formula:
Co.sub.aNi.sub.bMo.sub.c(C.sub.1-xB.sub.x).sub.dX.sub.e
wherein X is one or several elements selected from the group consisting of Cu, Si, Fe, P, Y, Er, Cr, Ga, Ta, Nb, V and W; wherein the indices a to e and x satisfy the following conditions: 55≤a≤75 at. % 0≤b≤15 at. % 7≤c≤17 at. % 15≤d≤23 at. % 0.1≤x≤0.9 at. % 0≤e≤10 at. %, each element selected from the group having a content≤3 at. % and preferably ≤2 at. %, the balance being impurities.

A method for production of a horology assembly of two components, comprising (i) supplying a first component (2) being a spring, and comprising at least one element made of elastic material provided with a tongue (20); supplying a second component (3) provided with at least one cut-out or opening (31, 32); permanently assembling the two components. The two components cooperate by means of an obstacle such as to create the assembly, and in particular the tongue is accommodated in the at least one cut-out or opening (31, 32).

A component intended to be in friction contact with another component, the component being coated with an electrically conductive layer in one piece, at least partially covering every surface of the component, the friction occurring on at least one of these surfaces, called the functional surface, the functional surface being surrounded by a plurality of side surfaces, the component having on its functional surface a texture formed of a succession of troughs coated with the electrically conductive layer, the troughs each extending between two side surfaces such that the electrically conductive layer remains in one piece over the component despite the wear caused by friction on the functional surface. The invention also relates to the method for manufacturing the component by the DRIE (deep reactive ion etching) process, wherein surface defects on the sides machined by the DRIE process are used to form the troughs.

A spiral timepiece spring with a two-phase structure, made of a niobium and titanium alloy, and method for manufacturing this spring, including: producing a binary alloy containing niobium and titanium, with: niobium: the remainder to 100%; titanium: strictly greater than 60% and less than or equal to 85% by mass of the total, traces of components from among O, H, C, Fe, Ta, N, Ni, Si, Cu, Al; applying deformations alternated with heat treatments until a two-phase microstructure is obtained comprising a solid solution of niobium with β-phase titanium and a solid solution of niobium with α-phase titanium, the α-phase titanium content being greater than 10% by volume, wire drawing to obtain wire able to be calendered; calendering or insertion into a ring to form a mainspring, in a double clef shape before it is wound for the first time, or winding to form a balance spring.

A barrel (1) for self-winding timepiece including a drum (11) provided with an inner lateral wall (12) and a mainspring (2) forming a winding including an outer coil (21) the end (22) of which is friction coupled with the inner lateral wall and free to slip against the inner lateral wall in the event of overtension of the mainspring (2). The end of the outer coil includes an external face (23) having two friction surfaces (24, 25) disposed in the top and bottom portion of the outer coil and arranged to be in contact with the inner lateral wall in such a way that the portion between the friction surfaces, referred to as central portion (26), is not in contact with the inner lateral wall, the central portion forming a reservoir (27) for a lubricant between the two friction surfaces.

Method for press-rolling a mainspring, from a wire comprising a pre-formed eye, utilising a roller press comprising a first support and guide means exerting a force on the wire in a first contact area located between a second and a third contact area comprised in a second and a third support and guide means, in order to wind, beyond the eye, an accumulation area with an opposite curvature to that of the eye, and wherein, as the wire advances, the position of the first contact area is gradually moved away from the second and third contact areas, to vary the press-rolling radius from a first minimum value to a second maximum value at a neck junction between the accumulation area and the eye.

A micromechanical functional assembly including at least one first part with a first functional surface intended to enter into frictional contact with a second functional surface, the second functional surface belonging either to the first part or to at least one second part constituting with the first part the functional assembly, wherein the functional assembly includes the first functional surface and the second functional surface are formed by a first layer including ultrananocrystalline, nanocrystalline or microcrystalline diamond, the first layer being topped by a second layer including S and F atoms. It also relates to the method for functionalising diamond.

A method for producing a timepiece spring includes a step for producing, by casting, a metallic glass raw material constituted of a metallic glass; a step for heating the metallic glass raw material to achieve a superplastic state; and a step for rolling the metallic glass raw material in a superplastic state to produce a sheet material. A timepiece spring is characterized by being obtained by the method for producing a timepiece spring.

A timepiece mainspring is accommodated inside a barrel, an inner end thereof is fixed to a barrel arbor included in the barrel, and an outer end thereof engages with an inner wall of the barrel. The timepiece mainspring includes a helical portion wound in a Bernoulli curve shape from the inner end in a free state having no applied load.

This invention teaches a new class of materials that can be used to manufacture hairsprings and/or other components of mechanical watches, and methods for manufacturing these components. The new class of materials is crystalline compounds, including, but not limited to, gallium arsenide, extrinsically doped gallium arsenide, extrinsically doped silicon, gallium nitride, extrinsically doped gallium nitride, gallium phosphide, extrinsically doped gallium phosphide, and quartz. This invention also teaches laminated/coated crystalline compounds. The lamination/coating may be applied by one of the following methods, including but not limited to: plasma enhanced chemical vapor deposition, atomic layer deposition, sputtering, electron beam evaporation, and thermal evaporation. Using crystalline compounds, in particular extrinsically doping the crystalline compounds, affords the possibility to controllably alter the mechanical, electrical, thermal, magnetic, and/or other properties of the watch components. These properties can be further altered by applying single or multiple laminates/coatings of varying thicknesses and/or geometries.