A printed energy storage device includes a first electrode including zinc, a second electrode including manganese dioxide, and a separator between the first electrode and the second electrode, the first electrode, second, electrode, and separator printed onto a substrate. The device may include a first current collector and/or a second current collector printed onto the substrate. The energy storage device may include a printed intermediate layer between the separator and the first electrode. The first electrode, and the second electrode may include 1-ethyl-3-methylimidazolium tetrafluoroborate (C.sub.2mimBF.sub.4). The first electrode and the second electrode may include an electrolyte having zinc tetrafluoroborate (ZnBF.sub.4) and 1-ethyl-3-methylimidazolium tetrafluoroborate (C.sub.2mimBF.sub.4). The first electrode, the second electrode, the first current collector, and/or the second current collector can include carbon nanotubes. The separator may include solid microspheres.

The present disclosure discloses a primary lithium battery comprising a reactive solid cathode, a liquid electrolyte, a separator, and a lithium anode. The liquid electrolyte is ionic conductive and is configured to undergo a series coupling reaction after solid phase reaction of the reactive solid cathode and the lithium anode. The liquid electrolyte comprises a solvent and an electrolyte salt, and a concentration of the electrolyte salt in the liquid electrolyte is 0.1-3 mol/L. The solvent comprises a sulfite ester type compound and an organic solvent, and a concentration of the sulfite ester type compound in the organic solvent is 5 wt % to 90 wt %.

A lithium primary battery includes a positive electrode, a negative electrode, and a non-aqueous electrolyte. The positive electrode contains a positive electrode material mixture including Li.sub.xMnO.sub.2 where 0 ≤ x ≤ 0.05. The negative electrode contains at least one of metal lithium and a lithium alloy. The non-aqueous electrolyte contains an oxalate borate complex component and a cyclic imide component. In the non-aqueous electrolyte, the concentration of the oxalate borate complex component is 5.5 mass% or less, and the concentration of the cyclic imide component is 1 mass% or less. The mass ratio of the cyclic imide component to the oxalate borate complex component contained in the non-aqueous electrolyte is 0.02 or more and 10 or less.

The disclosure provides a primary battery and an electrode assembly thereof. The electrode assembly includes a separator, a positive electrode, and a negative electrode current collector. The separator has a positive electrode side and a negative electrode side opposite to each other. The positive electrode is located at the positive electrode side of the separator, and the positive electrode includes a positive electrode current collector and a positive electrode material. The negative electrode current collector is located at the negative electrode side of the separator. The electrode assembly does not include a negative electrode material before charging or activation.

A battery for an implantable medical device (IMD) configured to support a relatively high rate of energy discharge relative to its capacity to support energy intensive therapy delivery, such as high energy anti-tachyarrhythmia shocks, by the IMD. The battery includes a first electrode, a second electrode separated a distance from the first electrode, an electrolyte disposed between the first electrode and the second electrode. The electrolyte includes a lithium salt including LiAsF6, an organic solvent, and an electrolyte additive that includes vinylene carbonate.

A metallic salt including at least one anion having a heterocyclic aromatic structure represented by one of Formulae 1 to 3; and a metallic cation: ##STR00001##
wherein, in Formulae 1 to 3, each X is independently N, P, or As, one of A.sub.1 and A.sub.2 is an electron-donating group, and the other one is an electron-withdrawing group, ring Ar.sub.1 and ring Ar.sub.2 are as defined herein, L is a linker group as defined herein, m is an integer from 1 to 5, and n is an integer from 0 to 5.

A printed energy storage device includes a first electrode including zinc, a second electrode including manganese dioxide, and a separator between the first electrode and the second electrode, the first electrode, second, electrode, and separator printed onto a substrate. The device may include a first current collector and/or a second current collector printed onto the substrate. The energy storage device may include a printed intermediate layer between the separator and the first electrode. The first electrode, and the second electrode may include 1-ethyl-3-methylimidazolium tetrafluoroborate (C.sub.2mimBF.sub.4). The first electrode and the second electrode may include an electrolyte having zinc tetrafluoroborate (ZnBF.sub.4) and 1-ethyl-3-methylimidazolium tetrafluoroborate (C.sub.2mimBF.sub.4). The first electrode, the second electrode, the first current collector, and/or the second current collector can include carbon nanotubes. The separator may include solid microspheres.

A DME-free lithium battery includes a positive electrode, a negative electrode, a separator arranged between the positive electrode and the negative electrode, and a liquid electrolyte composed of a solvent and at least one lithium electrolyte salt and with which the electrode and the separator are impregnated, wherein the solvent includes propylene carbonate (PC) as a first solvent component and 1,3-dioxolane (DOL) as a second solvent component, and the positive electrode and/or the negative electrode have a proportion of carbon black having a BET surface area of at least 1 m.sup.2/g.

A nonaqueous electrolyte primary battery with improved storage properties at high temperatures and excellent reliability, and a method for producing the battery are provided. The nonaqueous electrolyte primary battery includes a negative electrode containing metallic lithium or a lithium alloy, a positive electrode, a separator, and a nonaqueous electrolyte solution. The nonaqueous electrolyte solution contains at least LiClO.sub.4 as an electrolyte and 0.1 to 5% by mass of LiB(C.sub.2O.sub.4).sub.2.

This invention relates to the field of energy storage devices, and especially electrochemical energy storage devices including electrolytes comprising an ionic liquid, one or more solvents, and one or more salts of a Group 2 element. Effects on electrochemical performance of the electrolyte of each of the components of the electrolyte were systematically determined. In addition, interactions between the electrolytes and separator films were dissected to optimize electrochemical performance of coin cell batteries.