A fuel supply control system and method for a fuel cell are disclosed. The system includes: a fuel cell configured to receive a fuel gas and an oxidation gas and generate electric power; a recirculation line configured to circulate gas containing the fuel gas and connected to a fuel electrode of the fuel cell; a discharge valve provided in the recirculation line and configured to allow the gas to be discharged to the outside when open; a discharge amount estimator configured to estimate a discharge amount of the discharged gas based on a supply amount of the fuel gas supplied to the recirculation line, a consumption amount of the fuel gas consumed in the fuel cell, and a change in the amount of the gas in the recirculation line; an offset calculator configured to calculate the discharge amount of the gas estimated by the discharge amount estimator with the discharge valve closed, as a discharge offset; and a controller configured to control opening/closing of the discharge valve.

The present disclosure relates to a fuel cell system including: an air supply line configured to supply air to a fuel cell stack; a discharge line connected to the fuel cell stack and configured to guide exhaust gas discharged from the fuel cell stack; a discharge adapter connected to the discharge line and configured to discharge the exhaust gas to the outside; and a bypass line having one end connected to the air supply line and the other end connected to the discharge adapter, the bypass line being configured to selectively allow the air to flow from the air supply line to the discharge adapter, thereby effectively reducing a hydrogen concentration in exhaust gas discharged from the fuel cell stack.

The present invention relates to a sensor device (10) for a fuel cell system (100) for determining a purging parameter (SP) for controlling a purging process of the fuel cell system (100), comprising a first flow channel (20) for arranging in an anode feed section (122) of an anode section (120) of a fuel cell stack (110) and a second flow channel (130) for arranging in a recirculation section (126) of the anode section (120) of the fuel cell stack (110), which are separated from each other, at least in sections, by means of a gas-tight membrane (40), wherein the membrane (40) is designed to be permeable for protons and has an electrode section (42, 44) on both sides, as well as comprising a measuring device (50) for determining a fuel concentration difference between the first flow channel (20) and the second flow channel (30) as a purging parameter (SP) based on an electrical voltage between the two electrode sections (42, 44).

A method for diagnosing at least one fuel cell stack of a fuel cell device by way of a fuel cell diagnostic system includes: impressing a sinusoidal first and at least one sinusoidal second AC current into the fuel cell stack; recording a sinusoidal first and second voltage response of the fuel cell stack; evaluating the first voltage response and evaluating the second voltage response by way of an analytical algorithm for a differential impedance analysis; determining a first resistance, a second resistance and a capacitance of the fuel cell stack by specifying an equivalent circuit diagram for the fuel cell stack; and diagnosing the fuel cell stack on the basis of the determined first resistance, the determined second resistance and the determined capacitance, wherein the diagnosis is carried out in real time. A computer-readable storage medium and a fuel cell diagnostic system are also described.

A method for treating hydrogen-containing and oxygen-containing residual gases of fuel cells, wherein the residual gases are fed to a gas circuit, and a residual gas mixture resulting therefrom is circulated in the gas circuit by a device for converting hydrogen and oxygen to water. In order to reduce the amount of hydrogen and oxygen in the residual gas mixture, at least part of the residual gas mixture is discharged from the gas circuit.

A system for capturing carbon dioxide in flue gas includes a fuel cell assembly including at least one fuel cell including a cathode portion configured to receive, as cathode inlet gas, the flue gas generated by the flue gas generating device or a derivative thereof, and to output cathode exhaust gas and an anode portion configure to receive an anode inlet gas and to output anode exhaust gas, a fuel cell assembly voltage monitor configured to measure a voltage across the fuel cell assembly, and a controller configured to receive the measured voltage across the fuel cell assembly from the fuel cell assembly voltage monitor, determine an estimated carbon dioxide utilization of the fuel cell assembly based on the measured voltage across the fuel cell assembly, and reduce the carbon dioxide utilization of the fuel cell assembly when the determined estimated carbon dioxide utilization is above a predetermined threshold utilization.

A disclosed fuel cell system includes a fuel inlet that receives a fuel gas from a fuel source, a gas analyzer that determines a composition of the fuel gas received by the fuel inlet, and a stack including fuel cells that generate electricity using the fuel gas received from the fuel source. The fuel cell system further includes a controller that controls at least one of a fuel utilization of the stack, a current generated by the stack, or a voltage generated by the stack, based on the composition of the primary fuel gas determined by the gas analyzer. The controller may control the fuel cell system by increasing or decreasing a fuel flow rate to thereby increase or decrease the voltage generated by the stack to maintain a predetermined target voltage or to maintain a predetermined rate at which usable fuel is supplied to the stack based on composition.

The invention relates to a method for operating a fuel cell system (1), in particular a PEM fuel cell system, in which at least one fuel cell (2) is supplied with a hydrogen-containing anode gas via an anode gas path (3) and anode gas exiting the fuel cell (2) is returned via a recirculation path (4), wherein, in order to reduce a nitrogen content in the anode gas, a flush valve (5) arranged in the recirculation path (4) is opened and the recirculation path (4) is flushed. According to the invention, the actual composition of the anode gas is determined using at least one sensor (6) and the ageing status of the at least one fuel cell (2) is determined by comparing the determined actual composition with a target composition and/or an actual composition determined earlier. The invention also relates to a control device (7) for carrying out the method according to the invention.

A method for controlling a carbon dioxide utilization in a fuel cell assembly includes: measuring a voltage across the fuel cell assembly; determining an estimated carbon dioxide utilization of the fuel cell assembly based on at least the measured voltage across the fuel cell assembly by determining an expected voltage of the fuel cell assembly based on at least a temperature of the fuel cell assembly, a current density across the fuel cell assembly, a fuel utilization of the fuel cell assembly, and a cathode oxygen utilization of the fuel cell assembly; determining the estimated carbon dioxide utilization based on a comparison between the measured voltage and the determined expected voltage; comparing the determined estimated carbon dioxide utilization to a predetermined threshold utilization; and upon determining that the determined estimated carbon dioxide utilization is higher than the predetermined threshold utilization, reducing the carbon utilization of the fuel cell assembly.

Fuel cell systems configured for efficient byproduct recovery and reuse are disclosed herein. In one embodiment, a fuel cell system includes a reformer configured to reform a fuel containing methane (CH.sub.4) with steam to produce a reformed fuel having methane (CH.sub.4), carbon monoxide (CO), and hydrogen (H.sub.2). The fuel cell system also includes a fuel cell configured to perform an electrochemical reaction between a first portion of the reformed fuel and oxygen (O.sub.2) to produce electricity and an exhaust having carbon dioxide (CO.sub.2), water (H.sub.2O), and a second portion of the reformed fuel. The fuel cell system further includes an oxygen enricher configured to generate an oxygen enriched gas and a combustion chamber configured to combust the second portion of the reformed fuel with the oxygen enriched gas.