A method for diagnosing at least one fuel cell stack of a fuel cell device by way of a fuel cell diagnostic system includes: impressing a sinusoidal first and at least one sinusoidal second AC current into the fuel cell stack; recording a sinusoidal first and second voltage response of the fuel cell stack; evaluating the first voltage response and evaluating the second voltage response by way of an analytical algorithm for a differential impedance analysis; determining a first resistance, a second resistance and a capacitance of the fuel cell stack by specifying an equivalent circuit diagram for the fuel cell stack; and diagnosing the fuel cell stack on the basis of the determined first resistance, the determined second resistance and the determined capacitance, wherein the diagnosis is carried out in real time. A computer-readable storage medium and a fuel cell diagnostic system are also described.

A method for treating hydrogen-containing and oxygen-containing residual gases of fuel cells, wherein the residual gases are fed to a gas circuit, and a residual gas mixture resulting therefrom is circulated in the gas circuit by a device for converting hydrogen and oxygen to water. In order to reduce the amount of hydrogen and oxygen in the residual gas mixture, at least part of the residual gas mixture is discharged from the gas circuit.

Disclosed is a method of controlling an air supply system for a fuel cell. The air supply system includes a fuel cell stack, an air channel to supply air to an inlet of the fuel cell stack, a gas adsorption unit disposed on the air channel and configured to adsorb oxygen contained in air introduced into the air channel. In particular, the method includes: determining whether a power generation operation of the fuel cell stack is resumed; when the power generation operation of the fuel cell stack is resumed, controlling a voltage source to apply a voltage to the gas adsorption unit; and supplying air to the fuel cell stack through the air channel in a state in which the voltage is applied to the gas adsorption unit.

A system for capturing carbon dioxide in flue gas includes a fuel cell assembly including at least one fuel cell including a cathode portion configured to receive, as cathode inlet gas, the flue gas generated by the flue gas generating device or a derivative thereof, and to output cathode exhaust gas and an anode portion configure to receive an anode inlet gas and to output anode exhaust gas, a fuel cell assembly voltage monitor configured to measure a voltage across the fuel cell assembly, and a controller configured to receive the measured voltage across the fuel cell assembly from the fuel cell assembly voltage monitor, determine an estimated carbon dioxide utilization of the fuel cell assembly based on the measured voltage across the fuel cell assembly, and reduce the carbon dioxide utilization of the fuel cell assembly when the determined estimated carbon dioxide utilization is above a predetermined threshold utilization.

A method for controlling a carbon dioxide utilization in a fuel cell assembly includes: measuring a voltage across the fuel cell assembly; determining an estimated carbon dioxide utilization of the fuel cell assembly based on at least the measured voltage across the fuel cell assembly by determining an expected voltage of the fuel cell assembly based on at least a temperature of the fuel cell assembly, a current density across the fuel cell assembly, a fuel utilization of the fuel cell assembly, and a cathode oxygen utilization of the fuel cell assembly; determining the estimated carbon dioxide utilization based on a comparison between the measured voltage and the determined expected voltage; comparing the determined estimated carbon dioxide utilization to a predetermined threshold utilization; and upon determining that the determined estimated carbon dioxide utilization is higher than the predetermined threshold utilization, reducing the carbon utilization of the fuel cell assembly.

A method for determining the starting state of a fuel-cell system is provided having cathode and anode chambers separated by a membrane-electrode assembly, comprising the steps of initially introducing hydrogen into the anode chamber, measuring the voltage and evaluating whether at least a threshold value has been reached immediately after the start of the introduction of hydrogen into the anode chamber, and determining the starting state as a function of whether the threshold value has been reached.

The present disclosure generally relates to systems and methods for using a relative humidity sensor in a cathode exhaust stream of a fuel cell stack to optimize the performance and efficiency of the fuel cell stack.

A reforming element for a molten carbonate fuel cell stack and corresponding methods are provided that can reduce or minimize temperature differences within the fuel cell stack when operating the fuel cell stack with enhanced CO.sub.2 utilization. The reforming element can include at least one surface with a reforming catalyst deposited on the surface. A difference between the minimum and maximum reforming catalyst density and/or activity on a first portion of the at least one surface can be 20% to 75%, with the highest catalyst densities and/or activities being in proximity to the side of the fuel cell stack corresponding to at least one of the anode inlet and the cathode inlet.

Disclosed is a method of controlling an air supply system for a fuel cell. The air supply system includes a fuel cell stack, an air channel to supply air to an inlet of the fuel cell stack, a gas adsorption unit disposed on the air channel and configured to adsorb oxygen contained in air introduced into the air channel. In particular, the method includes: determining whether a power generation operation of the fuel cell stack is resumed; when the power generation operation of the fuel cell stack is resumed, controlling a voltage source to apply a voltage to the gas adsorption unit; and supplying air to the fuel cell stack through the air channel in a state in which the voltage is applied to the gas adsorption unit.

A fuel cell system having a fuel cell using a fuel gas containing a combustible gas and an oxidant gas to generate power includes an exhaust gas route for an exhaust gas from the fuel cell to circulate, an air supplier absorbing air within the fuel cell system and supplying the air to the exhaust gas, an air supply route for the air to circulate, a merging part where the exhaust gas and the air merge, a discharge route discharging a mixed gas composed of the merged exhaust gas and the air to the atmosphere, and a combustible gas detector that detects the concentration of a combustible gas in the mixed gas. With respect to flow of the air circulating in the air supply route and the discharge route, from the upstream side, the air supplier, the merging part, and the combustible gas detector are disposed in this order.