Provided are an ion exchange membrane that has excellent mechanical strength as well as can exhibit an excellent proton conductivity over a long period, a membrane electrode assembly, a fuel cell, a redox flow secondary battery, a water electrolyzer, and an electrolyzer for organic hydride synthesis.

An ion exchange membrane containing:

an electrolyte containing a perfluorocarbon sulfonic acid polymer; and

glass fiber having a SiO.sub.2 content of 99.9% by mass or more.

Composites of porous nano-featured silicon and various materials, such as carbon, are provided. The composites find utility in various applications, such as electrical energy storage electrodes and devices comprising the same.

Composites of porous nano-featured silicon and various materials, such as carbon, are provided. The composites find utility in various applications, such as electrical energy storage electrodes and devices comprising the same.

The present invention provides an anion exchange resin capable of producing an electrolyte membrane for a fuel cell, a binder for forming an electrode catalyst layer and a battery electrode catalyst layer. The anion exchange resin of the present invention has a hydrophobic unit, a hydrophilic unit and divalent fluorine-containing groups. The hydrophobic unit has divalent hydrophobic groups composed of one aromatic ring or a plurality of aromatic rings that are repeated via carbon-carbon bond. The hydrophilic unit has divalent hydrophilic groups composed of one aromatic ring or a plurality of aromatic rings, at least one of which has an anion exchange group, that are repeated via carbon-carbon bond. The divalent fluorine-containing groups have a specific structure and are bonded via carbon-carbon bond to the hydrophobic unit and/or the hydrophilic unit and/or a moiety other than these units.

Disclosed herein is an electrolytic membrane with cationic ion or anionic ion conducting capability comprising crosslinked inorganic-organic hybrid electrolyte in a porous support, wherein the inorganic-organic hybrid crosslinked electrolyte is formed by chemical born formation between Linkers and Crosslinkers, wherein Linkers and/or Crosslinkers include at least one element from Si, P, N, Ti, Zr, Al, B, Ge, Mg, Sn, W, Zn, V, Nb, Pb or S.

Composites of porous nano-featured silicon and various materials, such as carbon, are provided. The composites find utility in various applications, such as electrical energy storage electrodes and devices comprising the same.

Composites of porous nano-featured silicon and various materials, such as carbon, are provided. The composites find utility in various applications, such as electrical energy storage electrodes and devices comprising the same.

A composite proton conductive membrane, comprising an inorganic filler having covalently bonded acidic functional groups and a high surface area of at least 150 m.sup.2/g; and a water insoluble ionically conductive polymer. This membrane provides advantages over traditional polymeric proton conductive membranes for redox flow battery, fuel cell, and electrolysis applications include: 1) enhanced proton conductivity/permeance due to the formation of additional nanochannels for proton conducting; 2) improved proton/electrolyte selectivity for redox flow battery application; 3) reduced membrane swelling and gas or electrolyte crossover; 4) improved chemical stability; 5) increased cell operation time with stable performance, and 6) reduced membrane cost.

Provided are an anion exchange resin being capable of producing an electrolyte membrane and the like, which have improved chemical properties (durability). For example, used is an anion exchange resin comprising a hydrophobic unit being composed of a plurality of divalent hydrophobic groups repeated via carbon-carbon bond, the divalent hydrophobic group having a plurality of aromatic rings which are connected to each other via a divalent fluorine-containing group; and a hydrophilic unit being composed of a plurality of hydrophilic groups repeated via carbon-carbon bond, the hydrophilic groups being composed of a plurality of aromatic rings which are connected to each other via a divalent hydrocarbon group and/or carbon-carbon bond, and the hydrophilic groups containing an anion exchange group-containing group including a quaternary ammonium salt having a piperidine ring, and wherein the hydrophobic unit and the hydrophilic unit are connected via carbon-carbon bond.

Embodiments provide a redox flow battery, an ion exchange membrane for use in the redox flow battery and a method for producing the ion exchanger membrane. The ion exchange membrane includes a base layer, a first hydrophobic layer, and a second hydrophobic layer. The base layer includes sulfonated poly(ether ether ketone). The base layer has a first surface and a second surface. The first hydrophobic layer includes a polydimethylsiloxane elastomer. The first hydrophobic layer is positioned on the first surface of the base layer. The second hydrophobic layer includes the polydimethylsiloxane elastomer. The second hydrophobic layer is positioned on the second surface of the base layer. The ion exchange membrane is configured to prevent cross contamination of the first electrolyte and the second electrolyte. The redox flow battery includes a first half-cell, a second half-cell, and the ion exchange membrane. The first half-cell includes a first electrolyte. The second half-cell includes a second electrolyte. The first half-cell and the second half-cell are configured to undergo a redox reaction to discharge and charge the redox flow battery.