The present disclosure provides a growth method of a high-temperature phase lanthanum borosilicate crystal, where the high-temperature phase lanthanum borosilicate crystal is a β-La.sub.1-yLn.sub.yBSiO.sub.5 crystal prepared by a high-temperature flux method; a composite flux system is (La.sub.1-yLn.sub.y)BO.sub.3—LiMoO.sub.4—SiO.sub.2—B.sub.2O.sub.3, and (La.sub.1-yLn.sub.y)BO.sub.3, LiMoO.sub.4, SiO.sub.2, and B.sub.2O.sub.3 in the system have molar percentages of x.sub.1, x.sub.2, x.sub.3, and x.sub.4, respectively; 0<x.sub.1<0.3, 0.7≤x.sub.2<1, 0<x.sub.3<0.3, x.sub.1+x.sub.2+x.sub.3=1, x.sub.1:x.sub.4=2:1 to 4:1. In the present disclosure, a difficulty is overcome in the crystal growth of β-LaBSiO.sub.5 due to phase transition. The crystal is an optical function material that does not undergo the phase transition during annealing and can exist stably at room temperature. The crystal is widely used in laser, terahertz, and other fields.

An organometallic compound, represented by Formula 1:

M.sub.1(Ln.sub.1).sub.n1(Ln.sub.2).sub.n2  Formula 1

wherein, in Formula 1, M.sub.1 is a transition metal, Ln.sub.1 is a ligand represented by Formula 1-1, Ln.sub.2 is a ligand represented by Formula 2-1 or 2-2, n1 is 1 or 2, and n2 is 1 or 2:

##STR00001## wherein, in Formulae 1-1, 2-1, and 2-2, CY.sub.1, X.sub.21 to X.sub.28, X.sub.31, X.sub.32, R.sub.10, R.sub.31 to R.sub.37, R.sub.41 to R.sub.44, and b10 are as defined herein, and * and *′ each indicates a binding site to M.sub.1.

A luminescence device includes a first electrode, a first emission portion disposed on the first electrode, a second electrode disposed on the first emission portion, and a capping layer disposed on the second electrode and including a metal atom and a metal halide compound, wherein the metal atom is a lanthanide metal, a transition metal, or a post-transition metal and the metal halide compound is formed by combining an alkali metal atom and a halogen atom.

A polyimide luminescent material, a preparation method, and a used thereof are disclosed; the polyimide luminescent material includes a polyimide resin and a rare earth complex distributed in the polyimide resin, wherein the polyimide resin is a condensation polymer of an aromatic diamine containing a bidentate chelate ligand and an aromatic dianhydride, and the rare earth complex and the bidentate chelate ligand are connected by a chemical bond. The luminescent material has enhanced fluorescence intensity, thermal stability, and mechanical properties. The preparation method is simple and easy, and is suitable for industrial production.

The invention relates to an optoelectronic and/or photoelectrochemical device including a conductive support layer, n-type semiconductor, a sensitizer or light-absorber layer, a hole transporting layer, a spacer layer and a back contact, wherein the n-type semiconductor is in contact with the sensitizer or light-absorber layer, the sensitizer or light-absorber layer includes a perovskite or metal halide perovskite material, the hole transporting layer is in direct contact with the sensitizer or light-absorber layer and includes an inorganic hole transporting material or inorganic p-type semiconductor, the spacer layer is between the hole transporting layer and the back contact and includes a material being different from the inorganic hole transporting material and the material of the back contact.

The present invention relates to an electronic component comprising a cerium IV complex, a doped semi-conductor matrix material comprising the cerium IV complex and at least one electron donor, the use of the cerium IV complex, especially as an organic semi-conductor, as a dopant in organic semiconductor matrix materials and as a charge injector in a charge injection layer, and new cerium IV complexes.

The present application relates to a technical filed of energy sources and illumination, and discloses a rare earth oxide nanosheet composite modified by an organic ligand, a preparation method and an organic light-emitting diode (OLED) luminescent film. The rare earth oxide nanosheet composite modified by the organic ligand is obtained by adding the organic ligand in the rare earth nanosheet sol for ultrasonic coordination; and a mole ratio of the rare earth nanosheet sol to the organic ligand is 1:(3-9).

An organic light-emitting device including a first electrode, a second electrode, and an organic layer disposed between the first electrode and the second electrode, wherein the organic layer includes an emission layer, the emission layer includes a host, a dopant, and a sensitizer, the host does not include a metal atom, the dopant emits light, and the light has a decay time of about 100 nanoseconds or less, and the sensitizer includes an organometallic compound represented by one selected from Formulae 1 and 2 described in the specification.

Disclosed is a rare earth complex having a rare earth ion and a phosphine oxide ligand that is coordinated with the rare earth ion and is represented by the following formula (I):

##STR00001## wherein R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5, and R.sup.6 each independently represent an alkyl group which may have a substituent.

An organic electroluminescent device includes a pair of electrodes; and an organic layer between the pair of electrodes, which includes a light-emitting layer, wherein the organic layer contains a compound represented by the following formula (I); and the light-emitting layer contains a iridium complex phosphorescent material:

##STR00001##

wherein R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5, R.sup.6, R.sup.7 and R.sup.8 each represents a hydrogen atom or a substituent, and contiguous substituents of R.sup.1 to R.sup.8 may be bonded to each other to form a condensed ring; R.sup.9 represents an alkyl group, an alkenyl group, an aryl group, a hetero-aryl group, or a silyl group, and each of which group may be substituted with a substituent; and at least one of R.sup.1 to R.sup.9 represents a deuterium atom or a substituent containing a deuterium atom.