Embodiments of the hybrid thermal-chromatograph systems described herein solve the co-product generation problem associated with seawater desalination, and result in significant reduction in the selling price of fresh water generated through the process, while also solving problems associated with traditional lithium mining practices.

Electrodeionization and electrodialysis systems which eliminate or substantially prevent the feed water from entering the concentrating compartments, for improving the recovery of product water as well as improving the current efficiency. Electro-osmotically generated flows of water entering from the diluting compartments of the stack constitutes the majority of concentrate feed, leading to the production of high purity, desalinated waters in the diluting compartments and highly concentrate solutions in the concentrate compartments.

In this disclosure, a process of recycling acid, base and the salt reagents required in the Li recovery process is introduced. A membrane electrolysis cell which incorporates an oxygen depolarized cathode is implemented to generate the required chemicals onsite. The system can utilize a portion of the salar brine or other lithium-containing brine or solid waste to generate hydrochloric or sulfuric acid, sodium hydroxide and carbonate salts. Simultaneous generation of acid and base allows for taking advantage of both chemicals during the conventional Li recovery from brines and mineral rocks. The desalinated water can also be used for the washing steps on the recovery process or returned into the evaporation ponds. The method also can be used for the direct conversion of lithium salts to the high value LiOH product. The method does not produce any solid effluent which makes it easy-to-adopt for use in existing industrial Li recovery plants.

A vapor source system based on vapor-liquid ejector supercharging combined with flash vaporization technology belongs to the technical fields of waste heat utilization and steam generation. The system comprises a vapor-liquid ejector, a flash vaporization tank and a intermediate heat exchanger, wherein the vapor-liquid ejector uses high-pressure steam to raise temperature and pressure of low-pressure water absorbed from the flash vaporization tank; the pressure-increased water is flashed into low-pressure saturated steam after entering the flash vaporization tank; the saturated water which is not flashed is collected at the bottom of the flash vaporization tank. The system generates multiple low-pressure flash vaporization saturated steam with a small portion of high-pressure steam, and realizes the recovery and utilization of waste heat such as flue gas of boiler, improves the economy of thermal process, and provides a flexible and adjustable vapor source for heavy oil thermal recovery, seawater desalination or sewage treatment equipment.

A novel solar-powered desalination and water purification system is disclosed herein. The system includes a nanofiber-impregnated graphene aerogel, an untreated water source, a water collection surface, and a purified water storage container. A novel photocatalytic nanofiber-impregnated graphene aerogel for desalination and photodegradation of contaminants for use in the disclosed system is also disclosed herein. The nanofiber-impregnated graphene aerogel exhibits excellent hydrophilicity, thermal insulation, and photodegradation capability, and allows for efficient solar-powered evaporation of water. The introduction of photocatalytic nanofibers into the graphene aerogel allows effective interfacial evaporation and in situ photodegradation of contaminants. The rate of water evaporation is preferably greater than 1.3 gal/ft.sup.2 per day, and the contaminant removal is preferably greater than 90%. A method of desalinating and purifying water using the disclosed system is also disclosed herein.

Multi-chamber Compressor (6, 206, 506) of Mechanical Vapor re-Compression (MVC) and water treatment methods, the compressor bearing independent compression chambers of positive displacement, for heat-pumps, of two main variants: a) reciprocating-rotary motion (6, 206) wherein the compression chambers (7V) are radially arranged cylindrical sectors based on concentric circular sectors of the same angle, with, pistons of radially arranged vanes (20, 220) of respective surface and with the plane of the vanes passing through the axis of the common rotor (14) and the shaft (16) and b) reciprocating-linear motion (506) wherein the compression chambers (52v) are in series arranged cylinders with pistons/vanes (50v) of corresponding circular surfaces and with the plane of the vanes perpendicular to the common shaft (51). In both cases, the shaft (16, 51) and the motor are common to all the vanes (20v, 50v), which follow identical strokes. The surfaces of the vanes (20v, 50v), as well as of the compression chambers (7V, 52v), differ from each other, since each compression chamber (7V, 52v) has its own and independent pair of evaporation (ev, dv, Lv, by) and heat-exchanger chambers/areas (Cv/eCv, 32v/33v, 132v, 54v/53v), said compression chamber exclusively sucks from, compresses and discharges to, and the fluids/vapors being dispensed, are under different thermodynamic state conditions. The stages are independent from each other, the medium-vapor providing the energy of evaporation is produced in the stage itself, and flow rate and compression ratio CR are independently controlled and adjusted in each stage.

A direct-contact, spray-assisted, evaporation and condensation, DCSEC system includes a heating block configured to receive and heat up seawater; plural evaporation and condensation stages, wherein n is a natural number, each stage being configured to generate water vapors through flash evaporation; an evaporation only stage connected to a last stage of the plural evaporation and condensation stages, the evaporation only stage configured to receive a brine from the last stage n of the plural evaporation and condensation stages; an input/output block configured to receive the brine from the evaporation only stage and to discharge it outside the system, and also to receive cooling water; and a pressure-swing regeneration block fluidly connected to the evaporation only stage to receive the water vapors and to generate a hot vapor, which is provided to the heating block for heating the seawater.

Formulation F comprising A) 50 to 90 parts by weight of at least one block copolymer P of ethyleneoxide and propylene oxide, B) 0.5 to 10 parts by weight of at least one salt of an alkyl sulfate S, C) 0.05 to 0.5 parts by weight of a composition C comprising C1) 5 to 10 parts by weight of at least one polydimethylsiloxane bearing only terminal alkyl groups, C2) 1 to 3 parts by weight of at least one polydimethylsiloxane bearing at least alkoxylated hydroxy group, C3) at least one solvent,
wherein said formulation F is an aqueous formulation.

Exemplary embodiments in desalination by direct contact membrane distillation present a cylindrical cross-flow module containing high-flux composite hydrophobic hollow fiber membranes. The present embodiments are directed to a model that has been developed to describe the observed water production rates of such devices in multiple brine feed introduction configurations. The model describes the observed water vapor production rates for different feed brine temperatures at various feed brine flow rates. The model flux predictions have been explored over a range of hollow fiber lengths to compare the present results with those obtained earlier from rectangular modules which had significantly shorter hollow fibers.

Described herein are water desalination membranes and methods of desalinating water. Sulfonated poly(arylene ether) polymers are also disclosed, including those comprising one or more sulfonate groups at various points along the polymer chain. The polymers may be used as at least a portion of a water desalination membrane. The polymers described herein are useful for preventing transport of aqueous ionic species (e.g., Na.sup.+ and Cl.sup.−) across a membrane made from the polymers while allowing water to pass. Chlorine-stable polymers are described, as well as polymers exhibiting good performance for rejecting monovalent cations in the presence of polyvalent cations.