POWER SEMICONDUCTOR MODULE AND MANUFACTURING METHOD FOR POWER SEMICONDUCTOR MODULE
20220020651 · 2022-01-20
Assignee
Inventors
Cpc classification
H01L23/36
ELECTRICITY
H01L23/3142
ELECTRICITY
H01L2224/293
ELECTRICITY
H01L2924/00014
ELECTRICITY
H01L23/10
ELECTRICITY
H01L2924/00014
ELECTRICITY
H01L2224/92247
ELECTRICITY
H01L23/043
ELECTRICITY
H01L2224/32225
ELECTRICITY
H01L23/053
ELECTRICITY
H01L2224/2929
ELECTRICITY
H01L24/73
ELECTRICITY
International classification
H01L23/10
ELECTRICITY
H01L23/053
ELECTRICITY
Abstract
A frame is made of a first material. An external terminal electrode is attached to the frame. A heat sink plate supports the frame and includes a mounting region in the frame. The heat sink plate is made of a non-composite material containing copper with purity of 95.0 weight percentage or more. A first adhesive layer bonds the frame and the heat sink plate to each other. The first adhesive layer is made of a second material different from the first material, and has a first composition. A power semiconductor element is mounted on the mounting region of the heat sink plate. A cover is attached to the frame to constitute a sealing space sealing the power semiconductor element without gross leak. A second adhesive layer bonds the frame and the cover to each other, and has a second composition different from the first composition of the first adhesive layer.
Claims
1. A power semiconductor module comprising: a package, the package including an external terminal electrode, a frame to which the external terminal electrode is attached, the frame being made of a first material, a heat sink plate supporting the frame and including a mounting region in the frame, the heat sink plate being made of a non-composite material containing copper with purity of 95.0 weight percentage or more, and a first adhesive layer bonding the frame and the heat sink plate to each other, the first adhesive layer being made of a second material different from the first material and having a first composition; a power semiconductor element mounted on the mounting region of the heat sink plate; a cover attached to the frame to constitute a sealing space sealing the power semiconductor element without gross leak; and a second adhesive layer bonding the frame and the cover to each other, and having a second composition different from the first composition of the first adhesive layer.
2. The power semiconductor module according to claim 1, wherein an elastic modulus of the second adhesive layer is lower than an elastic modulus of the first adhesive layer.
3. The power semiconductor module according to claim 1, wherein an elastic modulus of the first adhesive layer is 10 GPa to 20 GPa.
4. The power semiconductor module according to claim 1, wherein the first adhesive layer contains an inorganic filler at a first weight ratio, and the second adhesive layer contains an inorganic filler at a second weight ratio smaller than the first weight ratio, or does not contain the inorganic filler.
5. The power semiconductor module according to claim 1, wherein each of the frame, the first adhesive layer, and the second adhesive layer contains resin.
6. The power semiconductor module according to claim 1, wherein the sealing space has environmental resistance to 500 cycles of temperature changes between −65° C. and +150° C.
7. The power semiconductor module according to claim 1, wherein airtightness between the heat sink plate and the frame has heat resistance to thermal treatment at 260° C. for 2 hours.
8. The power semiconductor module according to claim 1, wherein airtightness between the cover and the frame has heat resistance to thermal treatment at 260° C. for 30 seconds.
9. The power semiconductor module according to claim 1, further comprising a third adhesive layer bonding the external terminal electrode and the frame to each other, the third adhesive layer having a third composition different from the second composition of the second adhesive layer.
10. The power semiconductor module according to claim 9, wherein the third composition of the third adhesive layer is same as the first composition of the first adhesive layer.
11. The power semiconductor module according to claim 1, wherein the external terminal electrode is directly attached to the frame.
12. A manufacturing method for a power semiconductor module, comprising: preparing a package, the package including an external terminal electrode, a frame to which the external terminal electrode is attached, the frame being made of a first material, a heat sink plate supporting the frame and including a to-be-mounted region in the frame, the heat sink plate being made of a non-composite material containing copper with purity of 95.0 weight percentage or more, and a first adhesive layer bonding the frame and the heat sink plate to each other, the first adhesive layer being made of a second material different from the first material and having a first composition; mounting the power semiconductor element on the to-be-mounted region of the heat sink plate after the preparing of the package; and attaching a cover to the frame to constitute a sealing space sealing the power semiconductor element without gross leak, the attaching of the cover includes forming a second adhesive layer, the second adhesive layer bonding the frame and the cover to each other and having a second composition different from the first composition of the first adhesive layer.
13. The manufacturing method for the power semiconductor module according to claim 12, wherein the forming of the second adhesive layer includes: applying a paste layer on the cover; forming a half-cured layer by half curing the paste layer; and changing the half-cured layer to the second adhesive layer by causing curing of the half-cured layer to further progress on the package.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
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[0028]
DESCRIPTION OF THE PREFERRED EMBODIMENTS
[0029] Embodiments of the present invention will be described below with reference to the drawings.
First Embodiment
[0030] (Configuration)
[0031]
[0032] The power semiconductor element 200 may be a semiconductor element for high frequency. The semiconductor element for high frequency is a semiconductor element that operates with frequencies of approximately from several tens of megahertz (for example, 30 MHz) to 30 GHz. In this case, the power semiconductor module 900 is a high frequency module. Typical examples of the power semiconductor element 200 appropriate for the high frequency use include a lateral diffused MOS (LDMOS) transistor and a gallium nitride (GaN) transistor.
[0033] The power semiconductor element 200 is disposed on a mounting region 55M of a heat sink plate 50 of the package 100. It is preferable that the mounting region 55M and the power semiconductor element 200 be joined to each other with the joining layer 42 containing thermosetting resin and metal being interposed therebetween. It is preferable that the thermosetting resin of the joining layer 42 include epoxy resin. It is preferable that the metal of the joining layer 42 include silver.
[0034] Although the details will be described later, the package 100 includes the heat sink plate 50 and a frame 80. The heat sink plate 50 includes the mounting region 55M inside the frame 80. In other words, the heat sink plate 50 includes the mounting region 55M surrounded by the frame 80. The power semiconductor element 200 is mounted on the mounting region 55M of the heat sink plate 50.
[0035] The cover 300 is attached to the package 100. Specifically, the adhesive layer 46 bonds the frame 80 and the cover 300 to each other. This constitutes a sealing space 950 that seals the power semiconductor element 200 without gross leak. Thus, the power semiconductor element 200 is protected from an external environment with high airtightness so that water vapor and other gases in the atmosphere do not enter. It is preferable that the sealing space 950 have environmental resistance to 500 cycles of temperature changes between −65° C. and +150° C. Specifically, it is preferable that the sealing space 950 not have gross leak even after being exposed to the temperature changes.
[0036]
[0037] The frame 80 includes a first material (hereinafter also referred to as a “material of the frame 80”). It is preferable that the material of the frame 80 have heat resistance to thermal treatment at 260° C. for 2 hours. It is preferable that the material of the frame 80 include first resin (hereinafter also referred to as “resin of the frame 80”). It is preferable that the resin of the frame 80 be thermoplastic resin.
[0038] It is preferable that an inorganic filler (first inorganic filler) be dispersed in the resin of the frame 80. The inorganic filler in the resin of the frame 80 preferably includes at least one of fiber-like particles and plate-like particles. Owing to the shape being a fiber-like shape or a plate-like shape, when the frame 80 is formed with injection molding technology or the like, the filler is prevented from inhibiting a flow of the resin. Examples of a material of such an inorganic filler include silica glass fibers, alumina fibers, carbon fibers, talc (3MgO, 4SiO.sub.2, H.sub.2O), wollastonite, mica, graphite, calcium carbonate, dolomite, glass flakes, glass beads, barium sulfate, and titanium oxide. As the size of the inorganic filler made of talc on a flat plate, the particle diameter is 1 μm to 50 μm, for example. Here, the particle diameter is an arithmetic mean value of the length of the major axis obtained through cross-sectional observation of resin. It is preferable that the thermal expansion coefficient of the inorganic filler be 17 ppm/K or less, in consideration of the thermal expansion coefficient of copper. It is preferable that the content of the inorganic filler be 30 wt % to 70 wt %.
[0039] The external terminal electrode 90 is attached to the frame 80. In the present embodiment, the external terminal electrode 90 is directly attached to the frame 80. The external terminal electrode 90 is made of metal, and preferably contains copper with purity of 90 wt % (weight percentage) or more. Note that, instead of the material containing copper with high purity as described above, Kovar (trademark), iron-nickel alloy, or the like may be used. Note that nickel plating and gold plating on the nickel plating may be provided on the surface of the external terminal electrode 90 for the purpose of securing joinability to a bonding wire 205 or the like.
[0040] The heat sink plate 50 supports the frame 80. The heat sink plate 50 is made of a non-composite material containing copper with purity of 95.0 wt % or more, preferably purity of 99.8 wt % or more.
[0041] The heat sink plate 50 includes an inner surface 51 surrounded by the frame 80. The inner surface 51 includes a to-be-mounted region 55U in which the power semiconductor element 200 (
[0042] The adhesive layer 41 bonds the frame 80 and the heat sink plate 50 to each other. The adhesive layer 41 is made of a second material (hereinafter also referred to as a “material of the adhesive layer 41”) different from the material of the frame 80. It is preferable that the material of the adhesive layer 41 include second resin (hereinafter also referred to as “resin of the adhesive layer 41”). It is preferable that the resin of the adhesive layer 41 be thermosetting resin in view of heat resistance and high liquidity before being cured.
[0043] It is preferable that an inorganic filler (second inorganic filler) be dispersed in the resin of the adhesive layer 41. The inorganic filler in the resin of the adhesive layer 41 preferably contains at least one of silica glass and crystalline silica, and is more preferably made of silica glass. Typically, the thermal expansion coefficient of silica glass is approximately 0.5 ppm/K, and the thermal expansion coefficient of crystalline silica is approximately 15 ppm/K, and accordingly the thermal expansion coefficient of the inorganic filler can be 17 ppm/K or less. This is particularly desirable when epoxy resin or fluorine resin is used as the resin of the adhesive layer 41. In this case, it is preferable that the content of the inorganic filler be 50 wt % to 90 wt %. Instead of or together with at least one of silica glass and crystalline silica, at least one of alumina, aluminum hydroxide, talc, iron oxide, wollastonite, calcium carbonate, mica, titanium oxide, and carbon fibers may be used. The shape of the inorganic filler is, for example, a spherical shape, a fiber-like shape, or a plate-like shape. In contrast, when silicone resin is used as the resin of the adhesive layer 41, because the silicone resin has rubber elasticity, the restriction of the thermal expansion coefficient of the inorganic filler can be substantially disregarded. In this case, the content of the inorganic filler may be adjusted in view of liquidity control of the adhesive layer 41 or the like, and is preferably 1 wt % to 10 wt %. From the viewpoint of securing liquidity of the adhesive layer 41 before being cured, spherical silica glass (amorphous silica) having a particle diameter of 1 μm to 50 μm is optimal. Here, the particle diameter indicates an arithmetic mean diameter measured through cross-sectional observation of resin.
[0044] It is preferable that the elastic modulus of the adhesive layer 41 be from 10 GPa to 20 GPa. As described above, it is preferable that the adhesive layer 41 have an elastic modulus higher than that of a general adhesive layer. This is because, when heat resistance to a thermal load (typically, a load at approximately 260° C. for 2 hours) imposed during a mounting process of the power semiconductor element 200 is to be provided for the package 100, a material having a high elastic modulus is in many cases inevitably selected as the material of the adhesive layer 41. Specifically, to bring the thermal expansion coefficient of the adhesive layer 41 closer to the thermal expansion coefficient (in a case of Cu, approximately 17 ppm/K) of the heat sink plate 50 with the aim of reducing a thermal stress, the elastic modulus of the adhesive layer 41 is in many cases inevitably increased.
[0045] The adhesive layer 41 includes a first composition, and the adhesive layer 46 (
[0046] It is preferable that the elastic modulus of the adhesive layer 46 be lower than the elastic modulus of the adhesive layer 41. For example, the elastic modulus of the adhesive layer 46 may be half of the adhesive layer 41 or less. In a strict sense, the elastic modulus of the adhesive layer has temperature dependency; however, in this comparison, the elastic modulus at room temperature (for example, 20° C.) can be used as a standard.
[0047] It is preferable that the adhesive layer 41 contain the inorganic filler at a first weight ratio. It is preferable that the adhesive layer 46 contain the inorganic filler at a second weight ratio smaller than the first weight ratio, or not contain the inorganic filler. The inorganic filler is, for example, made of silica glass having a particle diameter of approximately 1 μm to 50 μm. For example, the second weight ratio may be half of the first weight ratio or less.
[0048] Bonding using the adhesive layer 41 has airtightness. It is preferable that the airtightness has heat resistance to the thermal treatment at 260° C. for 2 hours. In other words, it is preferable that the airtightness between the heat sink plate 50 and the frame 80 has heat resistance to the thermal treatment at 260° C. for 2 hours. Note that a test as to whether or not the airtightness between the heat sink plate 50 and the frame 80 has heat resistance to the thermal treatment at 260° C. for 2 hours may be carried out by performing a gross leak test, which is carried out by performing the thermal treatment on the package 100 (
[0049] It is preferable that the airtightness between the cover 300 and the frame 80 has heat resistance to thermal treatment at 260° C. for 30 seconds. Thus, it is preferable that the adhesive layer 46 has heat resistance to the thermal treatment at 260° C. for 30 seconds. The thermal treatment at 260° C. for 30 seconds is typical thermal treatment in a mounting process of the power semiconductor module 900. Note that, unlike the adhesive layer 41, the adhesive layer 46 is not subjected to heating during the mounting process of the power semiconductor element 200, and thus is not usually required to have such high heat resistance as to be able to tolerate approximately 260° C. for 2 hours.
[0050] (Manufacturing Method)
[0051] Next, a manufacturing method of the power semiconductor module 900 (
[0052] Next, the power semiconductor element 200 is mounted on the to-be-mounted region 55U of the heat sink plate 50. With this, the to-be-mounted region 55U (
[0053] With reference to
[0054] With reference to
[0055] Attachment of the cover 300 to the package 100 is performed so that such thermal damage as to cause gross leak is not given to the package 100 in which the power semiconductor element 200 is mounted. In other words, attachment of the cover 300 to the package 100 is performed so that such thermal damage as to cause gross leak is not given to the adhesive layer 41. For example, the cover 300 is attached to the package 100 with interposition of the adhesive layer 46 therebetween, which is cured at such a curing temperature that does not lead to the thermal damage described above. The curing temperature is, for example, less than 260° C.
[0056] Next, a manufacturing method of the package 100 (
COMPARATIVE EXAMPLES
[0057] With reference to
[0058] By using the above-described composite material as a material of the heat sink plate 50A, the thermal expansion coefficient of the heat sink plate 50A can be brought closer to the thermal expansion coefficients of the frame 80A made of ceramics and the power semiconductor element 200. With this, fracture due to a difference of thermal expansion and contraction can be prevented. This allows joining of the frame 80A and the power semiconductor element 200 to the top of the heat sink plate 50A at high temperature.
[0059] In the present comparative example, when the power semiconductor element 200 is mounted, the heat sink plate and the frame are joined to each other, similarly to the present embodiment described above. In order to mount the power semiconductor element 200 so as not to disturb the joining, there is a restriction that the power semiconductor element 200 needs to be mounted at a temperature lower than a joining temperature of the frame 80A. In the present comparative example, the frame 80A itself has high heat resistance and a difference between the thermal expansion coefficient of the frame 80A and the thermal expansion coefficient of the heat sink plate 50A is small, and thus joining between the frame 80A and the heat sink plate 50A can be performed at a high temperature of approximately 780° C. to 900° C. Thus, the joining hardly receives negative influence through exposure to a mounting temperature of the power semiconductor element 200 being a lower temperature. Further, because the thermal expansion coefficient of the heat sink plate 50A is close to the thermal expansion coefficient of the power semiconductor element 200, fracture of the power semiconductor element 200 due to a thermal stress during mounting can be avoided even if the mounting temperature is high to some extent. Therefore, a joining layer 42A for mounting of the power semiconductor element 200 can be formed with brazing at a high temperature of, for example, approximately 400° C.
[0060] In the present comparative example, a composite material needs to be used as a material of the heat sink plate 50A for the sake of adjustment of the thermal expansion coefficient. Thus, unlike the case of the heat sink plate 50 (
[0061] Next, a manufacturing method of a power semiconductor module 900B (
[0062] In the present comparative example, the power semiconductor element 200 has already been mounted with the joining layer 42 (
[0063] (Gist of Effects)
[0064] According to the present embodiment, the heat sink plate 50 (
[0065] The adhesive layer 46 that bonds the frame 80 and the cover 300 to each other has the second composition different from the first composition of the adhesive layer 41. With this, in comparison to the composition of the adhesive layer 41, the composition of the adhesive layer 46 can be made to be a composition appropriate for absorbing the difference of thermal expansion and contraction between the package 100 and the cover 300. Thus, occurrence of gross leak caused by damage due to the difference of the thermal expansion and contraction can be prevented.
[0066] The elastic modulus of the adhesive layer 46 is lower than the elastic modulus of the adhesive layer 41. With this, in comparison to the composition of the adhesive layer 41, the composition of the adhesive layer 46 can be made to be a composition appropriate for absorbing the difference of thermal expansion and contraction between the package 100 and the cover 300. On the other hand, since the elastic modulus of the adhesive layer 41 is higher than the elastic modulus of the adhesive layer 46, the thermal expansion coefficient of the adhesive layer 41 can be more easily brought closer to the thermal expansion coefficient of the heat sink plate 50. With this, damage to the package due to a thermal stress can be reduced. The inventors of the present invention arrived at the above-described configuration from the idea that, in order to prevent occurrence of gross leak of the power semiconductor module 900, regarding the adhesive layer 41, compatibility of the thermal expansion coefficient with the heat sink plate 50 is particularly important, while regarding the adhesive layer 46, stress relief due to elasticity of the adhesive layer 46 itself is particularly important.
[0067] The elastic modulus of the adhesive layer 41 is 10 GPa to 20 GPa. If the same composition as the composition of the adhesive layer 41 having such a high elastic modulus were applied to the adhesive layer 46, damage is liable to be caused to the power semiconductor module 900, in particular the cover 300 thereof, due to the difference of the thermal expansion and contraction between the package 100 and the cover 300. Further, due to the damage, gross leak may occur. According to the present embodiment, the composition of the adhesive layer 46 is different from the composition of the adhesive layer 41, and thus such a situation as described above can be avoided.
[0068] The adhesive layer 46 contains an inorganic filler at the second weight ratio smaller than the first weight ratio, or does not contain an inorganic filler. With this, the elastic modulus of the adhesive layer 46 can be reduced. This can enhance the effect of relieving a thermal stress due to the difference of the thermal expansion coefficient between the package 100 and the cover 300 owing to elasticity of the adhesive layer 46.
[0069] The airtightness between the cover 300 and the frame 80 has heat resistance to the thermal treatment at 260° C. for 30 seconds. With this, after the frame 80 and the cover 300 are bonded to each other, a mounting process of the power semiconductor module 900 corresponding to a thermal load as high as the thermal treatment at 260° C. for 30 seconds can be performed.
[0070] It is preferable that the airtightness between the heat sink plate 50 and the frame 80 have heat resistance to the thermal treatment at 260° C. for 2 hours. With this, even when the thermal load corresponding to the thermal treatment at 260° C. for 2 hours is applied at the time of mounting of the power semiconductor element 200, the application of the thermal load can be prevented from being a cause of gross leak of the sealing space 950 (
[0071] It is preferable that the sealing space 950 (
[0072] It is preferable that the to-be-mounted region 55U (
[0073] It is preferable that the material of the frame 80 include resin. With this, brittle fracture due to a thermal stress from the heat sink plate 50 to the frame 80 is made less liable to occur. It is preferable that the resin of the frame 80 be thermoplastic resin. With this, the frame 80 can be formed with high productivity using injection molding technology or the like. It is preferable that an inorganic filler be dispersed in the resin of the frame 80. With this, the thermal expansion coefficient of the frame 80 can be brought closer to the thermal expansion coefficient of the heat sink plate 50. It is preferable that the inorganic filler of the resin of the frame 80 include at least one of fiber-like particles and plate-like particles. With this, when the frame 80 is formed with injection molding technology or the like, the filler is prevented from inhibiting a flow of the resin.
[0074] It is preferable that the material of the adhesive layer 41 include resin. With this, a thermal stress applied from the heat sink plate 50 to the frame 80 through the adhesive layer 41 is relieved. Thus, fracture of the frame 80 due to the thermal stress is made less liable to occur. It is preferable that the resin of the adhesive layer 41 be thermosetting resin. With this, heat resistance of the adhesive layer 41 can be enhanced, and liquidity can be more easily secured before being cured. The liquidity is important in securing productivity of a process of forming the adhesive layer 41. If the liquidity is low, it is difficult to use methods such as printing, dispensing, and spraying. It is preferable that an inorganic filler be dispersed in the resin of the adhesive layer 41. With this, the thermal expansion coefficient of the adhesive layer 41 can be brought closer to the thermal expansion coefficient of the heat sink plate 50. This can prevent fracture due to a thermal stress under a high temperature and under a temperature cycle. As described above, the inorganic filler in the resin of the adhesive layer 41 preferably contains at least one of silica glass and crystalline silica, and is more preferably made of silica glass. With this, the thermal expansion coefficient of the inorganic filler can be 17 ppm/K or less, in consideration of the thermal expansion coefficient of copper.
[0075] When the power semiconductor element 200 is mounted, it is preferable that the to-be-mounted region 55U (
[0076] The external terminal electrode 90 is directly attached to the frame 80. This eliminates the need of the process of bonding the external terminal electrode 90 and the frame 80 to each other. Thus, a process of assembling the package 100 can be simplified.
[0077] (Modifications)
[0078]
Second Embodiment
[0079] (Configuration)
[0080]
[0081]
[0082]
[0083] (Manufacturing Method)
[0084] Next, a manufacturing method of the power semiconductor module 900v (FIG. 11) will be described. First, the package 100v (
[0085] With reference to
[0086] From the above, the additional frame 80u of the package 100v and the cover 300 are bonded to each other. With this, the power semiconductor module 900v (
[0087] Note that the above process can also be applied to the above-described first embodiment in substantially the same manner.
[0088] (Gist of Effects)
[0089] According to the present embodiment as well, the effects substantially the same as those of the first embodiment can be obtained.
[0090] The adhesive layer 44v has the third composition different from the second composition of the adhesive layer 46. With this, in comparison to the composition of the adhesive layer 44v, the composition of the adhesive layer 46 can be made to be a composition appropriate for absorbing the difference of thermal expansion and contraction between the package 100v and the cover 300. Thus, occurrence of gross leak caused by damage due to the difference of the thermal expansion and contraction can be prevented.
[0091] The third composition of the adhesive layer 44v may be the same as the first composition of the adhesive layer 41. Through such a common use of the compositions, the manufacturing process of the package 100v can be simplified.
[0092] The process of forming the adhesive layer 46 includes a process of changing the half-cured layer 46B provided on the cover 300 to the adhesive layer 46. With this, when the cover 300 provided with the half-cured layer 46B is prepared in advance, the adhesive layer 46 can be easily formed.
Working Examples and Reference Examples
[0093] First of all, an experiment for evaluating configurations of the package to which the cover is to be attached will be described below (see table 1 and table 2). Note that an experiment for comprehensively evaluating configurations including the cover and its adhesive layer as well as the package will be described later (see table 3).
[0094] Table 1 and table 2 below show the configurations of the package and results of a gross leak test performed on the configurations according to working examples (Nos. 1 to 25) and reference examples (Nos. 101 to 120), respectively. In the tables, “adhesive layer” refers to the adhesive layer between the heat sink plate and the frame, and “electrode” refers to the external terminal electrode. [Table 1]
TABLE-US-00001 TABLE 1 GROSS LEAK AFTER BEING WORKING ADHESIVE LAYER FRAME LEFT UNDER EXAMPLE MAIN MAIN ELECTRODE HIGH No. COMPONENT FILLER COMPONENT FILLER MATERIAL TEMPERATURE 1 EPOXY SILICA RESIN LIQUID CONTAINED COPPER NOT RESIN GLASS CRYSTAL OBSERVED 2 POLYMER KOVAR NOT OBSERVED 3 NONE COPPER NOT OBSERVED 4 SILICONE NONE COPPER NOT RESIN OBSERVED 5 SILICA COPPER NOT OBSERVED 6 FLUORINE SILICA COPPER NOT RESIN GLASS OBSERVED 7 EPOXY SILICA POLYPHENYLENE CONTAINED COPPER NOT RESIN GLASS SULFIDE OBSERVED (PPS) 8 POLYARYL- COPPER NOT ETHERKETONE OBSERVED (PAEK) 9 POLY- COPPER NOT ETHERKETONE OBSERVED (PEEK) 10 THERMO- COPPER NOT PLASTIC OBSERVED POLYIMIDE (TPI) 11 POLYAMIDE- COPPER NOT IMIDE (PAI) OBSERVED 12 POLY- COPPER NOT PHTHALAMIDE OBSERVED (PPA) 13 POLY- NONE COPPER NOT TETRA- OBSERVED FLUORO- ETHYLENE (Teflon) (PTFE) 14 POLYIMIDE COPPER NOT (PI) OBSERVED 15 SILICONE SILICA POLYPHENYLENE CONTAINED COPPER NOT RESIN SULFIDE OBSERVED (PPS) 16 POLY- COPPER NOT ARYLETHER- OBSERVED KETONE (PAEK) 17 POLY- COPPER NOT ETHER- OBSERVED KETONE (PEEK) 18 THERMOPLASTIC COPPER NOT POLYIMIDE OBSERVED (TPI) 19 POLYAMIDE- COPPER NOT IMIDE (PAI) OBSERVED 20 POLY- COPPER NOT PHTHALAMIDE OBSERVED (PPA) 21 POLYTETRA- NONE COPPER NOT FLUOROETHYLENE OBSERVED (Teflon) (PTFE) 22 POLYIMIDE (PI) COPPER NOT OBSERVED 23 EPOXY SILICA CERAMICS ZIRCONIA NONE COPPER NOT RESIN GLASS OBSERVED 24 FORSTERITE COPPER NOT OBSERVED 25 ALUMINA COPPER NOT OBSERVED
TABLE-US-00002 TABLE 2 GROSS LEAK REF- AFTER BEING ERENCE ADHESIVE LAYER LEFT UNDER EX- MAIN FRAME HIGH AMPLE COM- MAIN ELECTRODE TEMPER- No. PONENT FILLER COMPONENT FILLER MATERIAL ATURE 101 VINYL NONE RESIN LIQUID CONTAINED COPPER OBSERVED ACETATE CRYSTAL RESIN POLYMER 102 VINYL NONE OBSERVED CHLORIDE RESIN 103 ACRYLIC NONE OBSERVED RESIN 104 CELLULOSE NONE OBSERVED RESIN 105 UREA SILICA OBSERVED RESIN GLASS 106 MELAMINE SILICA OBSERVED RESIN GLASS 107 PHENOLIC SILICA OBSERVED RESIN GLASS 108 POLY- SILICA OBSERVED URETHANE GLASS RESIN 109 CHLOR- NONE OBSERVED OPRENE RESIN 110 NITRILE NONE OBSERVED RESIN 111 MODIFIED NONE OBSERVED SILICONE RESIN 112 URETHANE NONE OBSERVED RESIN 113 EPOXY SILICA POLY- OBSERVED RESIN GLASS AMIDE (NYLON) (PA) 114 POLY- OBSERVED PHENYL- ENEETHER (PPE) 115 POLY- OBSERVED ACETAL (POM) 116 POLY- OBSERVED CARBONATE (PC) 117 POLY- OBSERVED SULFONE (PSU) 118 POLY- OBSERVED ETHER- SULFONE (PEA) 119 POLY- OBSERVED ARYLATE (PAR) 120 POLY- OBSERVED ETHERIMIDE (PEI)
[0095] The content of the filler of the adhesive layer was 82 wt % in a case of silica glass, and was 5 wt % in a case of silica (crystalline silica). Note that, although detailed description is omitted, it is considered that there is no significant influence even if the content of silica glass is changed within a range of 50 wt % to 90 wt %, instead of 82 wt %. Further, it is considered that there is no significant influence even if the content of silica (crystalline silica) is changed within a range of 1 wt % to 10 wt %, instead of 5 wt %. When a filler for the frame was “contained”, a filler made of talc was added at 46 wt %. It is considered that there is no significant influence even if the content of the filler is changed within a range of 30 wt % to 70 wt %, instead of 46 wt %. As a material of the electrode, copper alloy (Japanese Industrial Standards (JIS) C 1940) or Kovar was used. As the heat sink plate, a copper material according to Japanese Industrial Standards (JIS) C 1510 was used, and the heat sink plate had dimensions of 32 mm×10 mm in plan view and a thickness dimension of 1.7 mm.
[0096] A gross leak test was performed on the package of table 1 and table 2 after being left under a high temperature. The leaving of the package under a high temperature was performed by leaving the package in an environment at 260° C. for 2 hours. This heating condition is close to a heating condition in the mounting process of the power semiconductor element.
[0097] The gross leak test after leaving of the package under a high temperature was performed on a structure configured in the following manner: a package to which the cover was not attached was left in an environment at 260° C. for 2 hours, and then a cover made of liquid crystal polymer was attached using an adhesive agent at a bonding temperature of 190° C. Note that the bonding is performed merely for the purpose of obtaining a sealed state for the sake of the gross leak test, and it is not suggested that a high thermal load is applied after the bonding. Accordingly, it is only necessary that the composition of the adhesive agent be selected such that leakage does not occur through the adhesive agent itself during the gross leak test. For the sake of convenience, in the present experiment, the same resin as the resin (second resin) of the adhesive layer used to join the heat sink and the frame was used as the adhesive agent. Regarding the gross leak test, specifically, Fluorinert (trademark) being a solvent having a high boiling point was heated to 120° C. f 10° C., and the above-described structure was immersed in the solvent for 30 seconds. Occurrence of a leakage was determined depending on whether or not there were bubbles during the immersion.
[0098] In each of No. 101 to No. 120 (table 2), a gross leak was observed after leaving of the package under a high temperature. It is inferred that the reason of the occurrence of the gross leak under the high temperature is because heat resistance of the adhesive layer of No. 101 to No. 120 (table 2) is lower than that of the adhesive layer of No. 1 to No. 25 (table 1).
[0099] Next, the experiment for comprehensively evaluating configurations including the cover and its adhesive layer as well as the package will be described below. Table 3 below shows configurations of the power semiconductor module and results of a temperature cycle test performed on the configurations according to working examples (Nos. 201 to 204) and comparative example (Nos. 205 to 208). In the table, “adhesive layer” in the column of “package” refers to the first adhesive layer (corresponding to the adhesive layer 41 of
TABLE-US-00003 TABLE 3 ATTACHMENT PACKAGE OF COVER FILLER OF FILLER OF TEMPERATURE ADHESIVE ADHESIVE CYCLE TEST MATERIAL LAYER MATERIAL LAYER PART OF No. OF FRAME (wt %) OF COVER (wt %) RESULTS LEAKAGE WORKING 201 LIQUID 80 LIQUID 40 PASS N/A EXAMPLE CRYSTAL CRYSTAL POLYMER POLYMER 202 PPS 80 PPS 40 PASS N/A 203 PEAK 80 PEAK 40 PASS N/A 204 PPS 80 LIQUID 40 PASS N/A CRYSTAL POLYMER COMPARATIVE 205 LIQUID 80 LIQUID 80 FAIL COVER EXAMPLE CRYSTAL CRYSTAL POLYMER POLYMER 206 PPS 80 PPS 80 FAIL COVER 207 PEAK 80 PEAK 80 FAIL COVER 208 LIQUID 40 LIQUID 40 FAIL PACKAGE CRYSTAL CRYSTAL POLYMER POLYMER
[0100] As a material of the frame, liquid crystal polymer, PPS, and PEAK in each of which a filler was dispersed was used. The liquid crystal polymer had a thermal expansion coefficient of 12 ppm and an elastic modulus of 11.3 GPa. The PPS had a thermal expansion coefficient of 17 ppm and an elastic modulus of 17.5 GPa. The PEAK had a thermal expansion coefficient of 17 ppm and an elastic modulus of 10 GPa.
[0101] As a material of each of the first adhesive layer and the second adhesive layer, a material in which a filler made of silica glass was dispersed in epoxy resin was used. Two types of compositions were used therefor. Specifically, a composition in which a filler made of silica glass was dispersed in epoxy resin at 80 wt % and a composition in which a filler made of silica glass was dispersed in epoxy resin at 40 wt % were used. The former (filler 80 wt %) had a thermal expansion coefficient of 12 ppm/K and an elastic modulus of 17 GPa. The latter (filler 40 wt %) had a thermal expansion coefficient of 120 ppm/K and an elastic modulus of 4 GPa. As a material of the electrode, copper alloy (Japanese Industrial Standards (JIS) C 1940) was used. As the heat sink plate, a copper material according to Japanese Industrial Standards (JIS) C 1510 was used, and the heat sink plate had dimensions of 32 mm×10 mm in plan view and a thickness dimension of 1.7 mm.
[0102] Temperature cycles were performed with 500 cycles of temperature changes between −65° C. and +150° C. The temperature cycles are simulation of temperature changes to which the power semiconductor module installed in a severe external environment is exposed. Thus, it is necessary that no gross leak be observed in the package used under a severe external environment after the temperature cycles. Note that the method of the gross leak test itself is the same as the method described above.
[0103] Note that liquid crystal polymer was used as a material of the cover. Further, in the present experiment, in order to simplify the experiment, instead of an actual mounting process of the power semiconductor element, a process of performing thermal treatment on the package was performed at 260° C. for 2 hours as a simulation of the mounting process.
[0104] From the results of the experiment, it was shown that use of a composition different from the composition of the first adhesive layer and the third adhesive layer as the composition of the second adhesive layer yielded more preferable results of the temperature cycle test. Specifically, it was shown that the elastic modulus of the second adhesive layer was preferably lower than the elastic modulus of the first adhesive layer and the third adhesive layer.
[0105] Note that the present experiment is performed using the package (see
[0106] While the invention has been shown and described in detail, the foregoing description is in all aspects illustrative and not restrictive. It is therefore understood that numerous unillustrated modifications can be devised without departing from the scope of the present invention.