FILM FROM WHICH PACKAGING CAN BE MANUFACTURED, IN PARTICULAR FOR FOODSTUFFS, OPTICAL GLASSES, INDIVIDUAL PARTS FOR BIOREACTORS, SOLAR PANELS OR THE LIKE

20210292065 · 2021-09-23

    Inventors

    Cpc classification

    International classification

    Abstract

    In the case of a film (1) from which packaging (2) can be manufactured, in particular for foodstuffs (3), optical glasses (4), individual parts for bioreactors, solar panels or the like, medical devices, pharmaceutical products or the like, the film (1) consists of at least two polymer layers which are joined together in a co-extension die (7) to form the film (1), the film (1) should already have a sterile or at least particle-free surface during the manufacturing process, which surface is reliably protected against contamination of all kinds during the transport and storage times of the film (1). This is achieved in that an additive (8) is present in one of the layers in a dosable amount and/or in that the material pairing between the first and second layers (5.sub.1, 6.sub.1) has a low adhesion force, and in that the first and second layers (5.sub.1, 6.sub.1) can be non-destructively detached from one another in a separating plane (15), in such a way that the film (1) can be divided into two film webs (11, 12).

    Claims

    1. A film (1) from which packaging (2) can be manufactured, in particular for foodstuffs (3), optical glasses (4), individual parts for bioreactors, solar panels or the like, medical devices, pharmaceutical products or the like, consisting of at least two polymer layers which are joined together in a co-extension die (7) to form the film (1), characterized in that, an additive (8) is present in one of the layers in a dosable amount and/or in that the material pairing between the first and second layers (5.sub.1, 6.sub.1) has a low adhesion force, and in that the first and second layers (5.sub.1, 6.sub.1) can be non-destructively detached from one another in a separating plane (15), in such a way that the film (1) can be divided into two film webs (11, 12).

    2. The film according to claim 1, characterized in that, the layer structure of the two layers (5, 6) has an identical structure.

    3. The film according to claim 1, characterized in that, the second layer (6) consists of several different sheets (14.sub.1, 14.sub.2, . . . 14.sub.n) and that the first sheet (14.sub.1) facing the separation plane (15) has a thinner wall thickness than the subsequent sheets (14.sub.1, 14.sub.2, . . . 14.sub.n).

    4. The film according to claim 1, characterized in that, within one of the two layers (5, 6), at least one oxygen-barrier sheet (13.sub.1 or 14.sub.2) and an oxygen-binding substrate sheet (13.sub.2 or 14.sub.3) are incorporated in one or both layers (5, 6), and/or that this oxygen-barrier sheet (13.sub.1 or 14.sub.2) is covered or enclosed by at least one further sheet (13.sub.2 or 14.sub.3) which is spaced further away from the separation plane (15).

    5. The film according to claim 4, characterized in that, the oxygen barrier (13.sub.3, 14.sub.3) is formed from the materials EVOH, PLA, PVOH, PA or PET.

    6. The film according to claim 4, characterized in that, in that the polymers (9.sub.1 to 9.sub.n or 10.sub.1 or 10.sub.n ) are formed from a polyolefin material for the respective sheets (13.sub.1. . . 13.sub.n , 14.sub.1. . . 14.sub.n) as LDPE, LLDPE, mLLDPE, HDPE, PPhomo or PPCopo, and that the layer structure of the first layer (5) has different sheets (13.sub.1. . . 13.sub.n) of these materials, which are optionally (13.sub.1. . . 13.sub.n) separated by sheets of another polymer material.

    7. The film according to claim 1, characterized in that, the respective first sheet (13.sub.1; 14.sub.1) of the two layers (5, 6) facing the separation plane (15) is formed from a polymer pairing or mutually incompatible polymers which have no or low adhesive forces, preferably from the material pairings polyolefin/PA, polyolefin/EVOH, polyolefin/PET or GPET/PE.

    8. The film according to claim 1, characterized in that, a surface-active substance is added in one of the layers (5 or 6), by means of which the adhesive forces between the layers of the two sheets (13.sub.1; 14.sub.1) lying apart from one another are increased or reduced.

    9. The film according to claim 1, characterized in that, after the two layers (5, 6) have been separated from one another, the two independent film webs (11, 12) are formed, each of which can be fed to a different purpose or area of use, and in that the respective surfaces of the film webs (11, 12) facing one another before the separation are particle-free and/or sterile.

    10. The film according to claim 1, characterized in that, polysorbate 40, 60, 65 or 80 as well as Tagat or Tween 20 or 80 are incorporated as surface-active substances in one of the sheets (13.sub.1 or 14.sub.1) of the layers (5, 6).

    Description

    BRIEF DESCRIPTION OF THE DRAWINGS

    [0016] The drawings show a sample embodiment of a film with various polymer layers in accordance with the present invention, the details of which are explained below. In the drawings:

    [0017] FIG. 1 shows a schematic co-extension die, in which different polymers are heated and liquefied, by means of which a film comprising two layers forming a parting plane is formed, in such a way that the layers can be separated from one another in a non-destructive manner, as a sectional view,

    [0018] FIGS. 2a show the film according to FIG. 1 with the two layers, in to 2c each of which there are different sheets of polymer,

    [0019] FIG. 2d shows the film according to FIG. 1 with the two layers having identical structures, and

    [0020] FIGS. 3a show various applications for the film according to FIGS. 1, to 3c which is constructed in two film webs with different or identical sheets.

    DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS

    [0021] FIG. 1 shows a schematic diagram of a co-extension die 7 in which different polymers 9.sub.1-9.sub.n and 10.sub.1-10.sub.n are filled. These polymers 9.sub.1-9.sub.n and 10.sub.1-10.sub.n can be made of different materials. The respective polymers 9.sub.1-9.sub.n are associated with a film 1 having an upper layer 5, and the polymers 10.sub.1-10.sub.n are associated with a lower layer 6 of the film 1. The respective polymers 9.sub.1-9.sub.n and 10.sub.1-10.sub.n are joined together in a co-extrusion process in the die 7. The parting plane between the two layers 5 and 6 is marked with the reference numeral 15.

    [0022] In particular, an additive 8 is admixed to the polymers 10.sub.1 of the layer 6. Once the polymers 9.sub.1-9.sub.n and 10.sub.1-10.sub.n have been joined together in the die 7 due to heating and leave the die 7, the film 1 is formed. In this case, the film 1 comprises the two layers 5 and 6 separated from one another by the separation plane 15, each of which comprises a plurality of sheets 13.sub.1, 13.sub.2-13.sub.n and 14.sub.1, 14.sub.2-14.sub.n, respectively. This is because any number of polymers 9.sub.1-9.sub.n and 10.sub.1-10.sub.n can be joined together in the die 7. In this case, the innermost sheet of the layer 5 facing the separation plane 15 is marked with the reference number 13 and the innermost sheet of layer 6 in relation to the separation plane 15 is marked with the reference number 14.sub.1, and the sheets further away from the separation plane 15 are marked with a higher ordinal number.

    [0023] The joining of the polymers 9.sub.1-9.sub.n and 10.sub.1-10.sub.n, respectively, is carried out in a particle-free or sterile environment, since impurities are not present inside the die 7 due to the high temperatures prevailing there.

    [0024] In FIG. 2a, the film 1 is composed of two layers 5 and 6, each having a sheet 13.sub.1 and 14.sub.1, respectively. In this regard, the additive 8 is mixed into the sheet 14.sub.1, in a predetermined amount. After the film 1 has been finished, the sheet 13.sub.1 can be non-destructively detached from the sheet 14.sub.1 to form two film webs 11 and 12 corresponding to the original layers 5 and 6, respectively.

    [0025] As the layers 5 and 6 are joined together inside the die 7 in a sterile, at least particle-free environment, the facing surfaces of the sheets 13.sub.1 and 14.sub.1 completely bond and seal together. Accordingly, no dirt particles can reach these surfaces of the film webs 11 and 12 during the storage and transport status of the film 1. Furthermore, the film 1 can be wound on a roll 16 for storage and transportation purposes. During the processing process of the film 1, it often has to be unwound from the roll 16 and processed several times. By unwinding the film 1 from the roll 16 and during the processing, the surfaces of the layers 5 and 6 are bonded to each other, so that no dirt particles or other impurities can reach the surface of the film webs 11 or 12 facing the separation plane 15 during this processing phase.

    [0026] FIG. 2b shows a film 1 with the two layers 5 and 6. The layer 5 now consists of two sheets 13.sub.1 and 13.sub.2, which are made of different polymers.

    [0027] Accordingly, the physical property of the film webs 11 is different from the physical property of the film web 12. Nevertheless, the layers 5 and 6 can be non-destructively detached from each other in the common separation plane 15 to produce the film webs 11 and 12, respectively.

    [0028] In FIG. 2c, layer 5 consists of three sheets 13.sub.1, 13.sub.2 and 13.sub.3 and layer 6 consists of two sheets 14.sub.1 and 14.sub.2, each of which comprises or is formed from different polymers. In this regard, a particular use of the film web 11 is, for example, to use it to provide packaging 2 for a foodstuff 3 comprising an oxygen scavenger sheet 13.sub.2. The scavenger component can in principle also be arranged in a further outer sheet 13.sub.3 or 13.sub.4. Then, a barrier should be provided in sheet 13.sub.2 or 13.sub.5, that is, spatially separated from the separation plane 15. Technically speaking, the attempt would be made to insert a scavenger sheet 13.sub.1 in such a way that it can react with oxygen as quickly as possible after activation.

    [0029] Consequently, a combination of a scavenger sheet 13.sub.1 and a barrier layer 13.sub.2 should be provided to first protect the scavenger component so that it cannot react and so it retains its original composition.

    [0030] The reaction start time, from when the sheet 13.sub.1 absorbs oxygen, cannot normally be determined precisely. The reaction begins as soon as oxygen reaches this sheet 13.sub.1. However, the absorption capacity of such an oxygen-absorbing sheet 13.sub.1 is limited, so that the manufacturer of a foodstuff 3 often desires the reaction start time for oxygen absorption to begin immediately at the packaging time of the foodstuff 3. Such a predetermined start of the reaction start time or oxygen absorption has not been possible up to now; this goal is only achieved with the layer structure explained above of the respective layer 5, 6 and its sealing agent of the second layer 6. The layer 6 contains an oxygen barrier and thus protects the scavenger from an unwanted reaction with oxygen in this embodiment of the sheet 13.sub.1. Therefore, an oxygen barrier must also be provided in layer 5, seen from the outside in front of the scavenger.

    [0031] Since now the sheet 13.sub.1 is formed of an oxygen absorbing or binding substrate, for example scavenger, which is completely covered by the layer 6 and moreover both the layer 5 and the layer 6 of the film 1 comprise an oxygen barrier sheet 13.sub.1 and 14.sub.2 respectively, the oxygen absorbing sheet 13.sub.4 is completely protected from the supply of oxygen during the transport and storage status. Thus, an adjustable reaction start time only occurs when the film web 12 is removed from the film web 11, and the film web 11 can be used immediately thereafter as packaging for the foodstuff 3.

    [0032] In FIG. 2d, the structure of the layers 5 and 6 is identical, so that there are two film webs 11 and 12 with identical physical properties.

    [0033] FIG. 3a shows how the film 1 is unwound from the roll 16 and immediately separated non-destructively into the two film webs 11 and 12. In this regard, the film web 11 with its particle-free surface can be placed directly on a glass panel of an iPhone so that no contamination occurs between the electrical device or its glass surface and the particle-free surface of the film web 11. The film web 11 can be used in an identical manner for packaging pharmaceutical products, solar panels, medical devices requiring sterile wrapping, furthermore packaging for individual parts of or for bioreactors also to be enclosed, or the like. This is merely an exemplary representation.

    [0034] The film web 12 can be put to another use, for example to package newspapers, magazines or other products to be protected against rainwater, which have a lower requirement on the surface composition of the film web 12.

    [0035] FIG. 3b shows that the film web 11 has its particle-free surface facing the foodstuff 3 in order to seal it in a completely airtight and watertight manner. The film web 11 can also be deep-drawn or perforated in some other way, if this is desired by the customer.

    [0036] The film web 12 comprises a material or combination of materials that is recyclable or that comprises recycled material. This is schematically represented by the recycle apparatus 17.

    [0037] FIG. 3c shows that identical film webs 11 and 12 can be used simultaneously to package a foodstuff 3.

    [0038] To simplify the separation of the film webs 11 and 12, it may be advantageous if the first sheet 141 of the layer 6 facing the separation plane 15 has a thinner wall thickness than the subsequent sheets 14.sub.2-14.sub.n in the layer 6, as this may reduce the adhesive forces required for separation.

    [0039] The polymers 9.sub.1-9.sub.n and 10.sub.1-10.sub.n for layers 5 and 6, respectively, are formed from polyolefin materials LDPE, LLDPE, mLLDPE, HDPE, PPCopo or PPhomo. Furthermore, the sheets 13.sub.1-13.sub.n and 14.sub.1-14.sub.n of the layers 5 and 6 can be formed of a thermoplastic polymer, for example the aforementioned one. The separation layer 15 has a polymer pairing of the materials of the polyolefins, in particular a pairing of polyolefin/PA, polyolefin/EVOH, polyolefin/PET or GPBET/PE. An adhesion promoter is usually provided between these layers, this is also polyolefinic.

    [0040] In addition, antistatic or other surface-active substances can be mixed into the sheets 13.sub.1 and 14.sub.1 facing the separation plane 15. Such substances are to be adapted to the intended use of the respective film web 11 or 12, so that, for example, electrical devices, accumulators, other electrically conductive components can also be stored antistatically by the respective film web 11 or 12.