Semiconductor device with interconnect to source/drain
10923579 ยท 2021-02-16
Assignee
Inventors
Cpc classification
H01L21/823878
ELECTRICITY
H01L29/66818
ELECTRICITY
H01L29/66628
ELECTRICITY
H01L21/76283
ELECTRICITY
H01L29/66772
ELECTRICITY
H01L27/1211
ELECTRICITY
H01L29/78618
ELECTRICITY
H01L29/42392
ELECTRICITY
H01L29/78606
ELECTRICITY
H01L21/823481
ELECTRICITY
H01L29/78603
ELECTRICITY
H01L21/3081
ELECTRICITY
H01L21/28587
ELECTRICITY
H01L29/78684
ELECTRICITY
H01L29/78696
ELECTRICITY
International classification
H01L21/762
ELECTRICITY
H01L29/423
ELECTRICITY
H01L29/66
ELECTRICITY
H01L21/306
ELECTRICITY
H01L27/12
ELECTRICITY
H01L29/49
ELECTRICITY
Abstract
A device including an SOI substrate and an isolation structure positioned at least partially in a trench that extends through a buried insulation layer and into a semiconductor bulk substrate of the SOI substrate is disclosed. The isolation structure includes a first dielectric layer positioned in a lower portion of the trench, a first material layer positioned above the first dielectric layer, the first material layer having a material different from a material of the first dielectric layer, and a second dielectric layer positioned above the first material layer, the second dielectric layer having a material different from the material of the first material layer.
Claims
1. A device, comprising: an SOI substrate comprising a semiconductor bulk substrate, a buried insulation layer positioned on said semiconductor bulk substrate and a semiconductor layer positioned on said buried insulation layer; a trench formed in said SOI substrate, said trench extending through said buried insulation layer and into said semiconductor bulk substrate; and an isolation structure positioned at least partially in said trench, said isolation structure comprising: a first dielectric layer positioned in a portion of said trench that extends into said bulk semiconductor substrate; a first material layer positioned above said first dielectric layer, said first material layer being made of a material that is different from a material of said first dielectric layer; a second dielectric layer positioned above said first material layer, said second dielectric layer being made of a material that is different from said material of said first material layer; and a liner layer positioned in said trench on said bulk semiconductor substrate and on said buried insulation layer, wherein said first material layer is positioned within said liner layer, wherein said first material layer is a spacer that comprises an opening that exposes a portion of an upper surface of said first dielectric layer.
2. The device of claim 1, wherein said first dielectric layer comprises silicon dioxide, said first material layer comprises silicon nitride and said second dielectric layer comprises an oxide material.
3. The device of claim 1, wherein said first dielectric layer comprises an upper surface that is substantially coplanar with an upper surface of said bulk semiconductor substrate.
4. The device of claim 1, wherein said buried insulation layer comprises an upper surface and said first material layer comprises an upper surface, and wherein said upper surface of said first material layer is positioned at a level that is below a level of said upper surface of said buried insulation layer.
5. The device of claim 1, wherein said second dielectric layer comprises an upper surface that is substantially coplanar with an upper surface of said semiconductor layer.
6. The device of claim 1, further comprising a liner layer positioned in said portion of said trench that extends into said bulk semiconductor substrate, wherein said first dielectric layer is positioned within said liner layer.
7. The device of claim 1, wherein said first material layer covers an entire upper surface of said first dielectric layer and said second dielectric layer covers an entire upper surface of said first material layer.
8. The device of claim 1, wherein a portion of said second dielectric layer is positioned in said opening in said first material layer and said second dielectric layer contacts said upper surface of said first dielectric layer.
9. A device, comprising: an SOI substrate comprising a semiconductor bulk substrate, a buried insulation layer positioned on said semiconductor bulk substrate and a semiconductor layer positioned on said buried insulation layer; a trench formed in said SOI substrate, said trench extending through said buried insulation layer and into said semiconductor bulk substrate; and an isolation structure positioned at least partially in said trench, said isolation structure comprising: a first dielectric layer positioned in a portion of said trench that extends into said bulk semiconductor substrate, said first dielectric layer comprising a first upper surface that is substantially coplanar with an upper surface of said bulk semiconductor substrate; a first material layer positioned above said first dielectric layer, said first material layer being made of a material that is different from a material of said first dielectric layer, said first material layer comprising an upper surface, wherein said upper surface of said first material layer is positioned at a level that is below a level of an upper surface of said buried insulation layer; a second dielectric layer positioned above said first material layer, said second dielectric layer being made of a material that is different from said material of said first material layer; and a liner layer positioned in said trench on said bulk semiconductor substrate and on said buried insulation layer, wherein said first material layer is positioned within said liner layer, wherein said first material layer is a spacer that comprises an opening that exposes a portion of an upper surface of said first dielectric layer and wherein a portion of said second dielectric layer is positioned in said opening in said first material layer and said second dielectric layer contacts said upper surface of said first dielectric layer.
10. The device of claim 9, wherein said second dielectric layer comprises an upper surface that is substantially coplanar with an upper surface of said semiconductor layer.
11. The device of claim 9, further comprising a liner layer positioned in said portion of said trench that extends into said bulk semiconductor substrate, wherein said first dielectric layer is positioned within said liner layer.
12. The device of claim 9, wherein said first material layer covers an entire upper surface of said first dielectric layer and said second dielectric layer covers an entire upper surface of said first material layer.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
(1) The disclosure may be understood by reference to the following description taken in conjunction with the accompanying drawings, in which like reference numerals identify like elements, and in which:
(2)
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(6) While the subject matter disclosed herein is susceptible to various modifications and alternative forms, specific embodiments thereof have been shown by way of example in the drawings and are herein described in detail. It should be understood, however, that the description herein of specific embodiments is not intended to limit the invention to the particular forms disclosed, but on the contrary, the intention is to cover all modifications, equivalents, and alternatives falling within the spirit and scope of the invention as defined by the appended claims.
DETAILED DESCRIPTION
(7) Various illustrative embodiments of the invention are described below. In the interest of clarity, not all features of an actual implementation are described in this specification. It will of course be appreciated that in the development of any such actual embodiment, numerous implementation-specific decisions must be made to achieve the developers' specific goals, such as compliance with system-related and business-related constraints, which will vary from one implementation to another. Moreover, it will be appreciated that such a development effort might be complex and time-consuming, but would nevertheless be a routine undertaking for those of ordinary skill in the art having the benefit of this disclosure.
(8) The following embodiments are described in sufficient detail to enable those skilled in the art to make use of the invention. It is to be understood that other embodiments would be evident, based on the present disclosure, and that system, structure, process or mechanical changes may be made without departing from the scope of the present disclosure. In the following description, numeral-specific details are given to provide a thorough understanding of the disclosure. However, it would be apparent that the embodiments of the disclosure may be practiced without the specific details. In order to avoid obscuring the present disclosure, some well-known circuits, system configurations, structure configurations and process steps are not disclosed in detail.
(9) The present disclosure will now be described with reference to the attached figures. Various structures, systems and devices are schematically depicted in the drawings for purposes of explanation only and so as to not obscure the present disclosure with details which are well known to those skilled in the art. Nevertheless, the attached drawings are included to describe and explain illustrative examples of the present disclosure. The words and phrases used herein should be understood and interpreted to have a meaning consistent with the understanding of those words and phrases by those skilled in the relevant art. No special definition of a term or phrase, i.e., a definition that is different from the ordinary or customary meaning as understood by those skilled in the art, is intended to be implied by consistent usage of the term or phrase herein. To the extent that a term or phrase is intended to have a special meaning, i.e., a meaning other than that understood by skilled artisans, such a special definition shall be expressively set forth in the specification in a definitional manner that directly and unequivocally provides the special definition for the term or phrase.
(10) As will be readily apparent to those skilled in the art upon a complete reading of the present application, the present methods are applicable to a variety of technologies, for example, NMOS, PMOS, CMOS, etc., particularly in the context of fully depleted silicon-on-insulator (FDSOI) technologies used for manufacturing ICs. The manufacturing techniques may be integrated in CMOS manufacturing processes. In particular, the process steps described herein are utilized in conjunction with any semiconductor device fabrication process that forms FETs and STIs for integrated circuits, and the process is readily applicable to a variety of devices, including, but not limited to, logic devices, memory devices such as SRAM devices, etc. Although the term MOS properly refers to a device having a metal gate electrode and an oxide gate insulator, that term is used throughout to refer to any semiconductor device that includes a conductive gate electrode (whether metal or other conductive material) that is positioned over a gate insulator (whether oxide or other insulator) which, in turn, is positioned over a semiconductor bulk substrate.
(11) Herein, techniques of manufacturing semiconductor devices comprising FETs are provided wherein contacts to source/drain regions of the FETs can be reliably formed. In particular, the disclosed techniques allow for an arrangement of the contacts such that the contacts at least partially cover STI regions without a risk of forming an electrical short to the semiconductor bulk substrate of the SOI substrate by the contact material.
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(13) The bulk semiconductor bulk substrate 101 may be a silicon substrate, in particular, a single crystal silicon substrate. Other materials may be used to form the semiconductor bulk substrate such as, for example, germanium, silicon germanium, gallium phosphate, gallium arsenide, etc. The semiconductor bulk substrate 101 may comprise N.sup.+/P.sup.+ doped regions for back biasing. The buried insulation layer 102 may include a dielectric material and may have a thickness of below 50 nm, for example. The buried insulation layer 102 may comprise silicon (di)oxide, for example, borosilicate glass. The buried insulation layer 102 may be composed of different layers and one of the different layers may comprise borophosphosilicate glass (BPSG) or an SiO.sub.2-compound comprising boron. The semiconductor layer 103 may provide the channel region of the FET and may be comprised of any appropriate semiconductor material, such as silicon, silicon/germanium, silicon/carbon, other II-VI or III-V semiconductor compounds and the like. The semiconductor layer 103 may have a thickness suitable for forming a fully depleted field effect transistor, for example, a thickness in a range from about 5-8 nm. For example, the thickness of the semiconductor layer 103 may be in the range of 5-20 nm, in particular, 5-10 nm, and the thickness of the buried insulation layer 102 may be in the range of 10-50 nm, in particular, 10-30 nm and, more particularly, 15-25 nm.
(14) In a P-channel FET area of the semiconductor layer 103, an SiGe channel may be formed. For example, a compressive strained silicon-germanium channel (cSiGe) is formed in the semiconductor layer 103 of the SOI substrate by local Ge enrichment involving the epitactical formation of a compressive SiGe layer on the exposed surface of the semiconductor layer 103. The compressive silicon-germanium channel may be provided in order to enhance the mobility of charge carriers in the channel region of a P-channel FET that is to be formed in the PFET area. It is noted that epitaxy may be supplemented by a condensation anneal that drives the Ge atoms into the SOI channel and oxidizes the epitaxial SiGe at the same time.
(15) Another semiconductor layer 104 comprising an upper silicided region 105 is formed over the semiconductor layer 103 of the SOI substrate. A shallow trench isolation (STI) is formed in the semiconductor bulk substrate 101 and a lower portion of the STI is filled with a dielectric layer 106, for example, a flowable oxide material layer. A dielectric buffer layer 107 is formed at a buried insulation level over the dielectric layer 106. The dielectric buffer layer 107 is made of a material different from the one of the dielectric layer 106 and also different from the one of the buried insulation layer 102. The dielectric buffer layer 107 may comprise a nitride material, for example, SiN. In and over the SOI substrate, a FET 108 is formed. The FET 108 comprises source/drain regions 108a, a silicided gate electrode 108b, a gate dielectric 108c and sidewall spacers 108d.
(16) The raised source and drain regions 108a may be formed, for example, by epitaxial growth. The gate electrode 108b may comprise metal gate and polysilicon gate materials. The material of the metal gate may include La, AL or TiN, for example.
(17) The metal gate may include a work function adjusting material, for example, TiN. In particular, the metal may comprise a work function adjusting material that comprises an appropriate transition metal nitride, for example, those from Groups IV-VI in the Periodic Table, including, for example, titanium nitride (TiN), tantalum nitride (TaN), titanium aluminum nitride (TiAlN), tantalum aluminum nitride (TaAlN), niobium nitride (NbN), vanadium nitride (VN), tungsten nitride (WN), and the like, with a thickness of about 1-60 nm. Moreover, the effective work function of the metal gate can be adjusted by added impurities, for example, Al, C or F. Atop of the metal gate, the poly gate may be formed.
(18) The gate electrode 108b is separated from the semiconductor layer 103 of the FDSOI substrate by the gate dielectric 108c. The gate dielectric 108c may comprise a high-k material layer with a dielectric constant k of above 4. The high-k material layer may comprise a transitional metal oxide, such as at least one of hafnium oxide, hafnium dioxide and hafnium silicon-oxynitride, and may be directly formed on the semiconductor layer of the FDSOI substrate.
(19) Contact structures (CA contacts) 109 formed in a dielectric layer 110 electrically contact the raised silicided source/drain regions 108a of the FET 108. It should be noted that a (CB) contact to the gate electrode 108b may also be formed in the dielectric layer 110. The contacts are electrically isolated from each other. The dielectric layer 110 may comprise or consist of a plasma enhanced nitride (PEN) layer. In particular, the dielectric layer 110 may be an interlayer dielectric (ILD). An oxide layer 111 is formed on the dielectric buffer layer 107 in an upper portion of the STI and additional oxide layers 112 are formed between the dielectric buffer layer 107 and the semiconductor bulk substrate 101 outside of the trench of the STI and between the dielectric layer 106 and the semiconductor bulk substrate 101 in the trench of the STI. Furthermore, an oxide layer 112a is formed below the dielectric layer 110.
(20) Different from the art, the dielectric buffer layer 107 formed in the STI protects the semiconductor bulk substrate 101 during the process of etching the contact hole (selective oxide etch) in which the CA contact structure 109 to the source/drain region positioned adjacent to the STI is formed. Since over-etching can be prevented, there is no risk of forming an electrical short to the semiconductor bulk substrate 101 by the contact material filled in the etched contact hole.
(21) The formation of the semiconductor device shown in
(22) As shown in
(23) A photoresist 210 is formed on the mask layer. A bottom anti-reflective coating (BARC) layer (not shown in
(24) A thin oxide layer (not shown) may be formed at sidewalls of the etched recesses and a liner 212 is formed on the thin oxide layer (see
(25) As shown in
(26) In the manufacturing stage shown in
(27) The flowable dielectric fill is followed by a steam anneal. The steam anneal is performed either in the same process chamber used for the deposition of the flowable dielectric material 216 or in another process chamber. The steam anneal results in shrinking and densification of the dielectric material 216. The steam anneal may be performed for some minutes to some hours and at a temperature of some hundred C., for example. The anneal process may be performed at a temperature in a range of about 150-800 C. According to one example, the anneal process may start at about 150 C. and ramp up the temperature gradually to a predetermined temperature of about 500-800 C. The pressure of the anneal process may be in a range of about 500-800 Torr. The flow rate of steam may be in a range of about 1-2 slm (standard-liter per meter). The duration of the steam thermal anneal process may, particularly, be in a range from about 20 minutes to about 2 hours.
(28) As shown in
(29) In the manufacturing stage shown in
(30) Formation of the FET 108 and the contacts 109, etc. may be performed as known in the art to obtain the semiconductor device shown in
(31) Different from the art, the nitride buffer layer formed in the STI (see reference numbers 217a in
(32)
(33) Another semiconductor layer 304 comprising an upper silicided region 305 is formed over the semiconductor layer 303 of the SOI substrate. A lower portion of a shallow trench isolation (STI) formed in the semiconductor bulk substrate 301 is filed with a dielectric layer 306. A dielectric liner 307 is formed in the STI at the levels of the semiconductor bulk substrate 301 and the buried insulation layer 302. The dielectric liner 307 may comprise a nitride material, for example, SiN. A spacer layer 308, for example, a nitride layer, is also formed in the STI. A dielectric material 309, for example, an oxide material, is formed in an upper portion of the STI. In and over the SOI substrate, a FET 310 is formed. The FET 310 comprises source/drain regions 310a, a silicided gate electrode 310b, a gate dielectric 310c and sidewall spacers 310d. CA contacts 311 are formed in a dielectric layer 312, for example, a plasma enhanced nitride layer, for electrically contacting the source/drain regions 310a of the FET 310. In particular, the dielectric layer 312 may be an interlayer dielectric (ILD). An oxide layer 313 is formed below the dielectric layer 312.
(34) Different from the art, the spacer layer 308 formed in the STI protects the semiconductor bulk substrate 301 during the process of etching the contact hole (selective oxide etch) in which the CA contact structure 311 close to the STI is formed. Since over-etching may be prevented, there is no risk of forming an electrical short to the semiconductor bulk substrate 301 by the contact material that is filled in the etched contact hole in order to form the contact 311.
(35) The formation of the semiconductor device shown in
(36) The process flow described above with reference to
(37) In the manufacturing step shown in
(38) As shown in
(39) In the manufacturing stage shown in
(40) In all of the above-described embodiments, the CA contact directly contacts the source/drain region of the FET. It has to be noted, however, that the described process flows may be integrated in the procedure of contacting a source/drain region via a trench silicide (TS) structure. Formation of the TS structures may comprise forming trenches in the dielectric layer 110 of
(41) As a result, the present disclosure provides SOI semiconductor devices comprising FETs with source/drain regions that are reliably contacted without electrical shorts to the semiconductor bulk substrate.
(42) The particular embodiments disclosed above are illustrative only, as the invention may be modified and practiced in different but equivalent manners apparent to those skilled in the art having the benefit of the teachings herein. For example, the process steps set forth above may be performed in a different order. Furthermore, no limitations are intended to the details of construction or design herein shown, other than as described in the claims below. It is therefore evident that the particular embodiments disclosed above may be altered or modified and all such variations are considered within the scope and spirit of the invention. Note that the use of terms, such as first, second, third or fourth to describe various processes or structures in this specification and in the attached claims is only used as a short-hand reference to such steps/structures and does not necessarily imply that such steps/structures are performed/formed in that ordered sequence. Of course, depending upon the exact claim language, an ordered sequence of such processes may or may not be required. Accordingly, the protection sought herein is as set forth in the claims below.