Electronic circuit package using composite magnetic sealing material
10403582 ยท 2019-09-03
Assignee
Inventors
Cpc classification
H01L2924/19105
ELECTRICITY
H01L2224/73204
ELECTRICITY
H01L21/78
ELECTRICITY
H01L21/4853
ELECTRICITY
H01L2924/00012
ELECTRICITY
H01L2224/97
ELECTRICITY
H01L2224/73204
ELECTRICITY
H01L24/97
ELECTRICITY
H01L2224/16225
ELECTRICITY
H01L2924/00012
ELECTRICITY
H01L2224/32225
ELECTRICITY
H01L2224/16225
ELECTRICITY
H01L2224/32225
ELECTRICITY
H01L2224/16235
ELECTRICITY
H01L23/552
ELECTRICITY
H01L2224/97
ELECTRICITY
H01L2224/16227
ELECTRICITY
H01L24/73
ELECTRICITY
International classification
H01L23/52
ELECTRICITY
H01L21/48
ELECTRICITY
H01L23/538
ELECTRICITY
H01L23/552
ELECTRICITY
H01L21/78
ELECTRICITY
Abstract
Disclosed herein is an electronic circuit package includes a substrate having a power supply pattern, an electronic component mounted on a surface of the substrate, and a composite molding member having conductivity that covers the surface of the substrate so as to embed the electronic component and that is connected to the power supply pattern. The composite molding member includes a resin material and a first filler blended in the resin material and containing 32 to 39 wt. % of a metal material composed mainly of Ni in Fe.
Claims
1. An electronic circuit package comprising: a substrate having a power supply pattern; an electronic component mounted on a surface of the substrate; a composite molding member having conductivity that covers the surface of the substrate so as to embed the electronic component, the composite molding member being connected to the power supply pattern, the composite molding member including a resin material and a first filler blended in the resin material, the first filler containing 32 to 39 wt. % of a metal material composed mainly of Ni in Fe; and a metal coating covering a surface of the first filler, the metal coating having a higher conductivity than that of the first filler.
2. The electronic circuit package as claimed in claim 1, wherein the composite molding member further includes a second filler having a smaller size than that of the first filler.
3. The electronic circuit package as claimed in claim 2, wherein a surface of the second filler is covered with a metal coating.
4. The electronic circuit package as claimed in claim 2, wherein the second filler is formed of a magnetic material.
5. The electronic circuit package as claimed in claim 2, wherein the second filler is formed of a conductive material.
6. The electronic circuit package as claimed in claim 2, wherein the second filler is formed of an insulating material.
7. The electronic circuit package as claimed in claim 2, wherein a blending ratio of the first and second fillers in the composite molding member is equal to or higher than 50 vol. % and equal to or lower than 85 vol. %.
8. The electronic circuit package as claimed in claim 2, wherein a blending ratio of the first filler to a total amount of the first and second fillers is equal to or higher than 50 vol. % and equal to or lower than 99 vol. %.
9. The electronic circuit package as claimed in claim 1, further comprising an insulating coating that insulates the electronic component and its terminal electrode from the composite molding member.
10. The electronic circuit package as claimed in claim 1, wherein the composite molding member contacts the power supply pattern exposed to the surface of the substrate.
11. The electronic circuit package as claimed in claim 10, wherein the composite molding member further contacts the power supply pattern exposed to a side surface of the substrate.
12. The electronic circuit package as claimed in claim 1, wherein the composite molding member contacts the power supply pattern exposed to a side surface of the substrate.
13. The electronic circuit package as claimed in claim 1, wherein the substrate includes a side surface having a side surface upper part and a side surface lower part protruding from the side surface upper part, wherein the power supply pattern is exposed to the side surface upper part of the substrate, and wherein the composite molding member covers the side surface upper part of the substrate without covering the side surface lower part of the substrate.
14. The electronic circuit package as claimed in claim 1, further comprising a metal film that covers the composite molding member, the metal film having higher conductivity than that of the composite molding member.
15. The electronic circuit package as claimed in claim 1, further comprising a magnetic film that covers the composite molding member, the magnetic film having higher permeability than that of the composite molding member.
16. The electronic circuit package as claimed in claim 1, wherein the metal material further includes 0.1 to 8 wt. % of Co relative to a total weight of the first filler.
17. The electronic circuit package as claimed in claim 1, wherein a thermal expansion coefficient of the composite molding member is equal to or lower than 15 ppm/ C.
18. The electronic circuit package as claimed in claim 1, wherein a thickness of the composite molding member at a portion above the electronic component is equal to or larger than 50 m.
19. The electronic circuit package as claimed in claim 18, wherein the thickness of the composite molding member at a portion above the electronic component is equal to or larger than 100 m and equal to or smaller than 300 m.
20. An electronic circuit package comprising: a substrate having a power supply pattern; an electronic component mounted on a surface of the substrate; and a composite molding member having conductivity that covers the surface of the substrate so as to embed the electronic component, the composite molding member being connected to the power supply pattern, the composite molding member including: a resin material; a first filler blended in the resin material, the first filler containing 32 to 39 wt. % of a metal material composed mainly of Ni in Fe, and a second filler blended in the resin material, the second filler having a smaller size than that of the first filler.
21. An electronic circuit package comprising: a substrate having a power supply pattern; an electronic component mounted on a surface of the substrate; and a composite molding member having conductivity that covers the surface of the substrate so as to embed the electronic component, the composite molding member being connected to the power supply pattern, wherein the power supply pattern is exposed to the surface of the substrate and wherein the composite molding member contacts the power supply pattern and includes a resin material and a first filler blended in the resin material, the first filler containing 32 to 39 wt. % of a metal material composed mainly of Ni in Fe.
22. An electronic circuit package comprising: a substrate having a power supply pattern; an electronic component mounted on a surface of the substrate; and a composite molding member having conductivity that covers the surface of the substrate so as to embed the electronic component, the composite molding member being connected to the power supply pattern, wherein the composite molding member includes a resin material and a first filler blended in the resin material, the first filler containing 32 to 39 wt. % of a metal material that is composed mainly of Ni in Fe and that includes 0.1 to 8 wt. % of Co relative to a total weight of the first filler.
23. An electronic circuit package comprising: a substrate having a power supply pattern; an electronic component mounted on a surface of the substrate; and a composite molding member having conductivity that covers the surface of the substrate so as to embed the electronic component, the composite molding member being connected to the power supply pattern and having a thermal expansion coefficient equal to or lower than 15 ppm/ C., wherein the composite molding member includes a resin material and a first filler blended in the resin material, the first filler containing 32 to 39 wt. % of a metal material composed mainly of Ni in Fe.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
(1) The above features and advantages of the present invention will be more apparent from the following description of certain preferred embodiments taken in conjunction with the accompanying drawings, in which:
(2)
(3)
(4)
(5)
(6)
(7)
(8)
(9)
(10)
(11)
(12)
(13)
(14)
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DETAILED DESCRIPTION OF THE EMBODIMENTS
(16) Preferred embodiments of the present invention will be explained below in detail with reference to the accompanying drawings.
(17) <First Embodiment>
(18)
(19) As illustrated in
(20) Although the type of the electronic circuit package 11 according to the present embodiment is not especially limited, examples thereof include a high-frequency module handling a high-frequency signal, a power supply module performing power supply control, an SIP (System-In-Package) having a 2.5D structure or a 3D structure, and a semiconductor package for radio communication or digital circuit. Although only two electronic components 31 and 32 are illustrated in
(21) The substrate 20 has a double-sided and multilayer wiring structure in which a large number of wirings are embedded therein and may be any type of substrate including: a thermosetting resin based organic substrate such as an FR-4, an FR-5, a BT, a cyanate ester substrate, a phenol substrate, or an imide substrate; a thermoplastic resin based organic substrate such as a liquid crystal polymer; an LTCC substrate; an HTCC substrate; and a flexible substrate. In the present embodiment, the substrate 20 has a four-layer structure including wiring layers formed on the front surface 21 and a back surface 22 and two wiring layers embedded therein. Land patterns 23 are an internal electrode for connecting to the electronic components 31 and 32. The land patterns 23 and each of the electronic components 31 and 32 are electrically and mechanically connected to each other through a respective solder 24 (or a conductive paste). For example, the electronic component 31 is a semiconductor chip such as a controller, and electronic component 32 is a passive component such as a capacitor or a coil. Some electronic components (e.g., thinned semiconductor chip) may be embedded in the substrate 20.
(22) The land patterns 23 are connected to external terminals 26 formed on the back surface 22 of the substrate 20 through internal wirings 25 formed inside the substrate 20. Upon actual use, the electronic circuit package 11A is mounted on an unillustrated mother board, and land patterns on the mother board and the external terminals 26 of the electronic circuit package 11A are electrically connected. A material for a conductor forming the land patterns 23, internal wirings 25, and external terminals 26 may be a metal such as copper, silver, gold, nickel, chrome, aluminum, palladium, indium, or a metal alloy thereof or may be a conductive material using resin or glass as a binder; however, when the substrate 20 is an organic substrate or a flexible substrate, copper or silver is preferably used in terms of cost and conductivity. The above conductive materials may be formed by using various methods such as printing, plating, foil lamination, sputtering, vapor deposition, and inkjet. In addition, a low-resistance metal such as Au, Pd, Ag, Sn, and the like may be formed on the land patterns 23 by means of plating, spattering, evaporating, and the like, or an antioxidizing film such as CuOSP and the like may be formed on the land patterns 23.
(23) The electronic components 31, 32, and their terminal electrodes and the solders 24 are covered with insulating coatings 51 and 52, respectively, and thereby insulated from the composite molding member 40. Although the insulating coating 51 is provided between the electronic component 31 and the substrate 20 in the example of
(24) As illustrated in
(25) The composite molding member 40 covers the front surface 21 of the substrate 20 so as to embed the electronic components 31 and 32 therein. The composite molding member 40 has a conductivity and high permeability. Thus, the composite molding member 40 serves as an electromagnetic shielding and a magnetic shielding in addition to an ordinary function of a molding member. In the present embodiment, a side surface 42 of the composite molding member 40 and a side surface 27 of the substrate 20 form the same plane. Although details of the composite molding member 40 are described later, the composite molding member 40 is made of a composite material having very small thermal expansion coefficient (equal to or lower than 15 ppm/ C., for example) compared with an ordinary molding material.
(26) The following describes a manufacturing method for the electronic circuit package 11 according to the present embodiment.
(27)
(28) As illustrated in
(29) Then, as illustrated in
(30) Then, as illustrated in
(31) Then, as illustrated in
(32) Then, as illustrated in
(33) Next, a molding material constituting the composite molding member 40 will be described in detail.
(34) The molding material constituting the composite molding member 40 has magnetism and conductivity unlike general molding materials. The composite molding member 40 is connected to the power supply pattern 23G and is thus applied with a fixed potential such as a ground potential. As a result, a composite shielding structure having both a magnetic shielding function and an electromagnetic shielding function can be provided.
(35) The composite molding member 40 includes a binder and a first filler having magnetism and conductivity. Although not especially limited, the resin binder preferably composed mainly of a thermosetting resin material. Specifically, the binder is preferably composed mainly of an epoxy resin, a phenol resin, a urethane resin, a silicone resin, or an imide resin and more preferably uses a base resin and a curing agent used for an epoxy resin-based or a phenol resin-based semiconductor sealing material.
(36) The most preferable is the epoxy resin having a reactive epoxy group at its terminal, which can be combined with various types of curing agents and curing accelerators. Examples of the epoxy resin include a bisphenol A epoxy resin, a bisphenol F epoxy resin, a phenoxy type epoxy resin, a naphthalene type epoxy resin, a multifunctional-type epoxy resin (dicyclopentadiene type epoxy resin, etc.), a biphenyl-type (bifunctional) epoxy resin, and an epoxy resin having a special structure. Among them, the biphenyl type epoxy resin, naphthalene type epoxy resin, and dicyclopentadiene type epoxy resin are useful since they can attain low thermal expansion. Examples of the curing agent or curing accelerator include amine-based compound alicyclic diamine, aromatic diamine, other amine-based compounds (imidazole, tertiary amine, etc.), an acid anhydride compound (high-temperature curing agent, etc.), a phenol resin (novolac type phenol resin, cresol novolac type phenol resin, etc.), an amino resin, dicyandiamide, and a Lewis acid complex compound. For material kneading, known means such as a kneader, three-roll mills, or a mixer may be used.
(37)
(38) The first magnetic filler F1 is formed of an FeNi based material and contains 32 to 39 wt. % of a soft magnetic metal material composed mainly of Ni. The remaining 61 to 68 wt. % is Fe. Such an FeNi based material is called Invar material. Using the Invar material for the first filler F1 can make the thermal expansion coefficient of the composite molding member 40 be equal to or less than, e.g., 15 ppm/ C. and can achieve high magnetic characteristics. The soft magnetic metal material composed of mainly Ni may contain a small amount of Co. That is, a part of Ni may be substituted for Co. The containing of Co enables a further reduction in the thermal expansion coefficient of the composite magnetic sealing material. The adding amount of Co to the total weight of the first filler F1 is preferably 0.1 wt. % or more and 8 wt. % or less.
(39) The shape of the first filler F1 is not especially limited. However, the magnetic filler 6 may preferably be formed into a spherical shape for high packing density. Further, fillers of different particle sizes may be blended as the first filler F1 for closest packing. Further, forming the first filler F1 into a spherical shape or substantially a spherical shape enables a reduction in damage to electronic components during molding. Particularly, for high packing density or closest packing, the shape of the first filler F1 is preferably a true sphere. The first filler F1 preferably has a high tap density and a small specific surface area. As a formation method for the first filler F1, there are known a water atomization method, a gas atomization method, and a centrifugal disc atomization method. Among them, the gas atomization method is most preferable since it can achieve a high tap density and reduce the specific surface area.
(40) The composite molding member 40 may contain, in addition to the first filler F1, a second filler F2a (
(41) The second filler F2a illustrated in
(42) The second filler F2b illustrated in
(43) The second filler F2c illustrated in
(44) The composite material constituting the composite molding member 40 may be a liquid or solid, depending on selection of a base resin and a curing agent according to the molding method therefor. The composite material in a solid state may be formed into a tablet shape for transfer molding and into a granular shape for injection molding or compression molding. The molding method using the composite material may be appropriately selected from among the followings: transfer molding; compression molding; injection molding; cast molding; vacuum cast molding; vacuum printing; printing; dispensing; and a method using a slit nozzle. A molding condition may be appropriately selected from combinations of the base resin, curing agent and curing accelerator to be used. Further, after-cure treatment may be applied as needed after the molding.
(45) As described above, in the electronic circuit package 11 according to the present embodiment, the composite molding member 40 has conductivity, so that the composite molding member 40 itself functions as an electromagnetic shield for the electronic circuit package 11. As a result, electromagnetic waves emitted from the electronic components 31 and 32 or electromagnetic waves coming from the outside are converted into a current inside the composite molding member 40 to be made to flow outside through the power supply pattern 23G. Further, the first filler F1 contained in the composite molding member 40 is formed of an Invar material, it is therefore possible to prevent warpage of the substrate, interfacial peeling in the molding material, cracking of the molding material, and the like due to a temperature change while ensuring magnetic shielding characteristics.
(46) <Second Embodiment>
(47)
(48) As illustrated in
(49) In the electronic circuit package 12 according to the present embodiment, the power supply pattern 25G exposed to the side surface 27 of the substrate 20 and the composite molding member 40 contact each other, so that the power supply pattern 23G need not be exposed to the surface 21 of the substrate 20. As a result, for example, the insulating coatings 51 and 52 can be formed on the entire surface of the surface 21 of the substrate 20, thereby simplifying the manufacturing process.
(50) The electronic circuit package 12 according to the present embodiment can be manufactured by cutting the aggregate substrate 20A into individual substrates 20 and then forming the composite molding member 40 on the upper and side surfaces 21 and 27 of the substrate 20.
(51) <Third Embodiment>
(52)
(53) As illustrated in
(54) In the electronic circuit package 13 according to the present embodiment, the power supply pattern 25G exposed to the side surface upper part 27a of the substrate 20 and the composite molding member 40 contact each other, so that the power supply pattern 23G need not be exposed to the surface 21 of the substrate 20. As a result, as in the second embodiment, the insulating coatings 51 and 52 can be formed on the entire surface of the surface 21 of the substrate 20, thereby simplifying the manufacturing process.
(55) The electronic circuit package 13 according to the present embodiment can be manufactured by forming a groove constituting the side surface upper part 27a in the aggregate substrate 20A, then forming the composite molding member 40 in the upper surface 21 of the substrate 20 so as to fill the groove therewith, and afterwards cutting the aggregate substrate 20A into individual substrates 20.
(56) <Fourth Embodiment>
(57)
(58) As illustrated in
(59) In the electronic circuit package 14 according to the present embodiment, the composite molding member 40 is connected to the power supply patterns 23G and 25G at both the upper and side surfaces 21 and 27 of the substrate 20, so that it is possible to make the potential (typically, a ground potential) of the composite molding member 40 more stable than in the electronic circuit package 12 according to the second embodiment.
(60) <Fifth Embodiment>
(61)
(62) As illustrated in
(63) In the electronic circuit package 15 according to the present embodiment, the composite molding member 40 is connected to the power supply patterns 23G and 25G at both the upper surface 21 and the side surface upper part 27a of the substrate 20, so that it is possible to make the potential (typically, a ground potential) of the composite molding member 40 more stable than in the electronic circuit package 13 according to the third embodiment.
(64) <Sixth Embodiment>
(65)
(66) As illustrated in
(67) The power supply pattern 29G is a dedicated pattern for applying a fixed potential to the composite molding member 40. The power supply pattern 29G is not connected to the land patterns 23 and wirings on the upper surface 21 of the substrate 20 but independently provided. The power supply pattern 29G is applied, through the internal wiring 25 formed inside the substrate 20, with a fixed potential same as that applied to the power supply pattern 23G. As exemplified in the present embodiment, as a power supply pattern for applying a fixed potential to the composite molding member 40, not only the power supply pattern 23G led out from the land pattern 23, but also the independent dedicated power supply pattern 29G can be used. With this configuration, it is possible to make the potential (typically, a ground potential) of the composite molding member 40 more stable.
(68) <Seventh Embodiment>
(69)
(70) As illustrated in
(71) The metal film 60 serves as an electromagnetic shielding as well as the composite molding member 40 and is preferably mainly composed of at least one metal selected from a group consisting of Au, Ag, Cu, and Al. The metal film 60 preferably has a resistance as low as possible and most preferably uses Cu in terms of cost. It is necessary that the resistivity of the metal film 60 is lower than at least the resistivity of the composite molding member 40. An outer surface of the metal film 60 is preferably covered with an anticorrosive metal such as SUS, Ni, Cr, Ti, or brass or an antioxidant film made of a resin such as an epoxy resin, a phenol resin, an imide resin, an urethane resin, or a silicone resin. The reason for this is that the metal film 60 undergoes oxidative deterioration by an external environment such as heat or humidity; and, therefore, the aforementioned treatment is preferable to suppress and prevent the oxidative deterioration. A formation method for the metal film 60 may be appropriately selected from known methods, such as a sputtering method, a vapor-deposition method, an electroless plating method, an electrolytic plating method. Before formation of the metal film 60, pretreatment for enhancing adhesion, such as plasma treatment, coupling treatment, blast treatment, or etching treatment, may be performed. As a base of the metal film 60, a high adhesion metal film such as a titanium film, a chromium film, or an SUS film may be formed thinly in advance.
(72) As described above, the electronic circuit package 17 according to the present embodiment includes the metal film 60 connected to the power supply pattern 25G, so that it is possible to make the potential (typically, a ground potential) of the composite molding member 40 more stable than in the electronic circuit package 11 according to the first embodiment.
(73) <Eighth Embodiment>
(74)
(75) As illustrated in
(76) The magnetic film 70 is a film formed of a composite magnetic material in which magnetic fillers are dispersed in a thermosetting resin material, a thin film formed of a soft magnetic material or a ferrite, or a foil or a bulk sheet and serves as a second magnetic shield. The effective permeability of the magnetic film 70 needs to be higher than that of the composite molding member 40 and is preferably twice or more higher than it.
(77) When a film formed of a composite magnetic material is selected as the magnetic film 70, an epoxy resin, a phenol resin, a silicone resin, a diallyl phthalate resin, a polyimide resin, an urethane resin, and the like may be used as the thermosetting resin material, and the magnetic film 70 can be formed by using a thick-film formation method such as a printing method, a molding method, a slit nozzle coating method, a spray method, a dispensing method, an injection method, a transfer method, a compression molding method, or a lamination method using an uncured sheet-like resin. Using the thermosetting resin material can enhance reliability required for electronic circuit packages such as heat resistance, insulating performance, impact resistance, falling resistance, and the like.
(78) As the magnetic filler, a ferrite or a soft magnetic metal is preferably used, and a soft magnetic metal having a high bulk permeability is more preferably used. As the ferrite or soft magnetic metal, one or two or more metals selected from a group consisting of Fe, Ni, Zn, Mn, Co, Cr, Mg, Al, and Si and oxides thereof may be exemplified. As specific examples, a ferrite such as an NiZn ferrite, an MnZn ferrite, an NiCuZn ferrite, a permalloy (FeNi alloy), a super permalloy (FeNiMo alloy), a sendust (FeSiAl alloy), an FeSi alloy, an FeCo alloy, an FeCr alloy, an FeCrSi alloy, an FeNiCo alloy, and Fe, and the like may be exemplified. The shape of the magnetic filler is not particularly limited; however, it may be formed into a spherical shape for a high filling level, and fillers having a plurality of different particle size distributions may be blended or combined for a densest filling structure. In order to maximize a shield effect by a permeability real component and a thermal conversion effect of a loss by a permeability imaginary component, it is more preferable to form the magnetic filler by making flat powder having an aspect ratio of 5 or more orientate.
(79) The surface of the magnetic filler is insulation-coated by an oxide of a metal such as Si, Al, Ti, or Mg, or an organic material for enhancing fluidity and adhesion. For the insulating coating, an oxide film may be formed by coating a thermosetting material on the surface of the magnetic filler or dehydration reaction of a metal alkoxide, and formation of a silicon oxide coating film is most preferable. It is more preferable to apply an organofunctional coupling treatment on the coating film thus formed.
(80) The composite magnetic material can be formed on the upper surface 41 of the composite molding member 40 using a known method such as a printing method, a molding method, a slit nozzle coating method, a spray method, a dispensing method, or a lamination method using an uncured sheet-like resin.
(81) When the thin film formed of a soft magnetic material or a ferrite is selected as the magnetic film 70, one or two or more metals selected from a group consisting of Fe, Ni, Zn, Mn, Co, Cr, Mg, Al, and Si and oxides thereof may be used. In this case, the magnetic film 70 can be formed on the upper surface 41 of the composite molding member 40 by using a plating method, a spray method, an AD method, and a thermal spraying method, as well as a thin-film formation method such as a sputtering method or a vapor-deposition method. In this case, the material for the magnetic film 70 may be appropriately selected based on a required permeability and frequency; however, in order to enhance a shield effect on a lower frequency side (kHz to 100 MHz), an alloy of FeCo, FeNi, FeAl, or FeSi is most preferably used. On the other hand, in order to enhance a shield effect on a higher frequency side (50 to several hundreds of MHz), a ferrite film formed of NiZn, MnZn, or NiCuZn, or Fe is most preferably used.
(82) When a foil or a bulk sheet is used as the magnetic film 70, it is possible to directly form the magnetic film 70 consisting of a foil or a bulk sheet on the upper surface 41 of the composite molding member 40 by previously setting the foil or bulk sheet in a mold for forming the composite molding member 40.
(83) As described above, in the electronic circuit package 18 according to the present embodiment, the magnetic film 70 having a higher permeability than that of the composite molding member 40 is formed on the upper surface 41 of the composite molding member 40, so that magnetic shielding characteristics can be further enhanced. Further, as exemplified by an electronic circuit package 18A shown in
(84) <Ninth Embodiment>
(85)
(86) As illustrated in
(87) In the electronic circuit package 19 according to the present embodiment, the surface of the composite molding member 40 serving as an electromagnetic shield and a magnetic shield is covered with the metal film 60 serving as an electromagnetic shield and the magnetic film 70 serving as a magnetic shield, so that it is possible to further enhance electromagnetic shielding characteristics and magnetic shielding characteristics.
(88) While the preferred embodiments of the present invention have been described, the present invention is not limited thereto. Thus, various modifications may be made without departing from the gist of the invention, and all of the modifications thereof are included in the scope of the present invention.
EXAMPLES
(89) First filler F1 having a median diameter (D50) of 10 m and second filler F2c having a median diameter (D50) of 0.7 m were prepared. The first filler F1 was formed of an Invar material with 64 wt. % of Fe and 36 wt. % of Ni, and an Ag having 50 nm thickness was plated on the surface thereof. The second filler F2c was formed of a heat resistant resin, and Ag having a thickness of 80 nm was plated on the surface thereof.
(90) Then, a biphenyl type epoxy resin, a phenol novolac type curing agent, and a catalyst (imidazole) were dissolved in butyl carbitol to prepare a binder. The above first filler F1 and second filler F2c were put into the binder, followed by stirring and kneading in a kneader, to obtain a pasty composite sealing material. The blending ratios of the first filler F1, second filler F2c, and binder in the composite sealing material were 50 vol. %, 25 vol. %, and 25 vol. %, respectively.
(91) Then, samples 1 to 3 having the same structure as that of the electronic circuit package 11 illustrated in
(92) After the post-curing, the upper surface 41 of the composite molding member 40 was ground by a grinder for thickness adjustment. The thicknesses (t) of the composite molding member 40 at a portion above the highest electronic component were set to 100 m, 200 m, and 300 m in the samples 1, 2, and 3, respectively.
(93) As a comparative example, in place of the above composite molding member, a general molding material having neither magnetism nor conductivity was used for molding, and then a Cu film of a 6 m thickness was formed on the surface of the obtained molding member by a sputtering method, whereby a comparative sample was obtained. The Cu film was connected to a ground pattern.
(94) Then, the above samples were each reflow-mounted on a characteristic evaluation substrate, and a neighboring magnetic field measuring apparatus was used to measure a noise attenuation amount for evaluation of shielding characteristics. The results are illustrated in
(95) As illustrated in