Metal-insulator-metal (MIM) capacitor
11545428 · 2023-01-03
Assignee
Inventors
Cpc classification
H01L2924/00012
ELECTRICITY
H01L2224/034
ELECTRICITY
H01L23/53238
ELECTRICITY
H01L2224/034
ELECTRICITY
H01L2224/03848
ELECTRICITY
H01L2224/0603
ELECTRICITY
H01L21/76816
ELECTRICITY
H01L28/75
ELECTRICITY
H01L2224/039
ELECTRICITY
H01L2224/0557
ELECTRICITY
H01L2924/00014
ELECTRICITY
H01L2224/05568
ELECTRICITY
H01L2224/039
ELECTRICITY
H01L2224/05186
ELECTRICITY
H01L2224/05186
ELECTRICITY
H01L2224/05022
ELECTRICITY
H01L2924/00014
ELECTRICITY
H01L2924/00012
ELECTRICITY
H01L2224/03848
ELECTRICITY
International classification
H01L23/522
ELECTRICITY
H01L21/768
ELECTRICITY
Abstract
A method of forming a metal-insulator-metal (MIM) capacitor with copper top and bottom plates may begin with a copper interconnect layer (e.g., Cu MTOP) including a copper structure defining the capacitor bottom plate. A passivation region is formed over the bottom plate, and a wide top plate opening is etched in the passivation region, to expose the bottom plate. A dielectric layer is deposited into the top plate opening and onto the exposed bottom plate. Narrow via opening(s) are then etched in the passivation region. The wide top plate opening and narrow via opening(s) are concurrently filled with copper to define a copper top plate and copper via(s) in contact with the bottom plate. A first aluminum bond pad is formed on the copper top plate, and a second aluminum bond pad is formed in contact with the copper via(s) to provide a conductive coupling to the bottom plate.
Claims
1. A metal-insulator-metal (MIM) capacitor device, comprising: a copper bottom plate defined in a portion of a copper interconnect layer; a dielectric layer formed over the copper bottom plate; a copper top plate and at least one copper bottom plate contact via formed in a passivation layer, wherein the copper top plate is formed over the dielectric layer; a planarized surface defining a planarized top surface of the copper top plate and a planarized top surface of each copper bottom plate contact via; and a bond pad layer formed on the planarized top surface of the copper layer and including: a top plate bond pad formed on the planarized top surface of the copper top plate; and a bottom plate bond pad formed on the planarized top surface of each copper bottom plate contact via and conductively coupled to the bottom plate bond pad by the at least one copper bottom plate contact via.
2. The MIM capacitor device of claim 1, wherein the top plate bond pad is formed directly onto the copper top plate.
3. The MIM capacitor device of claim 1, wherein in a horizontal plane extending through the MIM capacitor device, a lateral width of the copper top plate is greater than 1 μm, and a lateral width of each copper bottom plate contact via is less than 1 μm.
4. The MIM capacitor device of claim 1, wherein in a horizontal plane extending through the MIM capacitor device, a lateral width of the copper top plate is greater than 2 μm, and a lateral width of each copper bottom plate contact via is less than 1 μm.
5. The MIM capacitor device of claim 1, wherein in a horizontal plane extending through the MIM capacitor device, a lateral width of the copper top plate is in the range of 1-10 μm, and a lateral width of each capper-via copper bottom plate contact via is less than 1 μm.
6. The MIM capacitor device of claim 1, wherein in a horizontal plane extending through the MIM capacitor device, a lateral width of the copper top plate is in the range of 2-3 μm, and a lateral width of each copper bottom plate contact via is less than 0.5 μM.
7. The MIM capacitor device of claim 1, wherein the top plate bond pad and the bottom plate bond pad comprise aluminum bond pads.
8. The MIM capacitor device of claim 1, wherein the copper top plate, and the at least one copper bottom plate contact via comprise portions of the same copper layer or deposition in the passivation layer.
9. The MIM capacitor device of claim 1, wherein the copper top plate and the at least one copper bottom plate contact via are formed concurrently.
10. The MIM capacitor device of claim 1, wherein the copper top plate and the at least one copper bottom plate contact via are formed in openings in a passivation region formed over the copper bottom plate.
11. The MIM capacitor device of claim 1, wherein: the copper top plate is formed over a first region of the copper bottom plate, and the at least one copper bottom plate contact via is formed over a second region of the copper bottom plate.
12. The MIM capacitor device of claim 1, wherein the copper interconnect layer defining the copper bottom plate comprises a portion of a top-most copper layer of an integrated circuit device.
13. The MIM capacitor device of claim 1, wherein each of the copper top plate and the copper bottom plate has a thickness providing a sheet resistance of less than 100 milliohms per square.
14. The MIM capacitor device of claim 1, wherein the dielectric layer comprises a SiN layer having a thickness in the range of 400 Å-1000 Å.
15. The MIM capacitor device of claim 1, wherein the dielectric layer comprises at least one upwardly turning corner at a transition from a laterally-extending bottom region of the dielectric layer to a vertically-extending sidewall of the dielectric layer.
16. The MIM capacitor device of claim 1, wherein: the dielectric layer has a bowl-shape including at least one sidewall portion extending up from a bottom portion; the top plate bond pad fully covers the planarized top surface of the copper top plate; and the copper top plate is fully enclosed by the bowl-shaped dielectric layer and the top plate bond pad.
17. The MIM capacitor device of claim 1, wherein the dielectric layer does not extend laterally outside the top plate opening.
18. An integrated circuit device, comprising: a plurality of electronic devices; and a copper interconnect layer; a passivation layer formed over the copper interconnect laver; a top plate opening, at least one bottom plate contact via opening, and at least one interconnect via opening formed in the passivation laver; a bond pad layer formed over the passivation laver; an interconnect structure including: a copper interconnect element formed in the copper interconnect laver; at least one copper interconnect via formed in the at least one interconnect via opening in the passivation laver; and an interconnect bond pad formed in the bond pad laver; and a metal-insulator-metal (MIM) capacitor device, comprising: a copper bottom plate formed in the copper interconnect layer and laterally spaced apart from the copper interconnect element; a dielectric layer formed in the top plate opening in the passivation layer over the copper bottom plate; a copper top plate formed over the dielectric layer in the top plate opening in the passivation laver; at least one bottom plate contact via formed in the at least one bottom plate contact via opening in the passivation laver; a top plate bond pad formed in the bond pad layer and formed on the copper top plate; and a bottom plate bond pad formed in the bond pad layer and formed on the at least one copper bottom plate contact via, the bottom plate bond pad conductively coupled to the bottom plate bond pad by the at least one copper bottom plate contact via.
19. The integrated circuit device of claim 18, wherein in a horizontal plane extending through the MIM capacitor device, a lateral width of the copper top plate is greater than 1 μm, and a lateral width of each copper bottom plate contact via is less than 1 μm.
20. The integrated circuit device of claim 18, wherein in a horizontal plane extending through the MIM capacitor device, a lateral width of the copper top plate is in the range of 2-10 μm, and a lateral width of each copper bottom plate contact via is less than 1 μm.
21. The integrated circuit device of claim 18, wherein the dielectric layer comprises at least one upwardly turning corner at a transition from a laterally-extending bottom region of the dielectric layer to a vertically-extending sidewall of the dielectric layer, wherein the at least one upwardly turning corner of the dielectric layer improves the break-down voltage of the MIM capacitor device.
22. The integrated circuit device of claim 18, comprising a planarized surface defining a planarized top surface of the copper top plate and a planarized top surface of each copper bottom plate contact via; wherein the top plate bond pad is formed on the planarized top surface of the copper top plate.
23. The integrated circuit device of claim 18, wherein: the dielectric layer has a bowl-shape including at least one sidewall portion extending up from a bottom portion; the top plate bond pad fully covers a top surface of the copper top plate; and the copper top plate is fully enclosed by the bowl-shaped dielectric layer and the top plate bond pad.
Description
BRIEF DESCRIPTION OF THE FIGURES
(1) A more complete understanding of the present disclosure may be acquired by referring to the following description taken in conjunction with the accompanying drawings wherein:
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(11) It should be understood that the reference number for any illustrated element that appears in multiple different figures has the same meaning across the multiple figures, and the mention or discussion herein of any illustrated element in the context of any particular figure also applies to each other figure, if any, in which that same illustrated element is shown.
DETAILED DESCRIPTION
(12) Embodiments of the present invention provide an MIM capacitor and methods of forming an MIM capacitor (along with an integrated circuit device including an MIM capacitor) having a wide copper top plate and a copper bottom plate contacted by narrow copper via(s). The copper top plate and copper via(s) are formed concurrently, by concurrently filing a wide top plate opening (e.g., 2-10 μm width or diameter) and narrow via opening(s) (e.g., 0.1-0.5 μm width or diameter) with copper, e.g., using a single damascene copper deposition. Aluminum (Al) bond pads may be formed over the MIM capacitor, with a first Al bond pad formed on the copper top plate, and a second Al bond plate formed on the copper contact via(s) to provide a conductive contact to the copper bottom plate.
(13) As discussed above, forming copper vias, instead of conventional tungsten vias, allows the wide top plate opening and narrow bottom plate contact via(s) to be formed concurrently (e.g., using a single damascene copper deposition), due to the advantageous fill characteristics of copper for this purpose, as compared with the conventional use of tungsten. For example, as discussed above, deposited tungsten forms a conformal layer, and is thus not effective for concurrently filling wide openings (e.g., >1 μm width or diameter) and narrow openings (e.g., <1 μm width or diameter). In contrast, deposited copper may fill open volumes in a bottom-up manner, and thus may concurrently fill both wide openings and narrow openings effectively.
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(15) Tungsten CVD such as shown in
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(17) The inventor has conceived of forming an MIM capacitor having a wide top plate opening and narrow via opening(s) by using copper or other metal suitable to fill such openings in a bottom-up manner, e.g., nickel or cobalt, rather than a conformal manner as with tungsten.
(18) As discussed above, forming copper vias, instead of conventional tungsten vias, allows the wide top plate opening and narrow via opening(s) to be formed concurrently (e.g., using a single damascene copper deposition). Deposited copper advantageously may fill open volumes in bottom-up manner, and thus may concurrently fill both wide openings and narrow openings effectively.
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(20) In some embodiment, the bottom-up filling is achieved by adding organic additives into the electrochemical copper plating solution to suppress the plating rate on the surface of the wafer, while enhancing the plating rate within the openings. In some embodiments, the bottom-up copper fill may be further improved by optimizing the organic additives, such as accelerators, suppressors, and/or levelers, in the copper electrochemical plating solution or plating bath.
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(22) Then, as shown in
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(24) First, as shown in
(25) Next, as shown in
(26) Next, as shown in
(27) Next, as shown in
(28) The via openings 746A and 746B, along with the top plate opening 720, may then be filled with copper, e.g., using a single damascene copper deposition process, which may include (a) depositing a barrier layer and copper seed layer, (b) performing a copper electrochemical plating, (c) performing a copper anneal, and (d) performing a copper CMP, as discussed below.
(29) In this example embodiment, a barrier layer and a seed layer are first deposited into the openings, followed by copper electrochemical plating to fill the openings, e.g., as shown in
(30) Once the bottom plate contact via openings 746B and top plate opening 720 are filled with copper 754 to form copper bottom plate contact vias 760B and copper top plate 762, a MIM capacitor 780 is defined, wherein the second Cu MTOP structure 702B defines the capacitor bottom plate, the copper top plate 762 forms the capacitor top plate, and copper bottom plate 702B is separated from the copper top plate 762 by the dielectric layer 730. The copper bottom plate contact vias 760B are in contact with the copper bottom plate 702B, for connecting the copper bottom plate 702B to an overlying bond pad. The copper top plate 762 may be subsequently contacted by a top plate bond pad formed directly on the copper top plate 762, and the copper bottom plate 702B may be contacted by a bottom plate bond pad conductively coupled to the copper bottom plate 702B by the copper bottom plate contact vias 760B, as discussed below.
(31) In some embodiments, the deposited copper 754 may then be annealed, for example in a furnace for 30-105 min at a temperature of 200° C. A copper CMP (chemical mechanical planarization) may then be performed to planarize the structure at least down to the top surface of the passivation region 704 (or partially into the thickness of passivation region 704), thereby removing upper portions of the deposited copper 754, barrier layer 750, and dielectric layer 730. The resulting structure after the CMP is shown in
(32) Finally, as shown in
(33) The deposited aluminum bond pad stack may then be patterned and etched to define (a) a first bond pad 770A formed over copper vias 760A for conductive coupling to the first Cu MTOP structure 702A, and (b) a pair of bond pads for the MIM capacitor 780: in particular, a top plate bond pad 770B formed directly over the copper top plate 762, and a bottom plate bond pad 770C formed over copper vias 760B for conductive coupling to the copper bottom plate 702B.
(34) As shown in
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(36) Additional Al bond pad(s) 840C are formed over copper interconnect via(s) 824 of the copper interconnect structure 806, which may extend multiple layers downward into the device structure.
(37) In some embodiments, the copper top plate 812 and copper via(s) 816 of the MIM capacitor 802, along with copper interconnect via(s) 824 are formed in a common passivation layer 826 by concurrently filling a wide “tub” opening for the top plate 812 and narrow via openings, using a single damascene copper via process. This concurrent forming of the capacitor top plate and vias may reduce processing steps (and thus time and cost), e.g., as compared with a process in which an MIM capacitor is formed separately from interconnect vias of the respective integrated circuit device. Each copper element, e.g., the MIM capacitor top plate 812, bottom plate 810, and via(s) 816, along with elements of the copper interconnect structure 806, may be formed over a metallic barrier layer (e.g., Ta/Tan) 830 deposited before the respective copper element.
(38) Using copper for the interconnect vias may allow both the tub style top plate opening and narrow via openings to be filled concurrently by a bottom-up copper fill, as discussed above. This is generally not possible using tungsten, due to the conformal nature of tungsten deposits. Further, both the copper top plate and copper bottom plate of the MIM capacitor 802 may be thick, which may significantly reduce parasitic series resistance and thus the performance of the capacitor, e.g., as compared with capacitors using only via connections to contact both the top and bottom plates (as shown in
(39) In some embodiments, the vertical thickness of the top plate and/or bottom plate is at least 0.3 μm, e.g., in the range of 0.3 μm to 2.0 μm. In some embodiments, the copper top plate 812 may have a diameter or width in the range between 1 μm and 100 μm, e.g., in the range of 1-5 μm. In one example embodiment, the copper top plate 812 may have a diameter or width in the range of 2-3 μm.
(40) In some embodiments, the top plate sheet resistance is below 100 milliohms per square, e.g., in the range of 8-100 milliohms per square, which is substantially lower (e.g., by at least 2 or 3 orders of magnitude) than resistance provided by via connections of conventional designs. Each of the copper top plate 812 and copper bottom plate 812 may have any cross-sectional shape, e.g., square, rectangular, circular, or oval.