DEVICE FOR IDENTIFYING A DIAMOND

Abstract

A diamond identification apparatus relates to the field of examining natural and synthetic diamonds. The claimed apparatus for identifying a cut diamond comprises a measurement location with a measuring aperture at which the cut diamond to be examined is fixedly positioned; a movable optical system including a spectrometer, two sources of radiation at wavelengths of 250-280 nm and 350-380 nm, respectively, said two sources of radiation and the spectrometer being connected to the measurement location by optical fibres for inputting radiation into the cut diamond and by an optical fibre for outputting radiation from the cut diamond; and also a source of laser radiation at a wavelength of 532 nm and a microcontroller, wherein the cut diamond is positioned at the measurement location in such a way that the table of the diamond faces the measuring aperture of the measurement location, and the culet of the diamond is situated directly above the measuring aperture to which the optical fibres for inputting radiation and the optical fibre for outputting radiation are connected, and wherein the microcontroller is configured to control the alternate operation of the sources of radiation in a set time sequence, the movement of the optical system to allow the input of radiation into the cut diamond, and the processing of the spectrometer data.

Claims

1. An apparatus for identifying a cut diamond, comprising a measurement location with a measuring aperture at which the cut diamond to be examined is fixedly positioned; a movable optical system including a spectrometer, two sources of radiation with wavelengths of 250-280 nm and 350-380 nm, respectively, said two sources of radiation and the spectrometer being connected to the measurement location by optical fibres for inputting radiation into the cut diamond and by an optical fibre for outputting radiation from the cut diamond; and also a source of laser radiation with a wavelength of 532 nm, and a microcontroller, wherein the cut diamond is positioned at the measurement location in such a way that the table of the diamond faces the measuring aperture of the measurement location and the culet of the diamond is directly above the measuring aperture to which the optical fibres for inputting radiation and the optical fibre for outputting radiation are led, and wherein the microcontroller is configured to control alternate operation of the sources of radiation in a set time sequence, movement of the optical system to allow the input of radiation into the cut diamond, and also processing of the spectrometer data.

2. The apparatus according to claim 1, wherein the optical fibre for outputting radiation comprises two optical fibre segments optically coupled to each other by two collimating lenses.

3. The apparatus according to claim 1, wherein the optical system is configured to be movable such that the optical fibres for inputting and outputting radiation from the source of radiation with wavelengths of 250-280 nm come into direct contact with a surface of the cut diamond.

4. The apparatus according to claim 1, wherein the optical system is configured to be movable such that a gap of 1-2 mm size is formed between the optical fibres for inputting and outputting radiation from the source of radiation with wavelengths of 350-380 nm.

5. The apparatus according to claim 1, wherein the source of laser radiation is adapted for directing the laser radiation to the surface of the cut diamond through said gap.

6. The apparatus according to claim 5, further comprising a mirror mounted between the source of laser radiation and the cut diamond, wherein the directing of said laser radiation to the surface of the cut diamond is provided by said mirror.

7. The apparatus according to claim 4, wherein the optical system further comprises a notch filter adapted to be arranged between two collimating lenses to attenuate the radiation intensity from the sources of radiation.

8. The apparatus according to claim 7, wherein the notch filter is provided with a moving input/output mechanism for removing the filter from a radiation optical path when optical radiation is output from the source of radiation with wavelengths of 250-280 nm.

9. The apparatus according to claim 1, wherein the measuring aperture is formed in a central region of the measurement location for supplying the radiations to the surface of the diamond.

10. The apparatus according to claim 8, wherein the microcontroller is further configured to control the input/output mechanism for removing the notch filter from the radiation optical path.

11. The apparatus according to claim 4, further comprising a mirror mounted between the source of laser radiation and the cut diamond, wherein the directing of said laser radiation to the surface of the cut diamond is provided by said mirror.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

[0021] FIG. 1 shows a schematic diagram of the diamond identification apparatus when obtaining spectra of Raman scattering (RSS) and photoluminescence.

[0022] FIG. 2 shows a schematic diagram of the diamond identification apparatus when obtaining transmission spectra in the range of 250-280 nm.

[0023] FIG. 3 shows a diamond RSS spectrum with a characteristic line at 1332 cm.sup.?1.

[0024] FIG. 4 shows a photoluminescence spectrum of a natural diamond with a 415 nm line.

[0025] FIG. 5 shows a transmission spectrum typical for Type IIa diamonds.

DESCRIPTION OF EMBODIMENTS

[0026] FIG. 1 shows a schematic diagram of an apparatus for identifying a diamond 1 mounted at a measurement location 2 with a locking device (not shown) for centering a cut diamond (brilliant) relative to a measuring aperture formed in the center of the measurement location 2 for supplying radiations to a surface of the diamond. Meanwhile, the diamond is mounted at said measurement location 2 such that the diamond covers said aperture. Three optical fibres are used in the apparatus. One optical fibre 3 for outputting radiation is connected to a spectrometer 6 and consists of two segments optically coupled therebetween by two collimating lenses 4 forming parallel beams from the radiations passing through one of the segments of the optical fibre 3. An optical notch filter 5 can be interposed between the collimating lenses 4, which filter is configured to reduce by six orders of magnitude the intensity of a laser radiation with wavelength of 532 nm and by four orders of magnitude the intensity of a broadband radiation of 350-380 nm. Two other optical fibres 11 and 13 for inputting radiation are configured to input into the diamond the broadband radiations of 350-380 nm from a radiation source 10 in the form of a LED to excite photoluminescence, and of 250-280 nm from a radiation source 12 in the form of a LED 13 to measure absorption in the diamond. To excite the Raman scattering, a source of laser radiation (a compact solid-state laser) 7 with a wavelength of 532 nm is used in the apparatus. A focused laser radiation 8 generated by the laser radiation source 7 is directed by a mirror 9 to the sample being examined (cut diamond 1). A notch filter input/output device 14 is shown by a dashed line in FIG. 1. The input/output device represents an electric motor and is controlled by a microcontroller (not shown).

[0027] An optical system 15 (shown by a dashed line in FIGS. 1 and 2) includes a spectrometer 6, the radiation sources 10, 12 with the optical fibres (3, 11, 13) for inputting and outputting radiation, and is configured to be movable, e.g. by a moving device in the form of a movable platform (not shown) on which the above-mentioned elements of the diamond identification apparatus are mounted.

[0028] FIG. 2 shows an arrangement embodiment of the diamond identification apparatus when measuring the absorption of short-wave ultraviolet radiation (250-280 nm) in the diamond, which differs from the embodiment of the diamond identification apparatus of FIG. 1 in that the optical fibres 3, 11 and 13 contact the surface of the cut diamond (brilliant), and the notch filter 5 is removed from the optical path of the radiation under analysis. Direct contact of the optical fibres with the diamond makes it possible to detect even weak signals.

[0029] The Diamond Identification Apparatus Works in the Following Manner.

[0030] In a first examination step, it is verified whether the sample being examined is a diamond, wherein the sample of a cut diamond (brilliant) 1 is positioned onto the measurement location 2 and is fixed with its table towards the measuring aperture such that the culet is directly above the measuring aperture, strictly midway between the optical fibres for inputting and outputting radiation (FIG. 2). Here, responsive to a signal from the microcontroller (not shown), the entire optical system 15 including the radiation sources 10, 12, the three optical fibres for inputting and outputting radiation, the spectrometer 6, the collimating lenses 4 and the notch filter 5 is moved by the moving device so as to form a gap of 1-2 mm between the optical fibres for inputting and outputting radiation and the cut diamond 1 for passing the laser radiation from the laser radiation source 7 initiated by a signal from the microcontroller (FIG. 1). The compact solid-state laser with a wavelength of 532 nm is used as the laser radiation source for obtaining a Raman scattering spectrum. The laser radiation source 7 generates a focused beam 8 responsive to a signal of the microcontroller, which beam is directed using the mirror 9 to the cut diamond (brilliant). Here, the mirror 9 is disposed between the laser radiation source 7 and the diamond 1. The notch filter 5 attached to a supplementary filter input/output moving mechanism 14 is inserted between the collimating lenses 4 disposed between the two optical fibre segments, which filter reduces the intensity of the scattered laser radiation from the sample at the wavelength of 532 nm by the 6 orders of magnitude.

[0031] A resulting spectrum of the sample (diamond) being examined is shown in FIG. 3. The presence of a characteristic diamond line, 1332 cm (572.6 nm), indicates that the sample being examined is a diamond.

[0032] It should be noted that controlling the radiation sources (turning on/off), the notch filter input/output device, the movement of the optical system, and also a process of processing the spectrometer data are performed by the microcontroller. The spectrometer measurement results are processed in the microcontroller and results of identification of the cut diamonds are output on an electronic display (not shown) connected to the microcontroller.

[0033] In a second examination step, it is verified whether the sample being examined is a natural diamond. Here, the second examination step is performed in the same optical circuit shown in FIG. 1, when responsive to a signal from the microcontroller (not shown), the entire optical system 15 including the radiation sources 10, 12, the three optical fibres for inputting and outputting radiation, the spectrometer 6, the collimating lenses 4 and the notch filter 5 is moved by the moving device so as to form a gap of 1-2 mm between the optical fibres for inputting and outputting radiation and the cut diamond 1 for passing the broadband radiation from the radiation source 10 initiated by a signal of the microcontroller (FIG. 1).

[0034] In order to determine whether the diamond is natural, a technique for analyzing the diamond luminescence at a wavelength of 415 nm (optically active N3 center) is used. To excite luminescence, the radiation source 10 in the form of a LED having an emission band within the range of 350-380 nm is used to generate a radiation which is directed through the optical fibre 11 to the cut diamond (brilliant) 1. Next, the diamond photoluminescence caused by exposure to the LED radiation is detected via the optical fibre 3 by the spectrometer 6. It should be noted that, when the radiation source 10 operates within the wavelength range of 350-380 nm, a gap is formed between the optical fibre 11 for inputting radiation and the surface of the cut diamond (brilliant). This gap makes it possible to detect, at a constant solid angle, a greater photoluminescence flux by the optical fibre 3 for outputting radiation and, accordingly, to get results at a higher sensitivity. Moreover, the notch filter 5 inserted between the collimating lenses 4 of the optical fibre 3 segments reduces the intensity of scattered radiation from the LED 10 by four orders of magnitude. Note that we use the same notch filter 5 in the two examination steps described above. The presence of the spectral line in the diamond luminescence spectrum at a wavelength of 415 nm (FIG. 4) testifies that the diamond being examined is natural.

[0035] In a third examination step, transmission of an ultraviolet radiation of 250-280 nm through the cut diamond (brilliant) is studied. For this purpose, the radiation source 12 in the form of a LED generates the ultraviolet radiation which propagates through the optical fibre 13 onto the cut diamond 1 (brilliant). Having entered the cut diamond through its table, the ultraviolet radiation is successively reflected from opposite pavilion facets of the diamond, goes outside through the same diamond table, and enters the spectrometer 6 through the optical fibre 3.

[0036] With this scheme, the ultraviolet radiation passes twice through the crystal body, which makes it possible to get results at a higher sensitivity.

[0037] Here, the optical system 15 is moved such that the optical fibres 3, 11, 13 come into close contact with the surface of the cut diamond (brilliant) (FIG. 2). Radiation transmitted by the cut diamond (brilliant) is directed through the optical fibre 3 to the spectrometer 6, wherein the notch filter 5 is removed by the filter input/output mechanism 14. The absence of a band of 250-280 nm in the transmission spectrum of the cut diamond (brilliant) 1 gives evidence of that this is a natural diamond of Type IaA, IaB or IaAB. The presence of a band of 250-280 nm in the transmission spectrum of the cut diamond (brilliant) 1 (FIG. 5) gives evidence of that this is a diamond of Type IIa. If the results of measurements taken by the three techniques show that the examined sample is not a diamond, a Simulant legend appears on the electronic display of the diamond identification apparatus. If the examined sample is a natural diamond, then a Natural Diamond legend appears on the display. If the examined sample is not a natural diamond, then a IIa legend appears. About 2% of natural diamonds, substantially all synthetic (HPHT and CVD) diamonds and natural diamonds that have been subjected to a pressure-and-temperature treatment to improve color can be ascribed to the Type IIa. For reliable identification of these brilliants, they need to be studied in more details.

INDUSTRIAL APPLICABILITY

[0038] The inventive apparatus allows for effective identification of diamonds, including in finished jewelry. The applied design solutions make the apparatus compact, mobile and affordable, while ensuring the effective identification of cut diamonds based on the use of the described combination of investigation techniques. The apparatus makes it possible to determine: whether the examined brilliant is a diamond or its simulant, whether this is a natural diamond or a synthetic diamond, and whether more detailed studies are needed to determine whether the examined diamond has been subjected to a pressure-and-temperature treatment.