Preparation and application of dynamic non-wicking PU foam

Abstract

Disclosed are a dynamic non-wicking PU foam and preparation and application thereof The PU foam is prepared from polyether polyol, toluene-2,4-diisocyanate, non-wicking additive and auxiliary agent. The dynamic non-wicking additive is composed of carboxylic acids, amines and alkyl alcohols in any proportion. The auxiliary agent is composed of silicone surfactant, amine promoter, tin catalyst, pigment and water. The dynamic non-wicking PU foam has a high stability and an extremely non-wicking effect. The shoes made of the dynamic non-wicking PU foam also have extremely good dynamic non-wicking and waterproof effects, thus ensuring both comfort and stability of quality.

Claims

1. A dynamic non-wicking polyurethane (PU) foam, wherein the dynamic non-wicking polyurethane (PU) foam is prepared from the following components by weight percentage on the basis of the total dynamic non-wicking polyurethane (PU) foam: Polyether polyol: 62.6-75.4%, Diisocyanate: 15.9-26.2%, Dynamic non-wicking additive: 5.6-7.2%, and Auxiliary agent: 3.1-4.0%; wherein the dynamic non-wicking additive is one of (i) carboxylic acids, (ii) amines or (iii) alkyl alcohols, or (iv) is composed of carboxylic acids, amines, and alkyl alcohols in any proportion, wherein the carboxylic acids and the amines contain alkyl groups having a total of 8-20 carbon atoms, and the alkyl alcohols contain alkyl groups having a total of 11-20 carbon atoms; and the auxiliary agent is composed of the following components by weight percentage on the basis of the total auxiliary agent: Silicone surfactant: 18.8-33.2%, Amine promoter: 3.1-7.6%, Tin catalyst: 3.2-7.3%, Pigment: 20.4-24.8 %, and Water: 35.6-46.0%.

2. The dynamic non-wicking PU foam of claim 1, wherein the diisocyanate is toluene-2,4-diisocyanate.

3. The dynamic non-wicking PU foam of claim 1, wherein the dynamic non-wicking additive is composed of the following components by weight percentage on the basis of the total dynamic non-wicking additive: carboxylic acids: 18.8-38.6% amines: 29.6-34.4% alkyl alcohols: 31.8-46.8%.

4. The dynamic non-wicking PU foam of claim 1, wherein the amine promoter is composed of triethylene diamine and dipropylene glycol.

5. The dynamic non-wicking PU foam of claim 1, wherein the tin catalyst is stannous octoate.

6. A method for preparing the dynamic non-wicking PU foam of claim 1, comprising the steps of: (1) premixing the polyether polyol, the dynamic non-wicking additive and the auxiliary agent and stirring until a uniform mixture is made; (2) adding the diisocyanate which comprises toluene-2,4-diisocyanate to the mixture obtained in step (1); (3) stirring at a rotation speed of 2500-6000 revolutions per minute until a uniform mixture is made; and (4) placing the mixture at room temperature for 1-3 days to obtain the dynamic non-wicking PU foam.

7. The method of claim 6, wherein, in step (2), stirring is accomplished at a rotation speed of 5000 revolutions per minute.

8. A method of preparing the upper vamps, tongues, and collars of waterproof shoes comprising forming the upper vamps, tongues, and collars of waterproof shoes from the dynamic non-wicking PU foam of claim 1.

Description

DETAILED DESCRIPTION OF THE INVENTION

(1) The present invention is further described in detail below in combination with the examples, but the embodiments of the present invention are not limited thereto.

(2) In the examples of the present invention, the method for preparing the dynamic non-wicking PU foam comprises the following steps:

(3) (1). Premixing: the polyether polyols, the dynamic non-wicking additives and the auxiliary agents are mixed, and stirred to uniform;

(4) (2) High speed mixing: the toluene-2,4-diisocyanate is added to the mixture obtained in step (1), stirred in high speed (5000 revolutions per minute) to uniform; and placed at room temperature for 1-3 days, so as to obtain the dynamic non-wicking PU foam.

EXAMPLE 1

(5) The formulation of the dynamic non-wicking PU foam I is shown in the following table:

(6) TABLE-US-00001 Components Weight percentage Polyether polyol 62.6% Toluene-2,4-diisocyanate T-80 26.2% Dynamic non-wicking additive 7.2% Auxiliary agent 4.0%

(7) wherein the polyether polyol is composed of 75% of Polyether polyol 5615 and 25% of Polyether polyol 3045, all of the percentages are based on the total weight of the polyether polyols.

(8) The dynamic non-wicking additive has the components as shown in the following table:

(9) TABLE-US-00002 Components Weight percentage Dodecyl carboxylic acid 38.6% Tetradecyl amine 29.6% 6-undecanol 31.8%

(10) The auxiliary agent has the components as shown in the following table

(11) TABLE-US-00003 Components Weight percentage Silicone surfactant L-618 18.8% Amine promoter 3.1% Tin catalyst (Stannous octanoate T-9) 7.3% Black pigment 24.8% Water 46.0% Note: the silicone surfactant L -618 is purchased from MOMENTIVE Company, U.S.A. (similarly hereinafter).

(12) wherein the amine promoter is composed of triethylene diamine and dipropylene glycol.

(13) The non-wicking test of the PU foam I is performed according to the method specified by GORE-TEX, obtaining a dynamic non-wicking performance of 210000 times. However, the control product, i.e., the conventional PU foam without addition of the dynamic non-wicking additive (which is obtained using the same formulation and method as those in this example, except that the dynamic non-wicking additive is not added), obtaining a dynamic non-wicking performance of 300 times or less.

EXAMPLE 2

(14) The formulation of dynamic non-wicking PU foam II is shown in the following table:

(15) TABLE-US-00004 Components Weight percentage Polyether polyol 68.3% Toluene-2,4-diisocyanate T-80 22.2% Dynamic non-wicking additive 6.0% Auxiliary agent 3.5%

(16) wherein the polyether polyol is composed of 42% of Polyether polyol 5615 and 58% of Polyether polyol 3045, all of the percentages are based on the total weight of the polyether polyols.

(17) The dynamic non-wicking additives are shown in the following table:

(18) TABLE-US-00005 Components Weight percentage Tetradecyl carboxylic acid 18.8% Dodecyl amine 34.4% 1-undecanol 46.8%

(19) The auxiliary agent has the components as shown in the following table

(20) TABLE-US-00006 Components Weight percentage Silicone surfactant L-618 27.9% Amine promoter 4.3% Tin catalyst (Stannous octanoate T-9) 5.8% Black pigment 21.4% Water 40.6%

(21) wherein the amine promoter is composed of triethylene diamine and dipropylene glycol.

(22) The non-wicking test of the PU foam his performed according to the method specified by GORE-TEX, obtaining a dynamic non-wicking performance of 180000 times. However, the control product, i.e., the conventional PU foam without addition of the dynamic non-wicking additive (which is obtained using the same formulation and method as those in this example, except that the dynamic non-wicking additive is not added), obtaining a dynamic non-wicking performance of 300 times or less.

EXAMPLE 3

(23) The formulation of dynamic non-wicking PU foam III is shown in the following table:

(24) TABLE-US-00007 Components Weight percentage Polyether polyol 75.4% Toluene-2,4-diisocyanate T-80 15.9% Dynamic non-wicking additive 5.6% Auxiliary agent 3.1%

(25) wherein the polyether polyol is composed of 27% of Polyether polyol 5615 and 73% of Polyether polyol 3045, all of the percentages are based on the total weight of the polyether polyols.

(26) The dynamic non-wicking additive has the components as shown in the following table:

(27) TABLE-US-00008 Components Weight percentage Hexadecyl carboxylic acid 25.0% Tetradecyl amine 30.5% 1-dodecanol 44.5%

(28) The auxiliary agents are shown in the following table

(29) TABLE-US-00009 Components Weight percentage Silicone surfactant L-618 33.2% Amine promoter 7.6% Tin catalyst (Stannous octanoate T-9) 3.2% Black pigment 20.4% Water 35.6%

(30) wherein the amine promoter is composed of triethylene diamine and dipropylene glycol.

(31) The non-wicking test of the PU foam III is performed according to the method specified by GORE-TEX, obtaining a dynamic non-wicking performance of 165000 times. However, the control product, i.e., the conventional PU foam without addition of the dynamic non-wicking additive (which is obtained using the same formulation and method as those in this example, except that the dynamic non-wicking additive is not added), obtaining a dynamic non-wicking performance of 300 times or less.

EXAMPLE 4

(32) A dynamic non-wicking PU foam IV is shown in the following table:

(33) TABLE-US-00010 Components Weight percentage Polyether polyol 75.4% Toluene-2,4-diisocyanate T-80 15.9% Dynamic non-wicking additive 5.6% (6-undecanol) Auxiliary agent 3.1%

(34) wherein the polyether polyol is composed of 27% of Polyether polyol 5615 and 73% of Polyether polyol 3045, all of the percentages are based on the total weight of the polyether polyols.

(35) The auxiliary agents are shown in the following table

(36) TABLE-US-00011 Components Weight percentage Silicone surfactant L-618 33.2% Amine promoter 7.6% Tin catalyst (Stannous octanoate T-9) 3.2% Black pigment 20.4% Water 35.6%

(37) wherein the amine promoter is composed of triethylene diamine and dipropylene glycol.

(38) The non-wicking test of the PU foam IV is performed according to the method specified by GORE-TEX, obtaining a dynamic non-wicking performance of 60000 times. However, the control product, i.e., the conventional PU foam without addition of the dynamic non-wicking additive (which is obtained using the same formulation and method as those in this example, except that the dynamic non-wicking additive is not added), obtaining a dynamic non-wicking performance of 300 times or less.

EXAMPLE 5

(39) The formulation of dynamic non-wicking PU foam V is shown in the following table:

(40) TABLE-US-00012 Components Weight percentage Polyether polyol 75.4% Toluene-2,4-diisocyanate T-80 15.9% Dynamic non-wicking additive 5.6% (Tetradecyl amine) Auxiliary agent 3.1%

(41) wherein the polyether polyol is composed of 27% of Polyether polyol 5615 and 73% of Polyether polyol 3045, all of the percentages are based on the total weight of the polyether polyols.

(42) The auxiliary agents are shown in the following table

(43) TABLE-US-00013 Components Weight percentage Silicone surfactant L-618 33.2% Amine promoter 7.6% Tin catalyst (Stannous octanoate T-9) 3.2% Black pigment 20.4% Water 35.6%

(44) wherein the amine promoter is composed of triethylene diamine and dipropylene glycol.

(45) The non-wicking test of the PU foam V is performed according to the method specified by GORE-TEX, obtaining a dynamic non-wicking performance of 80000 times. However, the control product, i.e., the conventional PU foam without addition of the dynamic non-wicking additive (which is obtained using the same formulation and method as those in this example, except that the dynamic non-wicking additive is not added), obtaining a dynamic non-wicking performance of 300 times or less.

EXAMPLE 6

(46) The formulation of dynamic non-wicking PU foam VI is shown in the following table:

(47) TABLE-US-00014 Components Weight percentage Polyether polyol 75.4% Toluene-2,4-diisocyanate T-80 15.9% Dynamic non-wicking additive 5.6% (Hexadecyl carboxylic acid) Auxiliary agent 3.1%

(48) wherein the polyether polyol is composed of 27% of Polyether polyol 5615 and 73% of Polyether polyol 3045, all of the percentages are based on the total weight of the polyether polyols.

(49) The auxiliary agents are shown in the following table

(50) TABLE-US-00015 Components Weight percentage Silicone surfactant L-618 33.2% Amine promoter 7.6% Tin catalyst (Stannous octanoate T-9) 3.2% Black pigment 20.4% Water 35.6%

(51) wherein the amine promoter is composed of triethylene diamine and dipropylene glycol.

(52) The non-wicking test of the PU foam VI is performed according to the method specified by GORE-TEX, obtaining a dynamic non-wicking performance of 75000 times. However, the control product, i.e., the conventional PU foam without addition of the dynamic non-wicking additive (which is obtained using the same formulation and method as those in this example, except that the dynamic non-wicking additive is not added), obtaining a dynamic non-wicking performance of 300 times or less.

(53) The above-mentioned examples are the preferred embodiments of the present invention, but the embodiments of the present invention are not limited thereto. Any other changes, such as modifications, substitutions, combinations, and simplification should be in the equivalent replacement mode, without departing from the spirit and principle of the present invention, and be all embraced in the scope of protection of the present invention.