Stacked vertical NFET and PFET
10297513 ยท 2019-05-21
Assignee
Inventors
Cpc classification
H01L21/28079
ELECTRICITY
H01L21/823878
ELECTRICITY
H01L29/66772
ELECTRICITY
H01L21/76877
ELECTRICITY
H01L29/78618
ELECTRICITY
H01L21/823885
ELECTRICITY
H01L29/42392
ELECTRICITY
H01L21/823807
ELECTRICITY
H01L21/28088
ELECTRICITY
H01L27/0688
ELECTRICITY
H01L29/4966
ELECTRICITY
H01L29/495
ELECTRICITY
H01L21/823814
ELECTRICITY
H01L29/517
ELECTRICITY
H01L21/823842
ELECTRICITY
H01L21/8221
ELECTRICITY
H01L21/02129
ELECTRICITY
H01L27/1203
ELECTRICITY
H01L21/823828
ELECTRICITY
H01L21/823871
ELECTRICITY
H01L29/6656
ELECTRICITY
International classification
H01L21/02
ELECTRICITY
H01L21/768
ELECTRICITY
H01L29/49
ELECTRICITY
H01L21/28
ELECTRICITY
H01L27/12
ELECTRICITY
H01L21/225
ELECTRICITY
H01L27/06
ELECTRICITY
H01L29/06
ELECTRICITY
H01L21/84
ELECTRICITY
H01L29/66
ELECTRICITY
H01L29/08
ELECTRICITY
H01L29/10
ELECTRICITY
Abstract
The present invention provides stacked VFET devices. In one aspect, a method of forming a stacked VFET device includes: patterning a fin(s) in a wafer having a vertical fin channel of a VFET1 separated from a vertical fin channel of a VFET2 by an insulator; forming a bottom source and drain of the VFET1 below the vertical fin channel of the VFET1; forming a gate of the VFET1 alongside the vertical fin channel of the VFET1; forming a gate of the VFET2 alongside the vertical fin channel of the VFET2; forming a top source and drain of the VFET1 above the vertical fin channel of the VFET1; forming a bottom source and drain of the VFET2 below the vertical fin channel of the VFET2; and forming a top source and drain of the VFET2 above the vertical fin channel of the VFET2. A stacked VFET device is also provided.
Claims
1. A method of forming a stacked vertical field effect transistor (VFET) device, the method comprising the steps of: patterning at least one fin in a wafer, the at least one fin comprising a vertical fin channel of a first VFET (VFET1) separated from a vertical fin channel of a second VFET (VFET2) by an insulator; forming a bottom source and drain of the VFET1 below the vertical fin channel of the VFET1; forming a gate of the VFET1 alongside the vertical fin channel of the VFET1; forming a gate of the VFET2 alongside the vertical fin channel of the VFET2; forming a top source and drain of the VFET1 above the vertical fin channel of the VFET1; forming a bottom source and drain of the VFET2 below the vertical fin channel of the VFET2; forming a top source and drain of the VFET2 above the vertical fin channel of the VFET2; and depositing an interlayer dielectric (ILD) over the at least one fin.
2. The method of claim 1, wherein either i) the VFET1 is an n-channel FET (NFET) and the VFET2 is a p-channel FET (PFET), or ii) the VFET1 is a PFET and the VFET2 is an NFET.
3. The method of claim 1, wherein the wafer comprises a semiconductor-on-insulator (SOI) wafer having an SOI layer separated from a substrate by a buried insulator, wherein the at least one fin, as patterned, comprises a patterned portion of the substrate that serves as the vertical fin channel of the VFET1 and a patterned portion of the SOI layer that serves as the vertical fin channel of the VFET2, and wherein a patterned portion of the buried insulator serves as the insulator.
4. The method of claim 1, further comprising the steps of: forming bottom spacers of the VFET1 on the bottom source and drain of the VFET1; forming the gate of the VFET1 above the bottom spacers of the VFET1; forming top spacers of the VFET1 above the gate of the VFET1; depositing a doped layer of the VFET1 onto the top spacers of the VFET1; forming an isolation spacer on the doped layer of the VFET1; depositing a first doped layer of the VFET2 onto the isolation spacer; forming bottom spacers of the VFET2 on the first doped layer of the VFET2; forming the gate of the VFET2 above the bottom spacers of the VFET2; forming top spacers of the VFET2 above the gate of the VFET2; depositing a second doped layer of the VFET2 onto the top spacers; and driving dopants from the doped layer of the VFET1, the first doped layer of the VFET2, and the second doped layer of the VFET2 into the at least one fin to form the top source and drain of the VFET1, the bottom source and drain of the VFET2, and the top source and drain of the VFET2.
5. The method of claim 4, wherein the doped layer of the VFET1 comprises a first doped material, and wherein the first doped layer of the VFET2 and the second doped layer of the VFET2 each comprises a second doped material.
6. The method of claim 5, wherein either I) the first doped material is boron-doped glass (BSG) and the second doped material is phosphorous-doped glass (PSG), or II) the first doped material is PSG and the second doped material is BSG.
7. The method of claim 4, further comprising the step of: forming a contact to the bottom source and drain of the VFET2.
8. The method of claim 7, further comprising the steps of: patterning a contact trench extending down through the ILD, the top spacers of the VFET2, the gate of the VFET2, and the bottom spacers of the VFET2, stopping on the first doped layer of the VFET2; forming a sidewall spacer along at least one sidewall of the contact trench covering the gate of the VFET2; removing the first doped layer of the VFET2; and replacing the first doped layer of the VFET2 with a contact metal which fills the contact trench forming the contact to the bottom source and drain of the VFET2.
9. The method of claim 4, further comprising the step of: forming a contact to the top source and drain of the VFET1.
10. The method of claim 9, further comprising the steps of: patterning a contact trench extending down through the ILD, the top spacers of the VFET2, the gate of the VFET2, the bottom spacers of the VFET2, the first doped layer of the VFET2, and the isolation spacer, stopping on the doped layer of the VFET1; forming a sidewall spacer along at least one sidewall of the contact trench covering the gate of the VFET2; removing the doped layer of the VFET1; and replacing the doped layer of the VFET1 with a contact metal which fills the contact trench forming the contact to the top source and drain of the VFET1.
11. The method of claim 4, further comprising the step of: forming a contact to the top source and drain of the VFET2.
12. The method of claim 11, further comprising the steps of: patterning a contact trench in the ILD, exposing the top source and drain of the VFET2; and filling the contact trench with a contact metal to form the contact to the top source and drain of the VFET2.
13. The method of claim 4, further comprising the step of: forming a shared contact to the top source and drain of the VFET1 and the bottom source and drain of the VFET2.
14. The method of claim 13, further comprising the steps of: patterning a contact trench extending down through the ILD, the top spacers of the VFET2, the gate of the VFET2, and the bottom spacers of the VFET2, stopping on the first doped layer of the VFET2; forming a sidewall spacer along at least one sidewall of the contact trench covering the gate of the VFET2; extending the contact trench down through the first doped layer of the VFET2 and the isolation spacer, stopping on the doped layer of the VFET1; removing the doped layer of the VFET1 and the first doped layer of the VFET2; and replacing the doped layer of the VFET1 and the first doped layer of the VFET2 with a contact metal which fills the contact trench forming the shared contact to the top source and drain of the VFET1 and the bottom source and drain of the VFET2.
15. The method of claim 4, further comprising the step of: forming a contact to the bottom source and drain of the VFET1.
16. The method of claim 15, further comprising the steps of: patterning a contact trench extending down through the ILD, the top spacers of the VFET2, the gate of the VFET2, the bottom spacers of the VFET2, the first doped layer of the VFET2, the isolation spacer, the doped layer of the VFET1, the top spacers of the VFET1, the gate of the VFET1, and the bottom spacers of the VFET1, stopping on the substrate; forming a sidewall spacer along at least one sidewall of the contact trench covering the gate of the VFET1 and the gate of the VFET2; and filling the contact trench with a contact metal to form the contact to the bottom source and drain of the VFET1.
17. The method of claim 1, wherein the step of forming the gate of the VFET1 comprises the steps of: depositing a conformal dielectric onto the bottom spacers of the VFET1; and depositing a gate conductor onto the conformal gate dielectric, wherein the conformal gate dielectric comprises a high-K gate dielectric selected from the group consisting of: hafnium oxide (HfO.sub.2), lanthanum oxide (La.sub.2O.sub.3) and combinations thereof, and wherein the gate conductor comprises a workfunction setting metal selected from the group consisting of: titanium nitride (TiN), tantalum nitride (TaN), aluminum (Al)-containing alloys, titanium aluminide (TiAl), titanium aluminum nitride (TiAlN), titanium aluminum carbide (TiAlC), tantalum aluminide (TaAl), tantalum aluminum nitride (TaAlN), tantalum aluminum carbide (TaAlC), tungsten (W) and combinations thereof.
18. The method of claim 1, wherein the step of forming the gate of the VFET2 comprises the steps of: depositing a conformal dielectric onto the bottom spacers of the VFET2; and depositing a gate conductor onto the conformal gate dielectric, wherein the conformal gate dielectric comprises a high-K gate dielectric selected from the group consisting of: HfO.sub.2, La.sub.2O.sub.3 and combinations thereof, and wherein the gate conductor comprises a workfunction setting metal selected from the group consisting of: TiN, TaN, Al-containing alloys, TiAl, TiAlN, TiAlC, TaAl, TaAlN, TaAlC, W and combinations thereof.
19. A VFET device, comprising: at least one fin patterned in a wafer, the at least one fin comprising a vertical fin channel of a first VFET (VFET1) separated from a vertical fin channel of a second VFET (VFET2) by an insulator; a bottom source and drain of the VFET1 present below the vertical fin channel of the VFET1; a gate of the VFET1 disposed alongside the vertical fin channel of the VFET1; a gate of the VFET2 disposed alongside the vertical fin channel of the VFET2; a top source and drain of the VFET1 present above the vertical fin channel of the VFET1; a bottom source and drain of the VFET2 present below the vertical fin channel of the VFET2; a top source and drain of the VFET2 present above the vertical fin channel of the VFET2; and an ILD over the at least one fin.
20. The VFET device of claim 19, further comprising: bottom spacers of the VFET1 disposed on the bottom source and drain of the VFET1; top spacers of the VFET1 disposed above the gate of the VFET1; a doped layer of the VFET1 disposed on the top spacers of the VFET1; an isolation spacer disposed on the doped layer of the VFET1; a doped layer of the VFET2 disposed on the isolation spacer; bottom spacers of the VFET2 disposed on the doped layer of the VFET2; top spacers of the VFET2 disposed above the gate of the VFET2; and a second doped layer of the VFET2 disposed on the top spacers.
21. The VFET device of claim 20, wherein the doped layer of the VFET1 comprises a first doped material, wherein the doped layer of the VFET2 comprises a second doped material, and wherein either I) the first doped material is BSG and the second doped material is PSG, or II) the first doped material is PSG and the second doped material is BSG.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
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DETAILED DESCRIPTION OF PREFERRED EMBODIMENTS
(19) Provided herein are techniques for forming stacked vertical n-channel and p-channel VFETs (NFETs and PFETs). By comparison, typical VFET layouts include vertical NFETs and PFETs side-by-side one another on a wafer. Thus, in addition to the vertical orientation of the VFET structure, the present stacked VFET designs provide another dimension for complementary metal-oxide-semiconductor (CMOS) area scaling.
(20) An exemplary embodiment for forming a stacked VFET (NFET and PFET) device is now described by way of reference to
(21) As shown in
(22) The SOI layer 102 and the substrate 106 each can include any suitable semiconductor, such as silicon (Si), germanium (Ge), silicon germanium (SiGe), and/or a III-V semiconductor. Preferably, the SOI layer 102 and the substrate 106 are both undoped. According to an exemplary embodiment, a different material is used for SOI layer 102 than for the substrate 106, and the particular materials employed for the SOI layer 102 and the substrate 106 vary depending on whether the bottom/top VFETs are NFET/PFET or PFET/NFET. For instance, according to an exemplary embodiment, Si is used as the channel material for the NFET and SiGe is used as the channel material for the PFET. As will become apparent from the description that follows, a portion of the fin(s) patterned in the SOI layer 102 will serve as the vertical fin channel of the top VFET in the stack, while a portion of the fin(s) patterned in the substrate 106 will serve as the vertical fin channel of the bottom VFET in the stack. Thus, according to this particular example, if the device is configured with the bottom VFET/top VFET as NFET/PFET, then the substrate 106 would be Si and the SOI layer 102 would be SiGe. On the other hand, if the device is configured with the bottom VFET/top VFET as PFET/NFET, then the SOI layer 102 would be Si and the substrate 106 would be SiGe.
(23) As shown in
(24) The portions of the fin 204 patterned in the SOI layer 102 will now be given the reference numeral 102a, the portions of the fin 204 patterned in the buried insulator 104 will now be given the reference numeral 104a, and the portions of the fin 204 patterned in the substrate 106 will now be given the reference numeral 106a. As provided above, the portion 102a of the fin 204 patterned in the SOI layer 102 will serve as the vertical fin channel of the top VFET in the stack, while the portion 106a of the fin 204 patterned in the substrate 106 will serve as the vertical fin channel of the bottom VFET in the stack.
(25) As shown in
(26) An anneal is then used to activate the dopants in the bottom source and drain 206. According to an exemplary embodiment, the activation anneal is performed using a process such as rapid thermal annealing (RTA) at a temperature of from about 850 C. to about 1000 C., and ranges therebetween.
(27) Next, as shown in
(28) According to an exemplary embodiment, the bottom spacers 302 are formed using a directional deposition process whereby the spacer material is deposited with a greater amount of the material being deposited on horizontal surfaces (including on top of the bottom source and drain 206), as compared to vertical surfaces (such as along sidewalls of the fin 204). Thus, when an etch is used on the spacer material, the timing of the etch needed to remove the spacer material from the vertical surfaces will leave the bottom spacers 302 shown in
(29) A gate (i.e., a gate dielectric and gate conductor) of the bottom VFET is next formed alongside the fin 204 above the bottom spacers 302. To form the gate, a conformal gate dielectric 304 is deposited onto the bottom spacers 302 and alongside the fin 204. A gate conductor 306 is then deposited onto the conformal gate dielectric 304. See
(30) According to an exemplary embodiment, a metal gate is formed wherein the gate conductor 306 is a metal or combination of metals and the gate dielectric 304 is a high- dielectric. For instance, the gate conductor 306 is a workfunction setting metal. The particular workfunction setting metal employed can vary depending on whether the bottom VFET is an NFET (n-type workfunction setting metal) or PFET (p-type workfunction setting metal). Suitable n-type workfunction setting metals include, but are not limited to, titanium nitride (TiN), tantalum nitride (TaN) and/or aluminum (Al)-containing alloys such as titanium aluminide (TiAl), titanium aluminum nitride (TiAlN), titanium aluminum carbide (TiAlC), tantalum aluminide (TaAl), tantalum aluminum nitride (TaAlN), and/or tantalum aluminum carbide (TaAlC). Suitable p-type workfunction setting metals include, but are not limited to, TiN, TaN, and tungsten (W). TiN and TaN are relatively thick (e.g., greater than about 2 nanometers (nm)) when used as p-type workfunction metals. However, very thin TiN or TaN layers (e.g., less than about 2 nm) may also be used beneath Al-containing alloys in n-type workfunction stacks to improve electrical properties such as gate leakage currents. Thus, there is some overlap in the exemplary n- and p-type workfunction metals given above.
(31) The term high- as used herein refers to a material having a relative dielectric constant which is much higher than that of silicon dioxide (e.g., a dielectric constant =25 for hafnium oxide (HfO.sub.2) rather than 4 for silicon dioxide). Suitable high- gate dielectrics include, but are not limited to, HfO.sub.2 and/or lanthanum oxide (La.sub.2O.sub.3).
(32) Next, top spacers 308 of the bottom VFET are formed above the gate. See
(33) The top spacers 308 may also be formed using a directional deposition process, such as HDP CVD or PVD. As described above, with a directional deposition process a greater amount of the spacer material is deposited on horizontal surfaces, as compared to vertical surfaces (such as along sidewalls of the fin 204). Thus, when an etch is used on the spacer material, the timing of the etch needed to remove the spacer material from the vertical surfaces will leave the top spacers 308 shown in
(34) In order to form a top source and drain for the bottom VFET, a doped layer 402 for the bottom VFET is next deposited onto the top spacers 308 alongside the fin 204. See
(35) According to an exemplary embodiment, the dopant sources used in the present process flow include boron-doped glass (BSG) as a p-type dopant source and phosphorous-doped glass (PSG) an n-type dopant source. Thus, in the case where the bottom VFET is an NFET then the doped layer 402 is formed from PSG. On the other hand, in the case where the bottom VFET is a PFET then the doped layer 402 is formed from BSG. In the same manner as described above, the doped layer 402 can be deposited using a directional deposition process, such as HDP CVD or PVD, with a greater amount of the material (e.g., PSG or BSG) being deposited onto horizontal surfaces, followed by an etch to remove the material from vertical surfaces resulting in formation of the doped layer 402 shown in
(36) As provided above, the portion 102a of the fin 204 patterned in the SOI layer 102 will serve as the vertical fin channel of the top VFET in the stack, while the portion 106a of the fin 204 patterned in the substrate 106 will serve as the vertical fin channel of the bottom VFET in the stack. Referring to
(37) An n-p isolation spacer 404 is then formed above the doped layer 402 alongside the fin 204. Specifically, as shown in
(38) A top VFET is then formed over the bottom VFET. Formation of the top VFET proceeds in the same general manner as with the bottom VFET, however with a device of the opposite polarity being formed. Namely, if the bottom VFET is an NFET, then a PFET is formed as the top VFET. Conversely, if the bottom VFET is a PFET, then an NFET is formed as the top VFET.
(39) One difference in the formation of the top VFET is that doped layers (e.g., BSG or PSG) are used at the bottom and top of the device to form both the bottom and top source and drains. By comparison, with the bottom VFET a different doping process such as ion implantation followed by an activation anneal can be implemented for the bottom source and drain 206see above.
(40) Namely, as shown in
(41) According to an exemplary embodiment, when the top VFET is an NFET the doped layer 502 is formed from PSG, and when the top VFET is a PFET the doped layer 502 is formed from BSG. In the same manner as described above, the doped layer 502 can be deposited using a directional deposition process, such as HDP CVD or PVD, with a greater amount of the material (e.g., PSG or BSG) being deposited onto horizontal surfaces, followed by an etch to remove the material from vertical surfaces resulting in formation of the doped layer 502 shown in
(42) Bottom spacers 504 of the top VFET are next formed on the doped layer 502. Suitable materials for the bottom spacers 504 include, but are not limited to, SiO.sub.2 and/or SiOC.
(43) In the same manner as described above, the bottom spacers 504 can be deposited using a directional deposition process, such as HDP CVD or PVD, with a greater amount of the spacer material being deposited onto horizontal surfaces, followed by an etch to remove the material from vertical surfaces resulting in formation of the bottom spacers 504 shown in
(44) A gate (i.e., a gate dielectric and gate conductor) of the top VFET is next formed alongside the fin 204 above the bottom spacers 504. To form the gate, a conformal gate dielectric 506 is deposited onto the bottom spacers 504 and alongside the fin 204 (above the portion 104a of the buried insulator 104). A gate conductor 508 is then deposited onto the conformal gate dielectric 506. See
(45) According to an exemplary embodiment, a metal gate is formed wherein the gate conductor 508 is a metal or combination of metals and the gate dielectric 506 is a high-K dielectric. For instance, the gate conductor 508 is a workfunction setting metal. The particular workfunction setting metal employed varies depending on whether the top VFET is an NFET (n-type workfunction setting metal) or PFET (p-type workfunction setting metal). As provided above, suitable n-type workfunction setting metals include, but are not limited to, TiN, TaN and/or Al-containing alloys such as TiAl, TiAlN, TiAlC, TaAl, TaAlN, and/or TaAlC. Suitable p-type workfunction setting metals include, but are not limited to, TiN, TaN, and W. Suitable high- gate dielectrics include, but are not limited to, HfO.sub.2 and/or La.sub.2O.sub.3.
(46) Next, top spacers 510 of the top VFET are formed above the gate. Suitable materials for the top spacers 510 include, but are not limited to, SiO.sub.2 and/or SiOC. In the same manner as described above, the top spacers 510 can be deposited using a directional deposition process, such as HDP CVD or PVD, with a greater amount of the spacer material being deposited onto horizontal surfaces, followed by an etch to remove the material from vertical surfaces resulting in formation of the top spacers 510 shown in
(47) A second doped layer 512 of the top VFET is deposited onto the top spacers 510 alongside the fin 204. See
(48) A drive-in anneal is then used to drive dopants from the doped layers 402 and 502/512 into the fin 204 above the vertical fin channel (portion 106a) of the bottom VFET and into the fin 204 below/above the vertical fin channel (portion 102a) of the top VFET. This dopant drive-in will form the top source and drain 602 of the bottom VFET and the bottom and top source and drains 604 and 606, respectively, of the top VFET. As provided above, the dopants for the source and drains depend on whether a NFET (a p-type dopant) or a PFET (an n-type dopant) is being formed. As shown in
(49) As will be described in detail below, a top contact to the top VFET can be formed at the top of the fin 204. In order to prevent any potential short to other contacts (e.g., a bottom contact of the top VFET and/or to top and bottom contacts to the bottom VFETsee below), the top doped layer 512 is now removed from the alongside the fin 204 at the top VFET. See
(50) Exemplary processes for forming source and drain contacts to the top and bottom VFETs are now described.
(51) A sidewall spacer 804 is then formed lining the sidewalls of the contact trench 802. The spacer 804 serves to isolate the gate (of the top VFET) from the contact to be formed in the contact trench 802. Suitable materials for the sidewall spacer 804 include nitride spacer materials such as SiN and/or silicon oxynitride SiON. A nitride material is preferable for this sidewall spacer application since, as will be described below, the next task is to remove the doped layer 502 exposed at the bottom of the contact trench 802. As provided above, the doped layer 502 can include BSG or PSG (depending on whether a p-type or an n-type dopant source is needed). Both BSG and PSG are essentially silicon oxide materials doped with boron or phosphorous. Thus, an oxide-selective etch will remove the BSG or PSG doped layer 502, while leaving the sidewall spacer 804 intact and protecting the gate.
(52) An isotropic (non-directional) etching process is then used to remove the doped layer 502 from the top VFET. Suitable isotropic etching processes for removing the doped layer 502 include, but are not limited to, an oxide-selective wet etching process. The doped layer is then replaced with a contact metal which fills the contact trench 802, forming a contact 902 to the bottom source and drain of the top VFET. See
(53) The same basic process flow can also be used to form a top source and drain contact to the bottom VFET. See, for example,
(54) A spacer 1004 (e.g., SiN and/or SiON) is then formed lining the sidewalls of the contact trench 1002. The spacer 1004 serves to isolate the gate (of the top VFET) from the contact to be formed in the contact trench 1002. As described above, use of a nitride spacer material allows for selective removal of the, e.g., BSG or PSG, in doped layer 402 for contact formation.
(55) An isotropic etching process (such as an oxide-selective wet etching process) is then used to remove the doped layer 402 from the top VFET, and replace the doped layer 402 with a contact metal which fills the contact trench 1002, forming a contact 1102 to the top source and drain of the bottom VFET. See
(56) As highlighted above, a top source and drain contact to the top VFET can be formed over the top of the fin 204. See, for example,
(57) The process for forming contact 1202 is straightforward. Namely, standard lithography and etching techniques using a directional etching process such as RIE are used to pattern a contact trench in the ILD 702, exposing the top source and drain 606 at the top of the fin 204. The contact trench is then filled with a contact metal forming a contact 1202 to the top source and drain of the top VFET. Suitable contact metals include, but are not limited, to Cu, Ni, Pt and/or W.
(58) The exemplary contact configuration shown in
(59) The contact trench 1302 is then extended through the doped layer 502 and the isolation spacer 404, stopping on the doped layer 402. See
(60) Finally, as shown in
(61) The formation of a bottom source and drain contact to the bottom VFET is now described by way of reference to
(62) As described above, the bottom source and drain 206 of the bottom VFET was formed differently from the other source and drains in the stacked device. Namely, bottom source and drain 206 was formed immediately following fin patterning in the substrate 106 at the base of fine 204. Thus, contact can be made to the surface of the substrate 106 (rather than to the fin itself). Specifically, as shown in
(63) A sidewall spacer 1604 (e.g., SiN and/or SiON) is then formed lining the sidewalls of the contact trench 1602. The sidewall spacer 1604 serves to isolate the gates (of the top and bottom VFET) from the contact to be formed in the contact trench 1602. The contact trench 1602 is then filled with a contact metal forming a contact 1702 to the bottom source and drain of the bottom VFET. See
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(65) Although illustrative embodiments of the present invention have been described herein, it is to be understood that the invention is not limited to those precise embodiments, and that various other changes and modifications may be made by one skilled in the art without departing from the scope of the invention.