Packaging mechanisms for dies with different sizes of connectors
11488878 · 2022-11-01
Assignee
Inventors
Cpc classification
H01L25/18
ELECTRICITY
H01L2224/0401
ELECTRICITY
H01L2924/00012
ELECTRICITY
H01L2224/1403
ELECTRICITY
H01L2224/81193
ELECTRICITY
H01L2225/06513
ELECTRICITY
H01L23/538
ELECTRICITY
H01L24/80
ELECTRICITY
H01L2924/13091
ELECTRICITY
H01L2224/32225
ELECTRICITY
H01L2225/06517
ELECTRICITY
H01L2224/32225
ELECTRICITY
H01L2924/00
ELECTRICITY
H01L23/522
ELECTRICITY
H01L2224/16227
ELECTRICITY
H01L2924/00
ELECTRICITY
H01L2224/16237
ELECTRICITY
H01L22/34
ELECTRICITY
H01L24/01
ELECTRICITY
H01L2224/14133
ELECTRICITY
H01L25/0652
ELECTRICITY
H01L2224/08111
ELECTRICITY
H01L2924/00014
ELECTRICITY
H01L2224/05568
ELECTRICITY
H01L2924/13091
ELECTRICITY
H01L23/3128
ELECTRICITY
H01L23/5389
ELECTRICITY
H01L2224/451
ELECTRICITY
H01L2924/00014
ELECTRICITY
H01L2924/00012
ELECTRICITY
H01L2224/16225
ELECTRICITY
H01L22/32
ELECTRICITY
International classification
H01L25/18
ELECTRICITY
H01L25/065
ELECTRICITY
H01L23/522
ELECTRICITY
Abstract
Embodiments of mechanisms for testing a die package with multiple packaged dies on a package substrate use an interconnect substrate to provide electrical connections between dies and the package substrate and to provide probing structures (or pads). Testing structures, including daisy-chain structures, with metal lines to connect bonding structures connected to signals, power source, and/or grounding structures are connected to probing structures on the interconnect substrate. The testing structures enable determining the quality of bonding and/or functionalities of packaged dies bonded. After electrical testing is completed, the metal lines connecting the probing structures and the bonding structures are severed to allow proper function of devices in the die package. The mechanisms for forming test structures with probing pads on interconnect substrate and severing connecting metal lines after testing could reduce manufacturing cost.
Claims
1. A method of forming a semiconductor die package, the method comprising: forming an interconnect substrate, wherein forming the interconnect substrate comprises: forming a redistribution layer over a first substrate, the first substrate having a first beveled edge; forming a seed layer over the redistribution layer and the first beveled edge of the first substrate; forming a mask layer over the seed layer, the mask layer having a plurality of openings; forming a first interconnect contact, a second interconnect contact, and a third interconnect contact in the plurality of openings, wherein the first interconnect contact and the second interconnect contact are on a major surface of the first substrate, wherein the third interconnect contact is on the first beveled edge of the first substrate; and removing the mask layer and exposed portions of the seed layer; bonding the third interconnect contact to a sidewall of a first package substrate contact of a package substrate; bonding a first packaged die contact of a first packaged die to a second package substrate contact of the package substrate; bonding a second packaged die contact of the first packaged die to the first interconnect contact of the interconnect substrate; and bonding a third packaged die contact of a second packaged die to the second interconnect contact of the interconnect substrate.
2. The method of claim 1, wherein the first beveled edge extends lower than the redistribution layer.
3. The method of claim 1, wherein a sidewall of the interconnect substrate comprises the first beveled edge and a lower portion extending from the first beveled edge to a bottom of the interconnect substrate, wherein the lower portion is free of the third interconnect contact.
4. The method of claim 1, wherein bonding the third interconnect contact is performed at least in part using solder.
5. The method of claim 1, further comprising encapsulating the first packaged die and the second packaged die with an encapsulant, the encapsulant being interposed between the interconnect substrate and the package substrate.
6. The method of claim 1, further comprising forming a fourth interconnect contact on a second beveled edge of the first substrate.
7. The method of claim 1, wherein the first packaged die contact has a first width, the second packaged die contact has a second width, the first width being different than the second width.
8. A method of forming a semiconductor die package, the method comprising: bonding a first substrate to a second substrate, the second substrate having a cavity, wherein the first substrate is in the cavity, wherein a sidewall of the cavity comprises a first electrical contact, wherein bonding the first substrate to the second substrate comprises bonding the first substrate to the first electrical contact using a first electrical connector; bonding a third substrate to the first substrate and the second substrate; and bonding a fourth substrate to the first substrate, wherein the third substrate is electrically coupled to the second substrate through the first substrate.
9. The method of claim 8, further comprising forming a dielectric material between the first substrate and the second substrate.
10. The method of claim 9, wherein the dielectric material extends continuously from the first electrical connector to between the third substrate and the second substrate.
11. The method of claim 10, wherein the dielectric material extends continuously from the first electrical connector to between the fourth substrate and the first substrate.
12. The method of claim 11, wherein the dielectric material extends over an upper surface of the third substrate.
13. The method of claim 8, wherein bonding the third substrate to the first substrate uses a second electrical connector, wherein bonding the third substrate to the second substrate uses a third electrical connector, wherein the second electrical connector is smaller than the third electrical connector.
14. The method of claim 8, wherein an upper surface of the second substrate is level with an upper surface of the first substrate.
15. A method of forming a semiconductor die package, the method comprising: forming an interconnect substrate, wherein forming the interconnect substrate comprises: forming a redistribution layer over a first substrate, the first substrate having a first beveled edge; forming a seed layer over the redistribution layer and the first beveled edge of the first substrate; forming a mask layer over the seed layer, the mask layer having a plurality of openings; forming a first interconnect contact, a second interconnect contact, and a third interconnect contact in the plurality of openings, wherein the first interconnect contact and the second interconnect contact are on a major surface of the first substrate, wherein the third interconnect contact is on the first beveled edge of the first substrate; and removing the mask layer and exposed portions of the seed layer; bonding the third interconnect contact to a first package substrate contact of a package substrate, the package substrate having a cavity, the first package substrate contact being on a sidewall of the cavity; bonding a first packaged die contact of a first packaged die to a second package substrate contact of the package substrate; bonding a second packaged die contact of the first packaged die to the first interconnect contact of the interconnect substrate; and bonding a third packaged die contact of a second packaged die to the second interconnect contact of the interconnect substrate.
16. The method of claim 15, wherein the first packaged die contact of the first packaged die is a different size than the second packaged die contact of the first packaged die.
17. The method of claim 15, wherein the first interconnect contact, the second interconnect contact, and the third interconnect contact have a same material layer structure.
18. The method of claim 15, wherein the first beveled edge of the first substrate of the first substrate is free of the redistribution layer.
19. The method of claim 15, wherein bonding the third interconnect contact to the first package substrate contact on the sidewall of the package substrate comprises using a solder joint.
20. The method of claim 15, wherein an upper surface of the interconnect substrate is level with an upper surface of the package substrate.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
(1) For a more complete understanding of the present disclosure, and the advantages thereof, reference is now made to the following descriptions taken in conjunction with the accompanying drawings, in which:
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(16) Corresponding numerals and symbols in the different figures generally refer to corresponding parts unless otherwise indicated. The figures are drawn to clearly illustrate the relevant aspects of the embodiments and are not necessarily drawn to scale.
DETAILED DESCRIPTION
(17) The making and using of the embodiments of the present disclosure are discussed in detail below. It should be appreciated, however, that the present disclosure provides many applicable inventive concepts that can be embodied in a wide variety of specific contexts. The specific embodiments discussed are illustrative and do not limit the scope of the disclosure.
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(19) Each packaged die, such as packaged die 110 includes at least a semiconductor die (not shown). The semiconductor die includes a semiconductor substrate as employed in a semiconductor integrated circuit fabrication, and integrated circuits may be formed therein and/or thereupon. The semiconductor substrate refers to any construction comprising semiconductor materials, including, but not limited to, bulk silicon, a semiconductor wafer, a silicon-on-insulator (SOI) substrate, or a silicon germanium substrate. Other semiconductor materials including group III, group IV, and group V elements may also be used. The semiconductor substrate may further comprise a plurality of isolation features (not shown), such as shallow trench isolation (STI) features or local oxidation of silicon (LOCOS) features. The isolation features may define and isolate the various microelectronic elements. Examples of the various microelectronic elements that may be formed in the semiconductor substrate include transistors (e.g., metal oxide semiconductor field effect transistors (MOSFET), complementary metal oxide semiconductor (CMOS) transistors, bipolar junction transistors (BJT), high voltage transistors, high frequency transistors, p-channel and/or n-channel field effect transistors (PFETs/NFETs), etc.); resistors; diodes; capacitors; inductors; fuses; and other suitable elements. Various processes are performed to form the various microelectronic elements including deposition, etching, implantation, photolithography, annealing, and/or other suitable processes. The microelectronic elements are interconnected to form the integrated circuit device, such as a logic device, memory device (e.g., SRAM), RF device, input/output (I/O) device, system-on-chip (SoC) device, combinations thereof, and other suitable types of devices.
(20) Interconnect substrate 120 may be made of a semiconductor wafer, or a portion of wafer. In some embodiments, interconnect substrate 120 includes silicon, gallium arsenide, silicon on insulator (“SOI”) or other similar materials. Interconnect substrate 120 includes interconnect structures or redistribution layer(s) (RDL) to electrically connect packaged die 110 and substrate 130. RDLs are interconnect structures near the surface of die packages or on packaging structures to facilitate electrical connections. In some embodiments, interconnect substrate 120 also includes passive devices such as resistors, capacitors, inductors and the like, or active devices such as transistors. In some embodiments, substrate 130 includes additional integrated circuits. Interconnect substrate 120 may further include through substrate vias (TSVs) and may be an interposer. In addition, the interconnect substrate 120 may be made of other materials. In some embodiments, interconnect substrate 120 also includes bismaleimide triazine (BT) resin, FR-4 (a composite material composed of woven fiberglass cloth with an epoxy resin binder that is flame resistant), ceramic, glass, molding compound, or other supporting materials that may carry the conductive pads or lands needed to receive conductive terminals.
(21) Substrate 130 may be made of a semiconductor wafer, or a portion of wafer. In some embodiments, substrate 130 includes silicon, gallium arsenide, silicon on insulator (“SOI”) or other similar materials. In some embodiments, substrate 130 also includes passive devices such as resistors, capacitors, inductors and the like, or active devices such as transistors. In some embodiments, substrate 130 includes additional integrated circuits. In addition, the substrate 130 may be made of other materials. For example, in some embodiments, substrate 130 is a multiple-layer circuit board. In some embodiments, substrate 130 also includes bismaleimide triazine (BT) resin, FR-4 (a composite material composed of woven fiberglass cloth with an epoxy resin binder that is flame resistant), ceramic, glass, plastic, tape, film, or other supporting materials that may carry the conductive pads or lands needed to receive conductive terminals.
(22) Packaged die 110 is bonded to interconnect substrate 120 via connectors 115, and interconnect substrate 120 is bonded to substrate 130 via connectors 125. If two or more packaged dies, such as packaged die 110 and other packaged die(s), with different sizes of connectors are bonded to interconnect substrate 120, the packaging mechanisms could be challenging. Further, the cost of manufacturing the die package, such as die package 100, also needs to be taken into consideration. Interconnect substrates 120 with TSVs, which are also called interposers, provide functions for electrical connection and heat dissipation. However, interposers are expensive. For some applications that require low-cost die packages, alternative die package structures and methods for forming them are needed.
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(28) A plating seed layer 304 is then formed on redistribution structure 302 as shown in
(29) After plating seed layer 304 is formed, a photoresist layer 305 is defined over it, as shown in
(30) Afterwards, a conductive layer 307 is plated on the surface of exposed plating seed layer 304, such as over the surfaces in openings 306 and over surfaces of exposed regions 306′, in accordance with some embodiments. The conductive layer 307 is made of copper, copper alloy, or a combination thereof in some embodiments. Following the formation of the first conductive layer 307, a solder layer 308 is formed over conductive layer 307. In some embodiments, both the conductive layer 307 and solder layer 308 are formed by plating processes.
(31) The thickness of conductive layer 307 and solder layer 308 over exposed regions 306′ are thicker than in openings 306 due to larger exposed surface area during plating processes. In some embodiments, the thickness of conductive layer 307 over exposed regions 306′ is in a range from about 12 μm to about 40 μm. In some embodiments, the thickness of solder layer 308 over exposed regions 306′ is in a range from about 5 μm to about 40 μm.
(32) After the formation of the conductive layer 307 and solder layer 308, the photoresist layer 305 is removed, as shown in
(33) After the photoresist layer 305 is removed and the etching of exposed plating seed layer 304, the conductive layer 307 and solder layer 308 in the openings 306 are exposed to form external connectors (or bump structures) 310. The exposed conductive layer 307 and solder layer 308 formed over the posed regions 306′ form contact structures 311.
(34) A reflow process is then conducted to reflow the solder layer 308 over the patterned conductive layer 307 to prepare external connectors 310 for bonding. The solder layer 308 covering the conductive layer 307 near over exposed regions 306′ is also reflowed to cover side wall(s) of conductive layer 307, as shown in
(35) Following the reflow process described above, substrate 301 is thinned down to a thickness T.sub.1, as shown in
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(37) The redistribution structure 402 includes one or more redistribution layers (RDLs), which are insulated by passivation layers. A plating seed layer 404 is then formed on redistribution structure 402 as shown in
(38) After plating seed layer 404 is formed, a photoresist layer 405 is deposited and patterned over it, as shown in
(39) Afterward the conductive layer 407 is formed and the photoresist layer 405 is removed, as shown in
(40) After photoresist layer 405 is removed, a photoresist layer 408 is deposited and patterned over substrate 401, as shown in
(41) Following the patterning of photoresist layer 408, a conductive layer 410 and a solder layer 411 are plated on substrate 401 to fill at least portions openings (409.sub.I) and (409.sub.II), as shown in
(42) Afterward the solder layer 407 is deposited and the photoresist layer 408 is removed, as shown in
(43) Following the reflow process described above, region 400 is singulated into individual piece from the entire substrate 401 and becomes packaged die 110.sub.A, which is ready for further packaging. The singulation process is a sawing process, in accordance with some embodiments.
(44) Packaged die 110.sub.B have one-size external connectors, as shown in
(45) After interconnect substrates 120′, packaged dies 110.sub.A, and packaged dies 110.sub.B are prepared or provided, they are assembled on substrates 130′.
(46) Substrate 130′ also includes an opening 502 to house interconnect substrate 120′.
(47) After the interconnect substrate 120′ is bonded to substrate 130′, packaged dies 110.sub.A and 110.sub.B are bonded to interconnect substrate 120′ and substrate 130′, as shown in
(48) After the electrical test is done, packaged die 110.sub.B is bonded to the remaining connectors 310 of interconnect substrate 120′ to form bonded structures 115.sub.B, in some embodiments. However, the electrical test can be optional. In some embodiments, another electrical test is performed after packaged die 110.sub.B is bonded. This other electrical test can check the quality of bonding of packaged die 110.sub.B to reduce waste of resources. After both packaged dies 110.sub.A and 110.sub.B are bonded to substrate 130′ and interconnect substrate 120′, a molding compound 512 is applied over substrate 130′ to cover packed dies 110.sub.A and 110.sub.B and to fill the space underneath packaged dies 110.sub.A and 110.sub.B, a shown in
(49) After the molding compound 512 is formed, external connectors (such as solder balls) 138′ are formed on bonding pads 506 to form die package 100′, as shown in
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(51) The formation mechanisms for interconnect substrate 120″ are similar to those of interconnect substrate 120′. The formation mechanisms for packaged dies 110.sub.C and 110.sub.D are similar to the formation mechanisms of packaged die 110.sub.B described above. Substrate 130″ is similar to substrate 130′; however, the interconnect structures and bonding structures on substrate 130″ could be arranged differently from substrate 130′.
(52) After interconnect substrate 120″, packaged die 110.sub.C, and packaged die 110.sub.D are prepared or provided, they are assembled on substrate 130″.
(53) Afterwards, interconnect substrate 120″ is attached to substrate 130″, such as by a glue layer (not shown), as mentioned above. In addition, electrical connection is made between interconnect substrate 120″ and substrate 130″.
(54) After packaged die 110.sub.D is bonded to interconnect substrate 120″, a molding compound 712 is formed over substrate 130″ to protect packaged dies (110.sub.C and 110.sub.D) and substrate (120″) and connecting structures (bonding structures between packaged dies and substrate 120″, and wire bonds 125″) over substrate 130″. In some embodiments, an underfill is first formed under packaged dies 110.sub.C and 110.sub.D prior to forming molding compound 712. However, forming the underfill first is optional. Some molding compound materials can also act as underfill to fill the space between packaged dies 110.sub.C/110.sub.D and substrate 120″. After the molding compound 712 is formed, external connectors 138″ are formed on the opposite side (opposite from bonded packaged dies 110.sub.C and 110.sub.D) to form die package 100″, as shown in
(55) The process flow described above to form die package 100″ is merely one embodiment. Other process flow may also be used. For example, interconnect substrate 120″ could have been placed on substrate 130″ first before packaged dies 110.sub.C and 110.sub.D being bonded to substrate 120″. Further, packaged die 110.sub.D could have been bonded to interconnect substrate 120″ before packaged die 110.sub.C. Choosing which die to bond first depends on the components on die package 100″ and how these components are used. For example, packaged die 110.sub.C may be bonded first because the testing of packaged die 110.sub.D could require the presence of package die 110.sub.C. Other considerations may be needed in deciding the sequence of bonding and whether to conduct electrical testing in the sequence of forming die package 100″.
(56) The embodiments described above show two packaged dies bonded in each die package, such as packaged dies 110.sub.A and 110.sub.B on die package 100′ or packaged dies 110.sub.C and 110.sub.D on die package 100″. There could be more than two packaged dies on each die package.
(57) As mentioned above in the description for
(58) Probing pads 910 can be used to test the quality and connectivity of the bonding structures formed between packaged dies 110.sub.A, 110.sub.B, and interconnect substrate 120′. To test connectivity between signal structures and power-source structures or between signal structures and ground structures, metal lines are needed to connect these structures. However, the electrical connections used for testing need to be disconnected after testing is completed to allow the devices in the packaged dies 110.sub.A and 110.sub.B to work.
(59) By placing electrical-test probers with probing pads 910.sub.A and 910.sub.C and supplying current and/or voltage between probing pads 910.sub.A and 910.sub.C various electrical tests can be performed. For example, to test the quality of bonding, a current can be applied between probing pads 910.sub.A and 910.sub.C. The voltages of probing pads 910.sub.A and 910.sub.C are then measured to calculate the resistance between probing pads 910.sub.A and 910.sub.C. The value of the resistance measured would reflect the quality of bonding. A value higher than an expected range could indicate improper bonding, such as cracking, mis-alignment, etc. The structures connected between probing pads 910.sub.A and 910.sub.C enable testing the connection to the grounding and signal structures.
(60) Similarly, probing pads 910.sub.B and 910.sub.C connect bonding structures 115.sub.B that are connected to “Signal 2”, “Power 1”, “Power 2”, and “Signal 4” structures through electrical lines 925 (lines with circles). By placing electrical-test probers with probing pads 910.sub.B and 910.sub.D and supplying current and/or voltage between probing pads 910.sub.B and 910.sub.D various electrical tests can be performed. For example, to test the quality of bonding, a current can be applied between probing pads 910.sub.B and 910.sub.D. The voltages of probing pads 910.sub.B and 910.sub.D are then measured to calculate the resistance between probing pads 910.sub.B and 910.sub.D. The value of the resistance measured would reflect the quality of bonding. A value higher than an expected range could indicate improper bonding, such as cracking, mis-alignment, etc. The structures connected between probing pads 910.sub.B and 910.sub.D enable testing the connection to the power and signal structures.
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(62) Metal lines 920 could be on the same RDL level or different RDL levels. Similarly, metal lines 920 could be on the same RDL level or different RDL levels. As described above, multiple levels of RDLs could be used to avoid metal line crossing.
(63) The structures in
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(65) Afterwards, packaged die 110.sub.B is bonded to interconnect substrate 120′. Probers 1120 are then lowered to contact probe pads 910 to make electrical tests, as shown in
(66) Traditionally, the quality of bonding of packaged dies can be tested after the die package is completed. The test structures and the probing structures on interconnect substrate described above enable testing without waiting until the die package is completed assembled. If electrical data reveal that packaged dies or bonding structures are less than perfect, they can be removed and be replaced by new packaged dies with newly formed bonding structures. However, such rework is not possible for finished die package, when the molding compound is formed. The mechanisms for forming test structures with probing pads and severing connecting metal lines after testing could reduce manufacturing cost.
(67) Embodiments of mechanisms for testing a die package with multiple packaged dies on a package substrate use an interconnect substrate to provide electrical connections between dies and the package substrate and to provide probing structures (or pads). Testing structures, including daisy-chain structures, with metal lines to connect bonding structures connected to signals, power source, and/or grounding structures are connected to probing structures on the interconnect substrate. The testing structures enable determining the quality of bonding and/or functionalities of packaged dies bonded. After electrical testing is completed, the metal lines connecting the probing structures and the bonding structures are severed to allow proper function of devices in the die package. The mechanisms for forming test structures with probing pads on interconnect substrate and severing connecting metal lines after testing could reduce manufacturing cost.
(68) In some embodiments, a semiconductor die package is provided. The semiconductor die package includes a first packaged die, and an interconnect substrate with a redistribution structure. The first packaged die is bonded to the redistribution structure, and the interconnect substrate includes a plurality of probing pads whose electrical connections to the first packaged die being severed. The semiconductor die package also includes a package substrate with an interconnect structure. The interconnect substrate is bonded to the package substrate, and wherein the package substrate is electrically connected to the first packaged die.
(69) In some other embodiments, a method of forming a semiconductor die package is provided. The method includes bonding an interconnect substrate to a package substrate, and bonding a first packaged die to the package substrate and to the interconnect substrate. The method also includes bonding a second packaged die to the interconnect substrate, and performing an electrical test on a plurality of test structures. The plurality of test structures include a plurality of probing pads electrically connected to devices in the first packaged die and the second packaged die by metal lines. The method further includes severing the metal lines to terminate electrical connection between the plurality of probing pads, the first packaged die, and the second packaged die.
(70) In yet some other embodiments, a method of forming a semiconductor die package is provided. The method includes bonding an interconnect substrate to a package substrate, and bonding a first packaged die to the package substrate and to the interconnect substrate. The method also includes bonding a second packaged die to the interconnect substrate, and performing an electrical test on a plurality of test structures. The plurality of test structures include a plurality of probing pads electrically connected to devices in the first packaged die and the second packaged die by metal lines. The method further includes severing the metal lines to terminate electrical connection between the plurality of probing pads, the first packaged die, and the second packaged die. In addition, the method includes forming a molding compound over the packaged substrate to cover the first packaged die and the second packaged die bonded to the package substrate and the interconnect substrate. Additionally, the method includes forming external connectors of the package substrate.
(71) In an embodiment, a semiconductor die package is provided. The package includes a first packaged die bonded to an interconnect substrate by a first plurality of bonding structures and a second packaged die bonded to the interconnect substrate by a second plurality of bonding structures. The package further includes a plurality of test structures, wherein the plurality of test structures comprises a plurality of probing pads, a first test structure of the plurality of test structures being electrically isolated from the first plurality of bonding structures, the second plurality of bonding structures, and other ones of the plurality of probing pads.
(72) In yet another embodiment a semiconductor die package is provided. The package includes a first packaged die bonded to an interconnect substrate by a first plurality of bonding structures and a second packaged die bonded to the interconnect substrate by a second plurality of bonding structures. The package further includes a test structure, wherein the test structure comprises a probing pad, a first line section and a second line section, the first line section having a first end and a second end, the first end terminating at the probing pad, the second line section having a third end and a fourth end, the third end terminating at one of the first plurality of bonding structures or one of the second plurality of bonding structures, the fourth end and the second end being disconnected and aligned. A molding compound is formed over the first packaged die, the second packaged die, and the interconnect substrate.
(73) In yet still another embodiment a semiconductor die package is provided. The package includes a first substrate bonded to an interconnect substrate by a first plurality of bonding structures and a second substrate bonded to the interconnect substrate by a second plurality of bonding structures. The package further includes a plurality of test structures on the interconnect substrate, wherein each of the plurality of test structures comprise a probing pad connected to a discontinuous conductive line, a first segment of the discontinuous conductive line coupled to a corresponding one of the first plurality of bonding structures or a corresponding one of the second plurality of bonding structures, a second segment of the discontinuous conductive line coupled to the probing pad, terminating ends of the first segment and the second segment being separated by a gap. A molding compound is formed over the first substrate, the second substrate, and the interconnect substrate.
(74) Although embodiments of the present disclosure and their advantages have been described in detail, it should be understood that various changes, substitutions and alterations can be made herein without departing from the spirit and scope of the disclosure as defined by the appended claims. For example, it will be readily understood by those skilled in the art that many of the features, functions, processes, and materials described herein may be varied while remaining within the scope of the present disclosure. Moreover, the scope of the present application is not intended to be limited to the particular embodiments of the process, machine, manufacture, composition of matter, means, methods and steps described in the specification. As one of ordinary skill in the art will readily appreciate from the disclosure of the present disclosure, processes, machines, manufacture, compositions of matter, means, methods, or steps, presently existing or later to be developed, that perform substantially the same function or achieve substantially the same result as the corresponding embodiments described herein may be utilized according to the present disclosure. Accordingly, the appended claims are intended to include within their scope such processes, machines, manufacture, compositions of matter, means, methods, or steps.