Reducing direct source-to-drain tunneling in field effect transistors with low effective mass channels
09564514 ยท 2017-02-07
Assignee
Inventors
- Anirban Basu (Lagrangeville, NY, US)
- Amlan Majumdar (White Plains, NY, US)
- Jeffrey W. Sleight (Ridgefield, CT, US)
Cpc classification
H10D62/83
ELECTRICITY
H10D64/021
ELECTRICITY
H10D64/018
ELECTRICITY
H10D62/824
ELECTRICITY
H10D30/6735
ELECTRICITY
H10D30/675
ELECTRICITY
H10D64/258
ELECTRICITY
H10D30/6757
ELECTRICITY
H10D62/822
ELECTRICITY
H10D62/10
ELECTRICITY
International classification
H01L29/74
ELECTRICITY
H01L29/423
ELECTRICITY
H01L29/20
ELECTRICITY
H01L29/66
ELECTRICITY
H01L29/06
ELECTRICITY
H01L29/10
ELECTRICITY
H01L29/16
ELECTRICITY
H01L29/205
ELECTRICITY
H01L29/417
ELECTRICITY
H01L29/786
ELECTRICITY
Abstract
An approach to providing a barrier in a vertical field effect transistor with low effective mass channel materials wherein the forming of the barrier includes forming a first source/drain contact on a semiconductor substrate and forming a channel with a first channel layer on the first source/drain contact. The approach further includes forming the barrier on the first channel layer, and a second channel layer on the barrier followed by forming a second source/drain contact on the second channel layer.
Claims
1. A semiconductor structure with a barrier for field effect transistors with low effective mass channel materials, comprising: a semiconductor substrate; a first source/drain layer on the semiconductor substrate; a first channel layer on the first source/drain layer; a barrier layer on the first channel layer; a second channel layer on the barrier layer, wherein the barrier layer is composed of a first semiconductor material with a lower electron affinity than a semiconductor material of the first channel layer and the second channel layer in a n-type field effect transistor; a second source/drain layer on the second channel layer; a gate electrode around a gate dielectric layer and over the gate dielectric layer on a portion of the first source/drain layer, the gate dielectric layer around at least a first dielectric spacer; a second dielectric spacer surrounding the gate electrode; a contact metal layer contacting the first source/drain layer and surrounding the second dielectric spacer; and an interlayer dielectric over the gate dielectric layer on the portion of the first source/drain layer and surrounding the contact metal layer.
2. The semiconductor structure of claim 1, wherein the first channel layer and the second channel layer are composed of a same semiconductor material and have a same doping.
3. The semiconductor structure of claim 1, wherein the barrier layer is composed of a group III-V semiconductor material in an n-type field effect transistor.
4. The semiconductor structure of claim 1, wherein the barrier layer is composed of a group IV semiconductor material or a compound group IV semiconductor material in a p-type field effect transistor.
5. The semiconductor structure of claim 1, wherein the barrier layer is doped in a range 10.sup.16 cm.sup.3 to 10.sup.18 cm.sup.3 with a channel type doping material.
6. The semiconductor structure of claim 1, further comprises wherein the barrier layer is in a center of the first channel layer and the second channel layer.
7. The semiconductor structure of claim 1, wherein the barrier layer has a bandgap in a range of 1 eV to 2 eV.
8. The semiconductor structure of claim 1, wherein a thickness of the barrier layer is in a range 2 nm to 10 nm.
9. The semiconductor structure of claim 1, further comprising a gate dielectric layer deposited over the semiconductor structure, wherein the gate dielectric layer is a high-k dielectric material.
10. The semiconductor structure of claim 1, wherein the first source/drain layer, the first channel layer, the second channel layer, and the barrier are circular in shape and form a pillar.
11. The semiconductor structure of claim 1, further comprises: wherein the first dielectric spacer surrounds the second channel layer, the second source/drain layer and a contact metal layer on the second source/drain layer; wherein the gate dielectric layer is around the second source/drain layer, the first channel layer, the barrier layer, the second channel layer, and at least the first dielectric spacer, and on the portion of the first source/drain layer; and wherein the second dielectric spacer surrounds a gate metal contact over a portion of the gate electrode.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
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DETAILED DESCRIPTION
(19) Detailed embodiments of the claimed structures and methods are disclosed herein. The method steps described below do not form a complete process flow for manufacturing integrated circuits. The present embodiments can be practiced in conjunction with the integrated circuit fabrication techniques currently used in the art, and only so much of the commonly practiced process steps are included as are necessary for an understanding of the described embodiments. The figures represent cross-section portions of a semiconductor chip or a semiconductor wafer during fabrication and are not drawn to scale, but instead are drawn to illustrate the features of the described embodiments. Specific structural and functional details disclosed herein are not to be interpreted as limiting, but merely as a representative basis for teaching one skilled in the art to variously employ the methods and structures of the present disclosure. In the description, details of well-known features and techniques may be omitted to avoid unnecessarily obscuring the presented embodiments.
(20) References in the specification to one embodiment, other embodiment, another embodiment, an embodiment, etc., indicate that the embodiment described may include a particular feature, structure or characteristic, but every embodiment may not necessarily include the particular feature, structure or characteristic. Moreover, such phrases are not necessarily referring to the same embodiment. Further, when a particular feature, structure, or characteristic is described in connection with an embodiment, it is understood that it is within the knowledge of one skilled in the art to affect such feature, structure or characteristic in connection with other embodiments whether or not explicitly described.
(21) For purposes of the description hereinafter, the terms upper, lower, right, left, vertical, horizontal, top, bottom, and derivatives thereof shall relate to the disclosed structures and methods, as oriented in the drawing figures. The terms overlying, atop, over, on, positioned on or positioned atop mean that a first element is present on a second element wherein intervening elements, such as an interface structure, may be present between the first element and the second element. The term direct contact means that a first element and a second element are connected without any intermediary conducting, insulating or semiconductor layers at the interface of the two elements.
(22) In the interest of not obscuring the presentation of the embodiments of the present invention, in the following detailed description, some of the processing steps or operations that are known in the art may have been combined together for presentation and for illustration purposes and in some instances may not have been described in detail. In other instances, some processing steps or operations that are known may not be mentioned at all. It should be understood that the following description is focused on the distinctive features or elements of the various embodiments of the present invention.
(23) New device engineering is indispensable in overcoming difficulties of advanced metal-oxide-semiconductor field effect transistors (MOSFETs) and realizing high performance large scale integrations under, for example, the 10 nm gate-length regime. In addition to the improvements of gate stacks using metal gate/high-k gate dielectrics, new channel materials with enhanced carrier transport properties are needed for enhancing the performance of MOSFET circuits and chips. Embodiments of the present invention, recognize that n-channel field effect transistors (NFETs) with group III-V semiconductor channels are considered a compelling candidate for extending the device scaling limits of low-power and high-speed circuit operation, owing to their enhanced carrier transport properties compared to those of silicon (Si). Similarly, silicon-germanium (hereinafter SiGe) p-channel FETs (PFETs) are also considered a compelling candidate for low power and high speed circuit operation in light of their improved hole transport properties compared to those in Si. Additionally, a vertical FET structure is commonly used with nanowires and in the nanometer regime, in part, to reduce lattice and thermal expansion mismatch between group III-V semiconductors and silicon reducing the contact area between group III-V semiconductor material and silicon. Vertical FET structures include source/drain contacts which reside above and below a channel in the FET. As known to one skilled in the art, in FET such as MOSFET devices, a source contact may be used as a drain contact and vice versa depending on device operation and for this reason, in embodiments of the present invention, the source contact and the drain contact are referred to as source/drain contacts.
(24) Embodiments of the present invention recognize that FETs with low effective mass channel materials can outperform traditional silicon based FETs due to higher effective velocity in spite of lower gate capacitance. However, at short gate lengths (e.g. short L.sub.g), low effective mass materials lead to high source to drain (S/D) tunneling current that increases OFF-state current, I.sub.off. I.sub.off for FET devices has three components: classical thermionic emission effected by barrier height, direct source-to-drain tunneling effected by barrier height and electron effective mass, and band-to-band tunneling (gate induced drain leakage or GIDL) effected by bandgap and effective mass. I.sub.off increases at smaller effective mass, smaller bandgap (e.g. smaller E.sub.g), and shorter gate length (e.g. shorter L.sub.g) due to increases in direct S/D tunneling and increases in band-to-band tunneling. Modeling results have shown that for a bandgap approximately greater than 0.7 eV (i.e. E.sub.g greater than or equal to 0.7 eV) with channel widths in the five to ten nm range, I.sub.off is not limited by GIDL or band-to-band tunneling, but I.sub.off is limited by direct S/D tunneling.
(25) Embodiments of the present invention include structures and methods to form FET devices with low effective mass materials to lower S/D current and lower I.sub.off. Using bandgap engineering principles and the semiconductor material properties including electron affinity for NFETs or bandgap and electron affinity for PFETs, a barrier layer is used in embodiments of the present invention to reduce leakage when the FET is in an off-state. The barrier layer provides an additional potential energy barrier for charge carriers. Electron affinity is the energy required to extract an electron from the bottom of the conduction band just inside the semiconductor to the vacuum just outside of the semiconductor. Thus, for NFETs, the barrier layer must have lower electron affinity than the other channel materials. For PFETs, the barrier layer must have a larger sum of bandgap and electron affinity than the other channel materials in order to act as a barrier. In general, both these conditions (e.g. low electron affinity in NFET and larger sum of bandgap and electron affinity in PFET) may be satisfied by larger bandgap materials. Therefore, in general, for the purposes of the embodiments of the present invention, the barrier layer may be considered as the layer with a larger bandgap and utilizing larger bandgap materials.
(26) Embodiments of the present invention further recognize significant reductions in I.sub.off may be achieved by inserting a barrier layer to reduce direct S/D tunneling. As will be illustrated and discussed relative to the Figures, and with device modeling calculations of I.sub.off, the barrier layer, due to the wider bandgap, provides a larger barrier height than the other channel semiconductor materials and, thus reduces direct S/D tunneling and I.sub.off. Additionally, device modeling calculations of I.sub.off show that a thicker barrier results in larger I.sub.off reductions. Furthermore, the device modeling calculations show that the placement of the barrier impacts I.sub.off. The device modeling calculations illustrate that a barrier placed in the middle of the channel provides the largest reduction in I.sub.off. Barrier placement in the middle of the channel is most effective since the top of the barrier which limits I.sub.off occurs near the middle of the channel in an electrostatically well-tempered FET.
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(31) The device modeling calculations of I.sub.off versus effective mass show that a thicker barrier reduces I.sub.off. The device modeling calculations also show a barrier with a larger bandgap (which has a larger additional barrier height, E.sub.B) reduces I.sub.off. Additionally, the device modeling calculations depicted in
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(33) Layer 10 may be a semiconductor substrate layer. In the exemplary embodiment, layer 10 is composed of a silicon material. In other embodiments, layer 10 may be composed of any other semiconductor material including, for example, SiGe, SiGeC, SiC, Ge alloys, Ga, GaAs, InAs, InP, or other III-V compound semiconductor materials. Layer 10 may be doped, undoped, or contain doped or undoped regions or, may be a layered semiconductor substrate such as a semiconductor-on-insulator substrate. Layer 10 may be strained, unstrained or be a combination thereof.
(34) Layer 11a and layer 11b may be heavily-doped source/drain layers. Layer 11a and layer 11b may be composed of a first semiconductor layer material with the same doping polarity as the device polarity. For example, a NFET may be doped with an n-type doping material such as silicon, tellurium, selenium, or other n-type doping material suitable for III-V NFETs. A PFET may be doped with a p-type doping material such as boron or other p-type material suitable for SiGe PFETs. The first semiconductor material used in layer 11a and 11b may be doped using conventional methods such as ion implantation or may be incorporated as a part of the epitaxial growth process (e.g. MBE or MOCVD). Layer 11a and layer 11b may form a first source/drain contact and a second source/drain contact respectively.
(35) Layer 11a and layer 11b may be composed of a first semiconductor material which may be a group IV semiconductor or a group III-V semiconductor material. A group IV semiconductor material, or in modern chemistry standardization terms, as provided by the International Union of Pure and Applied Chemistry (IUPAC), a group 14 element, refers to the location of the semiconductor element in a column of the Periodic Table of Elements. For the purposes of the present invention, location of elements or semiconductor materials, will utilize the traditional group designation for semiconductors (e.g. Group III, Group IV, Group V and Group III-V) rather than the IUPAC group designation. In embodiments of the present invention, a group III-V semiconductor material, referred to as an III-V semiconductor material hereafter, denotes a semiconductor material that includes at least one element or material from group III and at least one element or material from group V of the Periodic Table of Elements. Typically, each of the III-V semiconductor layers may be a binary, a ternary, or a quaternary III-V containing compound. Examples of III-V compound semiconductors that may be used include, but, are not limited to alloys of InGaAs, AlGaAs, InAlAs, InAlAsSb, InAlAsP and InGaAsP.
(36) In an embodiment of the present invention, layers 11a and 11b may be composed of III-V semiconductor materials in a NFET. For example, layers 11a and 11b may be composed of GaAs or InAs or an alloy of InGaAs in a NFET. In another embodiment, layers 11a and 11b are composed of SiGe or another semiconductor material such as a Group IV semiconductor material (e.g. Ge) in a PFET.
(37) Typically, III-V semiconductor materials used in the embodiments of the present invention, may be produced or deposited using epitaxial growth processes known to one skilled in the art, for example, atomic layer deposition (ALD), molecular beam epitaxy (MBE) or metal-organic chemical vapor deposition (MOCVD) although other deposition methods may be used in some embodiments. The semiconductor materials used in semiconductor layers 11a, 11b, 12a, 12b and 13 in wafer 100 may be formed as single crystal III-V semiconductor layer, single crystal IV semiconductor layer, or other suitable semiconductor layer with low defect density (less than 10.sup.5 defects/cm.sup.2).
(38) Layer 11a and layer 11b are not deposited in an immediate sequence, but, as depicted in
(39) Layer 12a may be deposited using known deposition methods such as ALD, MBE, MOCVD, or other appropriate deposition method on layer 11a while layer 12b may be similarly deposited on layer 13. Layer 12a and 12b form first channel layers which may be composed of a low bandgap semiconductor material which may have a smaller bandgap than the bandgap of layer 13 (i.e. barrier layer). As previously discussed, the term bandgap refers to the energy difference between the top of the valence band and the bottom of the conduction band (i.e. expressed in units of eV). Layer 12a and layer 12b may be composed of GaAs or InAs or an alloy of InGaAs in a NFET, for example. Layer 12a and 12b may be composed of SiGe or another semiconductor material such as a Group IV semiconductor material (e.g. Ge) for example, in a PFET. In one embodiment, the second semiconductor material in layer 12a and 12b may be the same as the first semiconductor material in layers 11a and 11b.
(40) In an embodiment, layer 12a and layer 12b are composed of a second semiconductor material with a bandgap that may be the same as the bandgap of the first semiconductor material. In another embodiment, the bandgap of the second semiconductor material in layers 12a and 12b is less than the bandgap for the first semiconductor material of layer 11a and 11b, which form the source/drain contacts. In one embodiment, the bandgap of the second semiconductor material of layers 12a and 12b is in the range of 0.3 eV to 1 eV. In an exemplary embodiment, the second semiconductor material in layer 12a and 12b is an alloy of InGaAs for NFETs and SiGe for PFETs. In another embodiment, layer 12a and 12b may be composed of at one of the following semiconductor materials: GaAs, InAs, AlGaAs, InAlAs, InAlAsSb, InAlAsP and InGaAsP for NFETs, and Ge for PFETs, or another semiconductor material.
(41) Layer 12a and layer 12b forming the first channel layers may be doped or undoped. Layer 12a and 12b may doped in-situ during epitaxial growth or using ion plantation, for example. In an exemplary embodiment, the semiconductor material of layer 12a and layer 12b may be doped using the same doping material as the channel doping material consistent with the FET type doping (i.e. NFET or PFET channel doping materials). In an embodiment, layer 12a and layer 12b is doped with a p-type doping material such as zinc in an III-V semiconductor material for a NFET. In another embodiment, layer 12a and layer 12b is doped with an n-type doping material such as arsenic or phosphorous for a SiGe PFET. In one embodiment, the second semiconductor material in layer 12a and layer 12b may be undoped. The first channel layers formed from layer 12a and 12b have low carrier effective mass, which will lead to higher carrier velocities and therefore, higher ON-state currents.
(42) In an exemplary embodiment, layer 12a and layer 12b may have a thickness range of 2 nm to 20 nm. In other embodiments, the thickness of layers 12a and 12b, the first channel layer, may have a different minimum thickness and/or a different maximum thickness for each of layer 12a and layer 12b. In the exemplary embodiment, layer 12a and layer 12b are depicted with approximately the same thickness.
(43) Layer 13 is composed of a barrier semiconductor material. Layer 13 acts as a barrier layer in the channel and reduces I.sub.off of the FET device. Layer 13 may be composed of a barrier semiconductor material which is a different semiconductor material than the first semiconductor material, layers 11a and 11b, and the second semiconductor material, layers 12a and 12b. Layer 13 may be doped or undoped. In one embodiment, layer 13 is undoped and may be composed of a barrier semiconductor material with a greater bandgap than the second semiconductor material. In another embodiment, layer 13 which acts a barrier layer may be doped. The doping material is consistent with the channel doping material for the FET application. For example, a NFET is doped with a p-type doping material used in III-V semiconductor materials, for example, zinc and a PFET is doped with an n-type doping material such as arsenic or phosphorous. Doping of layer 13 may be done with suitable processes such as ion implantation or an in-situ doping process where the doping atoms may be added during the initial semiconductor layer formation (e.g. during epitaxial growth).
(44) The barrier semiconductor material which composes layer 13 may be selected according to the FET type. In one embodiment, an NFET may use a first barrier semiconductor material in the barrier layer (i.e. layer 13) with an electron affinity that is less than the electron affinity of the second semiconductor material used in layers 12a and 12b, the first channel layers. The typical electron affinity of the third semiconductor in a NFET may be in the range of 3.5 eV to 5 eV, but, not limited to this range. In an exemplary embodiment, the third semiconductor material in layer 13 for an NFET is InAlAs. In another embodiment, other semiconductor materials such as GaAs, alloys of AlGaAs, alloys of InGaAs, another III-V semiconductor material, or other suitable semiconductor material may be used for layer 13. In the exemplary embodiment, the third semiconductor material, InAlAs for an NFET, may be undoped. In another embodiment, the third semiconductor material for an NFET is doped with doping material appropriate for a NFET. For example, a p-type doping material such as with zinc may be used in a NFET doping layer 13. The doping concentration for layer 13, the barrier layer, is typically in the range of 10.sup.16 cm.sup.3 to 10.sup.18 cm.sup.3.
(45) In another embodiment, the FET is a PFET using a second barrier semiconductor material (i.e. layer 13) with a combined electron affinity and bandgap that is greater than the combined electron affinity and bandgap of the second semiconductor material used in layers 12a and 12b (i.e. the first channel layer). Layer 13 may be composed of a group IV semiconductor material or a group IV semiconductor compound material for a PFET in an embodiment. In one embodiment, the third semiconductor material in a PFET may be undoped Si. In another embodiment, the third semiconductor of layer 13 is SiGe with high Si content and the second semiconductor material such as SiGe with high Ge content or Ge. In another embodiment, layer 13 may be doped with n-type doping concentration in the range of 10.sup.16 cm.sup.3 to 10.sup.18 cm.sup.3.
(46) In an exemplary embodiment, layer 13 may have a thickness in the range of 2 nm to 10 nm. The thickness of layer 13 corresponds to the length of the barrier, L.sub.B in
(47) In an exemplary embodiment, layer 13 resides midway between layers 11a and 11b and, ideally, is equidistant from the closest surface of layer 11a (i.e. source layer) and the closest surface of layer 11b (i.e. drain layer). Layer 13 functions most effectively as a barrier layer to reduce I.sub.off in the semiconductor device illustrated in
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(53) In the exemplary embodiment, a gate electrode layer depicted as layer 17 is deposited on the gate dielectric layer (i.e. layer 17 covers layer 16). The gate electrode layer or layer 17 may be deposited by a known deposition method such as MBE, CVD, PECVD, ALD, PVD or other similar deposition methods. Layer 17 may be any suitable conductive material for a gate electrode. In the exemplary embodiment, the gate electrode is formed from layer 17 which may be titanium nitride. In an embodiment, the gate electrode may be one of the following metals: tungsten, tantalum, tantalum nitride, platinum, or gold. In another embodiment, the gate electrode or gate may be other conductive materials, for example, polysilicon, polysilicon germanium, polygermanium, conductive metal alloys, conductive nitrides, conductive oxides, and similar conductive materials or combination of conductive materials or layers. In some embodiments, the gate or gate electrode consisting of polysilicon, polysilicon germanium, or polygermanium may be doped with doping materials such as aluminum, boron, arsenic, phosphorous, antimony, gallium, or mixtures thereof.
(54) In an exemplary embodiment, a CMP is performed on the gate electrode, layer 17, stopping when reaching layer 14 and layer 15, the first dielectric layer and the spacer, respectively. In some embodiments, gate dielectric layer, layer 16 may be removed from the top surfaces of layer 14 and layer 15 by CMP.
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(56) A third dielectric layer, layer 18 may be deposited on the top surface of the gate electrode of layer 17. The third dielectric layer deposited by a known deposition method such as MBE, CVD, PECVD, ALD, PVD, or other similar dielectric deposition process. The third dielectric layer, layer 18, may be composed of a SiO.sub.2 dielectric material in the exemplary embodiment. The third dielectric material may also be a dielectric material such as SiN, SiON, or a high-K dielectric. In an embodiment, the third dielectric material may be the same dielectric material as the first dielectric material but, it may not be the same material as the second dielectric. In one embodiment, a CMP may be performed on the top surface of layer 18 to form a planar surface.
(57) Layer 18 may be etched with a suitable etch process to form the second spacer. The second spacer composed of the third dielectric material of layer 18 wraps around the gate dielectric (i.e. layer 16), the first spacer composed of layer 15, and first dielectric layer, layer 14. In the exemplary embodiment, the second spacer made from layer 18 forms a ring around the gate dielectric layer which is layer 16. In the exemplary embodiment, the width of the second spacer formed from layer 18 is in the range of 5 nm to 50 nm. In other embodiments, the width of the second spacer may be different. For example, the width of the second spacer could be less than 5 nm. In an embodiment, the shape of the second spacer may be different. For example, the second spacer may be a box.
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(60) Layer 19 may be composed of a fourth dielectric material. In an embodiment, the fourth dielectric of layer 19 may be the same as the second dielectric material. However, the fourth dielectric material may be not the same material as the first dielectric material or the third dielectric material. In another embodiment, the fourth dielectric material may be another dielectric such as SiN. In the exemplary embodiment, the fourth dielectric material may be a high-k dielectric material, for example, hafnium silicate or hafnium oxide. In one embodiment, a CMP process may be used to form a planar surface for layer 19. Layer 19 may be etched using a suitable etch process, for example, RIE, to the top of the gate dielectric layer (i.e. layer 16). The third spacer composed of the fourth dielectric material wraps around the gate electrode (layer 17) and the second spacer (i.e. layer 18). The thickness of layer 19 may be in the range of 5 nm to 50 nm.
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(69) In some embodiments, the wafers formed by the embodiments of the present invention may be diced in semiconductor chip form. The resulting semiconductor chips can be distributed by the fabricator in raw wafer form (that is, as a single wafer that has multiple unpackaged chips), as a bare die or in a packaged form. In the latter case, the chip is mounted in a single chip package (such as a plastic carrier, with lead that is affixed to a motherboard or other higher level carrier) or in a multichip package (such as a ceramic carrier that has either or both surface interconnections or buried interconnections). In any case the chip is then integrated with other chips, discreet circuit elements, and motherboard or (b) end product. The end product can be any product that includes integrated circuit chips, ranging from toys and other low-end applications to advanced computer products having a display, a keyboard or other input device and a central processor.