System, a use of such a system and a multi system for cleaning exhaust gas
09844752 · 2017-12-19
Assignee
Inventors
Cpc classification
B01D2259/4566
PERFORMING OPERATIONS; TRANSPORTING
F02M26/15
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F01N2590/02
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
B01D53/507
PERFORMING OPERATIONS; TRANSPORTING
Y02T10/12
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
F01N3/085
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F01N3/04
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F01N2570/04
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
B01D53/96
PERFORMING OPERATIONS; TRANSPORTING
International classification
F01N3/04
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F01N3/08
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
B01D53/96
PERFORMING OPERATIONS; TRANSPORTING
F02M26/15
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
Abstract
A system, a use of such a system and a multi system for cleaning exhaust gas from a combustion engine. The system comprises a first exhaust gas scrubber to communicate with a scrubber water circulation tank. A first outlet of the first exhaust gas scrubber is connectable to a first inlet of the scrubber water circulation tank, and a first inlet of the first exhaust gas scrubber is connectable to a first outlet of the scrubber water circulation tank, to enable circulation of scrubber water between the scrubber water circulation tank and the first exhaust gas scrubber. An air supply device feeds air into the first exhaust gas scrubber to aerate the scrubber water during its passage through the first exhaust gas scrubber. Accordingly, a second inlet of the first exhaust gas scrubber is arranged to be connected to an outlet of the air supply device.
Claims
1. A system for cleaning exhaust gas (EG) from a combustion engine, comprising a first exhaust gas scrubber connected to a scrubber water circulation tank to communicate with the scrubber water circulation tank, a first outlet of the first exhaust gas scrubber being connected to a first inlet of the scrubber water circulation tank and a first inlet of the first exhaust gas scrubber being connected to a first outlet of the scrubber water circulation tank to enable circulation of scrubber water between the scrubber water circulation tank and the first exhaust gas scrubber, an air supply device connected to the first exhaust gas scrubber to feed air into the first exhaust gas scrubber to aerate the scrubber water during its passage through the first exhaust gas scrubber, a second inlet of the first exhaust gas scrubber being connected to an outlet of the air supply device, and means for chemicals supply to a flow of scrubber water from a second outlet of the scrubber water circulation tank.
2. A system according to claim 1, wherein the air supply device is connected to the first exhaust gas scrubber to feed air into the first exhaust gas scrubber when no exhaust gas (EG) from the combustion engine is fed into the first exhaust gas scrubber.
3. A system according to claim 1, wherein the second inlet of the first exhaust gas scrubber is connected to an outlet of the combustion engine.
4. A system according to claim 1, wherein the air supply device is a purge air fan.
5. A system according to claim 1, wherein the means for chemicals supply supplies at least one of hydrogen peroxide (H.sub.2O.sub.2) and an alkaline agent.
6. A system according to claim 1, further comprising an analytical equipment to evaluate a degree of oxidation of sulphites in the aerated scrubber water.
7. A multi system for cleaning exhaust gas (EG) from a combustion engine comprising a system according to claim 1 and a second exhaust gas scrubber connected to the scrubber water circulation tank to communicate with the scrubber water circulation tank and enable circulation of scrubber water between the scrubber water circulation tank and the second exhaust gas scrubber, wherein the second exhaust gas scrubber is receives and cleans the exhaust gas (EG) while the first exhaust gas scrubber aerates the scrubber water during its passage through the first exhaust gas scrubber.
8. A multi system according to claim 7, comprising a third exhaust gas scrubber connected to the scrubber water circulation tank to communicate with the scrubber water circulation tank and enable circulation of scrubber water between the scrubber water circulation tank and the third exhaust gas scrubber.
9. A multi system according to claim 7, wherein one of said exhaust gas scrubbers is of EGR type.
10. Use of a system according to claim 1 for alternating operation between aeration of scrubber water during its passage through the first exhaust gas scrubber and cleaning of exhaust gas (EG) from the combustion engine.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
(1) Embodiments of the invention will now be described, by way of example, with reference to the accompanying schematic drawings, in which
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DETAILED DESCRIPTION
(7) Before going into details of the invention, the general principle of an exhaust gas scrubber will be described.
(8) A typical exhaust gas scrubber to be used on-board a ship is a so called wet scrubber of the EGC type (Exhaust Gas Cleaning). A wet EGC scrubber process as such is well known in the art and the general idea is to remove particulate matter such as soot, oil and heavy metals in the exhaust gas from a combustion engine, such as a diesel engine on-board a ship, and at the same time wash out acid gases such as SO.sub.X from the exhaust gas by a flow of water. SO.sub.X is formed during the combustion process when sulphur in the fuel combines with oxygen. The basic principle when using wet scrubbers is that the SO.sub.X is neutralized and bound as sulphates or sulphites when reacting with the alkaline water used in the EGC scrubber.
(9) A typical example of an exhaust gas scrubber 1 of the wet scrubber type is disclosed in
(10) To further improve the removal efficiency of the exhaust gas scrubber 1, the residence time of the exhaust gas EG in the second chamber 7 may be increased. Alternatively, the available surface area inside the second chamber 7 may be increased by causing a larger contact surface with the exhaust gas EG. Well known techniques for this purpose is the use of spray nozzles, packed towers or an aspirator (not disclosed).
(11) The thus cleaned exhaust gas EG may be emitted into the ambient air via the outlet 10 after a quality control (not disclosed) ensuring that it meets legislated emission levels.
(12) An exhaust gas scrubber 1 may in general use seawater or freshwater, or even a mixture thereof.
(13) Now referring to
(14) Starting with the scrubber process loop 13, this comprises the scrubber water circulation tank 15 having a first inlet 17 and a second inlet 18. The first inlet 17 is arranged in communication with a first outlet 11 of the first exhaust gas scrubber 1a forming part of the scrubber process loop 13. The second inlet 18 is arranged in communication with the pre-treatment process loop 16.
(15) Further, the scrubber water circulation tank 15 has a first outlet 20 arranged in communication, via a main pump 23, with a first inlet 21 of the first exhaust gas scrubber 1a. A second outlet 33 of the scrubber water circulation tank 15 is arranged in communication with the pre-treatment process loop 16.
(16) The scrubber process loop 13 is to be regarded as a closed loop.
(17) The first exhaust gas scrubber 1a is arranged to be fed with a flow of fresh air from an air supply device in the form of a purge air fan 24. For this purpose, an outlet 12 of the purge air fan 24 is arranged in communication with a second inlet 4 of the first exhaust gas scrubber 1a. The used fresh air is arranged to be let out from the first exhaust gas scrubber via a second outlet 10. The second outlet 10 could be a separate outlet of the first exhaust gas scrubber 1a. However, in the system 100 illustrated in
(18) The pre-treatment process loop 16 is connected to the scrubber process loop 13 via the second outlet 33 and the second inlet 18 of the scrubber water circulation tank 15.
(19) Starting from the second outlet 33 of the scrubber water circulation tank 15, the pre-treatment process loop 16 comprises a piping comprising a first inlet 26 comprising a first valve 27 and second inlet 29 comprising a second valve 30. The first valve 27 is connected to a supply 28 of an alkaline agent, such as NaOH (sodium hydroxide) or Na.sub.2CO.sub.3 (sodium carbonate), allowing a controlled supply of the alkaline agent to the pre-treatment process loop 16. The second valve 30 is connected to a supply 31 of H.sub.2O.sub.2 (hydrogen peroxide) allowing a controlled supply of H.sub.2O.sub.2 to the pre-treatment process loop 16. In the claims, the first and second inlets 26 & 29, the first and second valves 27 & 30, and the supplies 28 & 31, are referred to as means for chemicals supply. It is to be understood that the positions of the means for chemicals supply may be altered. Downstream of the second inlet 29 is a water cleaning unit 32.
(20) The purpose of the water cleaning unit 32 is to minimize the amount of particulate matter being transferred back to the scrubber water circulation tank 15 or being discharged to the sea. Water cleaning units 32 as such are well known in the art. It may by way of example be a separator in the form of a high speed separator, a filter, a hydro cyclone or the like. Particulate matter collected by the water cleaning unit 32 may be stored in a tank (not disclosed) for later delivery at suitable reception facilities, while the cleaned scrubber water may be discharged overboard directly from the water cleaning unit 32 via an outlet 34. The water cleaned by the water cleaning unit 32 may alternatively be returned into the scrubber water circulation tank 15 via its second inlet 18.
(21) It is to be understood that the cleaned scrubber water to be discharged overboard may undergo a quality control 41 before being discharged.
(22) In some cases it might be suitable to arrange a small buffer tank (not disclosed) in a position between the water cleaning unit 32 and the inlets 26, 29 for supply of alkaline agent and H.sub.2O.sub.2. The purpose of such a buffer tank is to allow a sufficient dwell time for the chemicals supplied to the scrubber water to intermix and react therewith before reaching the water cleaning unit 32.
(23) In the following the operation of the system 100 will be discussed. The system may be operated in two different modes, either an exhaust gas cleaning mode or an aeration mode. During operation of the system 100 scrubber water is continuously circulated through the first exhaust gas scrubber 1a and either exhaust gas or air, depending on the mode of operation, is pumped into the first exhaust gas scrubber 1a and thus the circulating scrubber water.
(24) Starting with exhaust gas cleaning mode, reference is made to the initial paragraphs of the detailed description describing the overall function of an exhaust gas scrubber. Exhaust gas (EG) is fed from the combustion engine 2 to the first exhaust gas scrubber 1a. Accordingly, an outlet 19 of the combustion engine 2 is arranged to communicate with the second inlet 4 of the first exhaust gas scrubber 1a. The scrubber water is circulated in the scrubber process loop 13 from the first exhaust gas scrubber 1a via the scrubber water circulation tank 15 and back to the first exhaust gas scrubber 1a. During this circulation, the SO.sub.X contained in the exhaust gas reacts with the inherently alkaline scrubber water, whereby the SO.sub.X is absorbed in the scrubber water. If the inherent alkalinity is insufficient, a supply of an alkaline agent may be made in the scrubber process loop. Further, particulate matter contained in the exhaust gas will be washed out and accumulated in the circulating scrubber water. The thus circulating scrubber water will typically have a pH of 7-8.
(25) During the exhaust gas cleaning mode, the amount of washed out particulate matter will accumulate in the circulating scrubber water.
(26) To allow a treatment of the thus circulating scrubber water, a part stream or flow, or a full stream or flow, of scrubber water from the second outlet 33 of the scrubber water circulation tank 15 is let through the pre-treatment process loop 16.
(27) During the passage through the pre-treatment process loop 16, alkaline agent may be added to the scrubber water via the first inlet 26.
(28) The purpose of the addition of the alkaline agent is to adjust the pH value of the scrubber water by increasing the pH to a value within the range of 8-10 and more preferred to a range of 8.5-9.5. By the addition of an alkaline agent to the scrubber water in a position upstream the water cleaning unit 32, it has been shown that the efficiency of the particle separation to follow will be increased.
(29) Further, while passing the second inlet 29 an optional addition of H.sub.2O.sub.2 (hydrogen peroxide) may be made. Hydrogen peroxide is very reactive with inorganic compounds contained in the scrubber water, whereby a very fast oxidization of the sulphites in the scrubber water is made possible. Thus, the supply of hydrogen peroxide may be used to further lower the COD value in line with the equations (1)-(3) discussed above.
(30) Depending on the presence of any buffer tank (not disclosed) in the pre-treatment process loop 16, the resulting mixture of alkaline agent, H.sub.2O.sub.2 and scrubber water may be allowed to either stay in the buffer tank during a certain dwell time before being fed to the water cleaning unit 32, or be fed directly into the water cleaning unit 32.
(31) The separated particulate matter will be stored in a suitable tank while the cleaned scrubber water either will be circulated back into the scrubber process loop 13 or be discharged overboard (via 41).
(32) It is to be understood that the flow of scrubber water to the pre-treatment process loop 16 may be continuous or dis-continuous.
(33) Accordingly, during the exhaust cleaning mode, SOx will be washed out from the exhaust gas while at the same time, either continuously or dis-continuously, particulate matter may be separated from the circulating scrubber water and the oxygen content of the circulating scrubber water may be increased by a supply of H.sub.2O.sub.2.
(34) Now turning to the aeration mode. The system 100 may be operated in an aeration mode during a stand-still of the combustion engine 2, i.e. when no exhaust gas from the combustion engine 2 is fed into the first exhaust gas scrubber 1a. During such stand-still, the first exhaust gas scrubber 1a will instead of being supplied with exhaust gas, be fed with fresh air from the purge air fan 24. During the supply of fresh air by the purge air fan 24, the scrubber process loop 13 will be operated by circulating scrubber water from the scrubber water circulation tank 15 via the first exhaust gas scrubber 1a, aerating the same.
(35) The purge air fan 24 may be electrically driven or be driven by an auxiliary combustion engine (not disclosed).
(36) By the aeration, the oxygen level in the scrubber water passing the first exhaust gas scrubber 1a will be increased. Referring back to equations (1)-(3) and the discussion thereof given above, this means that the amount of oxygen present in the scrubber water will be increased to a level high enough to ensure that the process described by equations (1)-(3) will proceed with a complete oxidation of the SO.sub.2 absorbed in the scrubber water. Accordingly, the COD value may be kept low and within legislated levels.
(37) Based on experience, it is estimated that the aeration mode should be kept in operation for approximately 30-60 minutes to ensure an almost complete oxidation of the sulphites. However, the system 100 comprises an analytical equipment 14 arranged upstream the water cleaning unit 32 in the pre-treatment process loop 16 and including oxygen sensors or redox probes to determine when the aeration process has reached a sufficient level. By a redox probe is meant a probe measuring the reduction potential (also known as redox potential). The reduction potential is a measure of the tendency of a chemical species to acquire electrons and thereby be reduced. Reduction potential is measured in volts (V), or millivolts (mV). Each species has its own intrinsic reduction potential; the more positive the potential, the greater the species' affinity for electrons and tendency to be reduced.
(38) When it is determined that the aeration process has reached a sufficient level, the scrubber water is not further aerated. This is because the risk of corrosion in the water cleaning unit increases with an increasing oxygen level of the scrubber water.
(39) In
(40) Now turning to
(41) The multi system differs from the systems of
(42) The advantage of a multi system according to
(43) This provides a more redundant system, as the scrubbing is not solely relying on a single scrubber.
(44) It goes without saying that all exhaust gas scrubbers 1a, 1b may at one and the same time be operated in either exhaust gas cleaning mode or aeration mode.
(45) The operational philosophy of the multi system 102 is that while the ship is in harbor the main combustion engine 2 is not in operation, i.e. it is in a stand-still state. Hence, only one of the exhaust gas scrubbers 1a, 1b, typically the smallest first exhaust gas scrubber 1a, may be operated in exhaust gas cleaning mode to thereby clean exhaust gas from an auxiliary engine (not disclosed) required to operate the required facilities onboard. In this mode of operation, the other exhaust gas scrubber, typically the larger second exhaust gas scrubber 1b, may be used, in combination with the purge air fan 24, for scrubber water aeration, wherein fresh air is blown into the larger exhaust gas scrubber 1b via the purge air fan 24. When the main combustion engine 2 starts up, the exhaust gas from both the main combustion engine and the auxiliary engine may be gathered and cleaned in the second exhaust gas scrubber 1b. This releases the first exhaust gas scrubber 1a so that this may now be used in combination with the purge air fan 24 for aeration of the circulating scrubber water, wherein fresh air is blown into the smaller exhaust gas scrubber 1a via the purge air fan 24.
(46) It is to be understood that each exhaust gas scrubber 1a, 1b may be provided with its own purge air fan 24. It is also to be understood that the purge air and the exhaust gas may be fed into the respective exhaust gas scrubbers through the same inlet instead of, as illustrated, through separate inlets.
(47) As described above, at least a part flow of the circulating scrubber water may be fed into the pre-treatment process loop 16 where an alkaline agent may be added to the scrubber water for facilitating separation of particulate matter, and H.sub.2O.sub.2 may be added to the scrubber water for further aeration of it.
(48) Based on experience, it is estimated that the aeration mode should be kept in operation for approximately 30-60 minutes to ensure an almost complete oxidation of the sulphites. Analytical instruments (not disclosed) such as oxygen sensors or redox probes may be used to determine when the aeration process has reached a sufficient level.
(49) Now turning to
(50) The multi system disclosed in
(51) EGR scrubber processes as such are well known in the art and the general idea is to reduce the amount of nitrogen oxide (NO.sub.X) in the exhaust gas to be emitted from the combustion engine 2, such as a diesel engine on-board a ship. The EGR scrubber 52 as such is a so called wet scrubber based on the same principle as the EGC scrubbers 1a and 1b. However, as a major difference to an EGC scrubber, an EGR scrubber only cleans a portion of the exhaust gas, which is re-circulated back into the combustion chamber of the combustion engine for the purpose of reducing the level of NO.sub.X. Approximately up to 40% of the exhaust gas may be re-circulated back into the combustion engine 2. The re-circulated exhaust gas replaces some of the excess oxygen in the resulting pre-combustion mixture. The thus lowered oxygen level increases the level of carbon dioxide (CO.sub.2). NO.sub.X is primarily formed when a mixture of nitrogen and oxygen is subjected to a high temperature. However, the combustion air circulated back to the combustion engine 2 through the EGR scrubber has the effect that the combustion temperature is reduced. Consequently the level of NO.sub.X formed in the exhaust gas may be reduced. Like the EGC scrubbers 1a and 1b, the EGR scrubber 52 may in general use seawater or freshwater, or even a combination thereof.
(52) The operation of the multi system 103 is in all essential parts the same as previously discussed. To avoid undue repetition, where suitable, reference is made to the embodiment discussed in view of
(53) As mentioned above, the major difference is that the scrubber water circulation tank 15 is further connected to the scrubber water circulation loop 50 comprising the pump 51 and the third exhaust gas scrubber 52. Accordingly, the scrubber water is not only circulated in the scrubber process loop 13 via the first and second exhaust gas scrubbers 1a, 1b and in the pre-treatment process loop 16 but also in the scrubber water circulation loop 50 serving the third exhaust gas scrubber 52.
(54) The operational philosophy of the multi system 103 is that while the ship is in harbor the main combustion engine 2 is not in operation, i.e. it is in a stand-still state. Hence, only one of the EGC exhaust gas scrubbers 1a, 1b, typically the smallest first exhaust gas scrubber 1a, may be operated in exhaust gas cleaning mode to thereby clean exhaust gas from an auxiliary engine (not disclosed) required to operate the required facilities onboard. In this mode of operation, the other EGC exhaust gas scrubber, typically the larger second exhaust gas scrubber 1b, may be used for scrubber water aeration. The EGR or third exhaust gas scrubber 52 may be idle or operated to re-circulate exhaust gas into the auxiliary engine (not illustrated). A separate EGR scrubber (not illustrated) could be provided for the auxiliary engine.
(55) When the main combustion engine 2 starts up, the exhaust gas from both the main combustion engine 2 and the auxiliary engine may be gathered and cleaned in the second exhaust gas scrubber 1b. This releases the first exhaust gas scrubber 1a so that this may now be used for scrubber water aeration. During operation of the main combustion engine 2, the third exhaust gas scrubber 52 is operated to re-circulate exhaust gas into the engine 2 and possibly also the auxiliary engine (not illustrated).
(56) It is to be understood that each exhaust gas scrubber 1a, 1b may be provided with its own purge air fan 24.
(57) As described above, at least a part flow of the circulating scrubber water may be fed into the pre-treatment process loop 16 where alkaline agent may be added to the scrubber water for facilitating separation of particulate matter, and H.sub.2O.sub.2 may be added to the scrubber water for further aeration of it.
(58) Based on experience, it is estimated that the aeration mode should be kept in operation for approximately 30-60 minutes to ensure an almost complete oxidation of the sulphites. Analytical instruments (not disclosed) such as oxygen sensors or redox probes may be used to determine when the aeration process has reached a sufficient level.
(59) It is to be understood that also the EGR scrubber 52 may be set to be operated in an aeration mode.
(60) It goes without saying that the first, second and third exhaust gas scrubbers 1a, 1b and 52 may at one and the same time be operated in either exhaust gas cleaning mode or aeration mode.
(61) Throughout the description, the embodiments of the invention have been based on an embodiment of an exhaust gas scrubber 1a, 1b and 52 comprising a first and a second chamber 3, 7 respectively, wherein the main purpose of the first chamber 3 is to rapidly cool down the exhaust gas from the combustion engine 2. It is to be understood that the step of cooling down may be omitted and hence also the first chamber 3.
(62) It is also to be understood that there are numerous exhaust gas scrubbers available on the market and that the invention should not be limited to the design and the operation of the individual exhaust gas scrubber, no matter if it is a scrubber of the EGC or EGR type. By way of example, it is possible to use so called multiple inlet scrubbers allowing a plurality of combustion engines to be connected thereto.
(63) Further, it is to be understood that there are numerous water cleaning units available for the purpose of separating particulate matter from a liquid, whereby the invention should not be limited to the embodiments described.
(64) Also, other air supply devices than purge air fans may be used in connection with the present invention, such as a blower, a compressor, etc.
(65) Furthermore, the exhaust gas scrubbers of a multi system according to the invention need not share one and the same scrubber water circulation tank but may communicate with one scrubber water circulation tank each.
(66) The analytical equipment 14 need not be positioned according to
(67) The quality of the circulating scrubber water and also the quality of the water to be discharged may be checked by a quality control system QC well known in the art. The quality system may by way of example comprise a plurality of sensors. As non-limiting examples, one or several of the following sensors may be used: pH sensors, oxygen sensors, redox probes, turbidity sensors and PAH-sensors (Poly Aromatic Hydrocarbon).
(68) Finally, the hydrogen peroxide and/or the alkaline agent need not be supplied to the scrubber water before it is fed to the water cleaning unit but could instead be supplied to the cleaned scrubber water when this leaves the water cleaning unit.
(69) From the description above follows that, although various embodiments of the invention have been described and shown, the invention is not restricted thereto, but may also be embodied in other ways within the scope of the subject-matter defined in the following claims.