STA-19, a molecular sieve having a GME structure and phosphorus in the framework, is described. STA-19AP (as prepared) can have a lower alkyl amine, such as trimethylamine, and olig-(1,4-diazabicyclo[2.2.2]octane)-pentyl dibromide ([DABCO-C5].sub.x where x represents the number of repeating units) or olig-(1,4-diazabicyclo[2.2.2] octane)-hexyl dibromide ([DABCO-C6].sub.x) as SDAs. A lower alkyl ammonium hydroxide, such as tetrabutylammonium hydroxide (TBAOH), can be used as a pH modifier for the preparation of SAPO-STA-19. A calcined product, STA-19C, formed from STA-19AP is also described. Methods of preparing STA-19AP, STA-19C and metal containing calcined counterparts of STA-19C are described along with methods of using STA-19C and metal containing calcined counterparts of STA-19C in a variety of processes, such as treating exhaust gases and converting methanol to olefins are described.

Provided is a honeycomb catalyst in which a plurality of through holes are provided in proximity to each other in a row arrangement in the lengthwise direction, and are set apart by partitions. A honeycomb unit contains at least two types of inorganic particles and an inorganic binder. The inorganic particles contain zeolite having an SiO2/Al2O3 composition ratio of less than 15 and a CHA structure and an oxide other than zeolite, which has a positive thermal expansion coefficient. The ratio (X:Y) of the volume (X) of zeolite and the volume (Y) of oxide is 50:50 to 80:20. A displacement amount of absorbed water is reduced and cracking is controlled while maintaining high NOx purging performance.

The present invention relates to a method for the preparation of a molecular sieve of the CHA-type as well as catalytic applications thereof.

A catalyst article having an extruded support having a plurality of channels through which exhaust gas flows during operation of an engine, and a single layer coating or a bi-layer coating on the support, where the extruded support contains a third SCR catalyst, the single layer coating and the bilayer-coating contain platinum on a support with low ammonia storage and a first SCR catalyst. The catalytic articles are useful for selective catalytic reduction (SCR) of NOx in exhaust gases and in reducing the amount of ammonia slip. Methods for producing such articles are described. Methods of using the catalytic articles in an SCR process, where the amount of ammonia slip is reduced, are also described.

The problem to be solved by the present invention is to provide a good NOx selective reduction catalyst. To solve the problem is a NOx selective reduction catalyst containing a composite oxide of Ti, Ce, W, and P or S.

An exhaust gas purification system for an internal combustion engine is provided with a filter including a selective catalytic reduction NOx catalyst carried thereon. Further, a post-catalyst is provided for an exhaust gas passage disposed on a downstream side from the filter. The post-catalyst has an oxidizing function, and the post-catalyst has such a function that the production of N.sub.2 based on the oxidation of ammonia is facilitated in a predetermined first temperature area. A filter regeneration process execution unit is programmed to control the temperature of the post-catalyst to be in the first temperature area while adjusting the temperature of the filter to be in a predetermined second temperature area lower than a filter regeneration temperature during a certain period of time.

A catalyst composition comprising a mixture of (a) a zeolite compound in an amount of from 10% to 60% by weight, wherein the zeolite compound comprises cations selected from Fe.sup.2+, Fe.sup.3+, Cu.sup.+, Cu.sup.2+ or mixtures thereof, and (b) a ceria/zirconia/alumina composite oxide, wherein the alumina content in said composite oxide is in the range of 20 to 80% by weight, in particular of 40 to 60% by weight,
a catalyst comprising such catalyst composition and its use for exhaust gas after-treatment of diesel and lean burn engines.

Systems and methods of placeshifting media playback between two or more devices are provided. For example, a method for placeshifting media may include downloading onto a first device an index of files accessed or modified on a second device via a data storage server, at least one of the files being a media file played on the second device. The first device may display a user selectable list of the files on the first device before issuing a request for the media file to the data storage server. The data storage server may send the media file to the first device from the data storage server, and the first device may play back the media file where the second device left off.

In an exhaust gas purification system provided with a denitration catalyst layer, a reducing agent oxidation catalyst layer is installed together; a reducing agent and air are supplied into the reducing agent oxidation catalyst layer at the time of catalyst regeneration of the denitration catalyst layer; a high-temperature oxidation reaction gas is produced by a reaction heat generated by an oxidation reaction of the reducing agent and the air in this reducing agent oxidation catalyst layer; and this high-temperature oxidation reaction gas is introduced into the denitration catalyst layer to heat the denitration catalyst, thereby recovering a denitration performance of the catalyst.

A selective catalytic reduction (SCR) catalyst includes a support layer. A copper-loaded chabazite (Cu/CHA) layer is supported on the support layer. A copper-loaded beta zeolite (Cu/beta) is supported on the Cu/CHA layer. The Cu/beta may be hydrothermally pre-aged prior to use of the SCR catalyst in a vehicle. The pre-aged Cu/beta is essentially free of phosphorous (P), calcium (Ca), zinc (Zn), sodium (Na), potassium (K), magnesium (Mg), iron (Fe), CaSO.sub.4, Ca.sub.19Zn.sub.2(PO.sub.4).sub.14, CaZn.sub.2(PO.sub.4).sub.2, ash, and/or soot.