A ceramic honeycomb body having intersecting walls that form channels extending axially from a first end face to a second end face and plugs to seal the channels at least at one of the first end face and the second end face. The plugs include a first active component, such as a catalytically active component or a chemically active component, of the plug structure, wherein the intersecting walls comprise no first active component and optionally have a second active component of the wall structure or disposed on the walls. Included are methods of making the ceramic honeycomb body having plugs of the first active component and walls with no first active component.

This honeycomb catalyst is provided with a honeycomb unit in which a plurality of through holes are arranged in parallel in a longitudinal direction with being separated by partition walls, wherein the honeycomb unit contains a zeolite and an inorganic binder, the zeolite satisfies all of conditions (A) to (D): (A) having a CHA structure in which the composition ratio of SIO.sub.2/Al.sub.2O.sub.3 is less than 15; (B) having Cu being carried by 3.5 to 6.0 wt % with respect to zeolite; (C) having an average particle diameter of 0.05 to 1 μm; and (D) being contained by 150 to 350 g/L with respect to the whole of the honeycomb unit, and excellent NOx purifying performance, reduction of water absorption and displacement, and inhibition of crack occurrence can be exerted.

A honeycomb structure includes: a honeycomb structure body including a plurality of cells; and a plugging portion to alternately plug open end parts of the plurality of cells on one side as an inflow side of the exhaust gas and open end parts on the other side as an outflow side of the exhaust gas. The partition wall is loaded, on the side of the outflow cells, with an oxidation catalyst made of a transition metal oxide to oxidize NO gas or an oxidation catalyst made of a transition metal oxide loaded at CeO.sub.2 to oxidize NO gas. The partition wall has porosity of 70% or less, the oxidation catalyst has a particle diameter of more than 1 μm and less than 50.0 μm, and the loading amount of the oxidation catalyst is 5.0 g/L or more and 50 g/L or less.

A reducing agent injection device includes a honeycomb structure and a urea spraying device spraying a urea water solution in mist form. In addition, the reducing agent injection device includes a carrier gas inlet that introduces carrier gas f between the urea spraying device and the honeycomb structure. The exhaust gas treatment method of the present invention supplies the urea water solution from the urea spraying device into the cells from the first end face of the honeycomb structure body to generate the ammonia, while introducing the carrier gas f from the carrier gas inlet, and injecting the ammonia to the outside to treat exhaust gas containing NO.sub.X.

A reducing agent injection device includes a honeycomb structure and a urea spraying device spraying a urea water solution in mist form. A pair of electrode members is formed in the honeycomb structure. The honeycomb structure of the reducing agent injection device, the hydraulic diameter HD, defined as HD=4×S/C, when the area of the cross section of one of the cells in the cross section perpendicular to the cell extending direction is S, and the peripheral length of the cross section of one of the cells is C, is 0.8 to 2.0 mm. Also, the open frontal area OFA of the honeycomb structure in the cross section perpendicular to the cell extending direction is 45 to 80%.

A reducing agent injection device includes a first honeycomb structure and a urea spraying device spraying a urea water solution in mist form. A pair of electrode members is formed in the first honeycomb structure. The ratio L/D of length L in the cell extending direction of the honeycomb structure body to diameter D of the cross section perpendicular to the cell extending direction is 0.5 to 1.2. Also, it is preferable that a urea hydrolysis catalyzer is provided in the second end face side of the honeycomb structure body, with a gap from the second end face.

A method of manufacturing an on-board diagnostic (OBD) limit part and a method of testing to evaluate an OBD system. The method of manufacturing the OBD limit part includes introducing a contaminant to a selective catalytic reduction (SCR) catalyst and contacting the contaminant with the SCR catalyst for a selected period of time. The method of manufacturing utilizes a vessel, the contaminant, and the SCR catalyst. The OBD limit part is a combination of the contaminant and the SCR catalyst within the vessel. The method of testing to evaluate the OBD system includes collecting data related to an exhaust gas before and after the exhaust gas is exposed to the OBD limit part, collecting an indication provided by the OBD system, and comparing the data related to the exhaust gas and the indication provided by the OBD system. The method of testing to evaluate the OBD system utilizes a system that includes an exhaust gas source, a first and a second fluid path, the OBD limit part, and the OBD system.

A porous ceramic honeycomb body (10) including intersecting walls that form channels (22) extending axially from a first end face to a second end face and layered plugs (62) comprised of a first layer (64) disposed on channel walls and a second layer (66) disposed inward toward an axial center of each respective channel on the first layer. The plugs seal at least one of a first portion of the channels at the first end face and a second portion of channels at the second end face of the porous ceramic honeycomb body.

An emissions treatment system for an exhaust stream of an internal combustion engine including hydrocarbons, carbon monoxide, and nitrogen oxides is provided. The disclosed system can include an exhaust conduit in fluid communication with the internal combustion engine via an exhaust manifold; a first three-way conversion catalyst (TWC-1) located downstream of the internal combustion engine in the exhaust conduit; an SCR-HCT catalyst comprising a selective catalytic reduction catalyst and a hydrocarbon trap downstream of the TWC-1 in the exhaust conduit; and a third catalyst downstream of the SCR-HCT combination in the exhaust conduit, the third catalyst comprising a platinum group metal (PGM) e.g., in an amount effective to oxidize hydrocarbons. Methods of making and using such systems and components thereof are also provided.

An after-treatment system includes, in series along an exhaust gas flow direction through the after-treatment system: a diesel oxidation catalyst (DOC), a diesel exhaust fluid (DEF) delivery device, a soot-reducing device and a selective catalytic reduction (SCR) catalyst.