The present invention relates to a process for conducting endothermic gas phase or gas-solid reactions, wherein the endothermic reaction is conducted in a production phase in a first reactor zone, the production zone, which is at least partly filled with solid particles, where the solid particles are in the form of a fixed bed, of a moving bed and in sections/or in the form of a fluidized bed, and the product-containing gas stream is drawn off from the production zone in the region of the highest temperature level plus/minus 200 K and the product-containing gas stream is guided through a second reactor zone, the heat recycling zone, which at least partly comprises a fixed bed, where the heat from the product-containing gas stream is stored in the fixed bed, and, in the subsequent purge step, a purge gas is guided through the production zone and the heat recycling zone in the same flow direction, and, in a heating zone disposed between the production zone and the heat recycling zone, the heat required for the endothermic reaction is introduced into the product-containing gas stream and into the purge stream or into the purge stream, and then, in a regeneration phase, a gas is passed through the two reactor zones in the reverse flow direction and the production zone is heated up; the present invention further relates to a structured reactor comprising three zones, a production zone containing solid particles, a heating zone and a heat recycling zone containing a fixed bed, wherein the solid particles and the fixed bed consist of different materials.

A device and system for energy generation using plasma incineration and further, for producing electricity by hydrogen gas generation and combustion.

The present disclosure relates to a dissimilar metal-doped cerium oxide including cerium oxide and a dissimilar metal other than the cerium oxide, in which a relationship of the following formula (1) is satisfied:

0.8≤|(D90)−(D10)|/D50≤2.0  (1) (in the formula (1), D10, D50, and D90 respectively represent the following: D10: particle diameter at which cumulative volume fraction is 10% D50: particle diameter at which cumulative volume fraction is 50% D90: particle diameter at which cumulative volume fraction is 90%).

A method of carbon dioxide hydrogenation comprises introducing gaseous water to a positive electrode of an electrolysis cell comprising the positive electrode, a negative electrode, and a proton-conducting membrane between the positive electrode and the negative electrode. The proton-conducting membrane comprises an electrolyte material having an ionic conductivity greater than or equal to about 10.sup.−2 S/cm at one or more temperatures within a range of from about 150° C. to about 650° C. Carbon dioxide is introduced to the negative electrode of the electrolysis cell. A potential difference is applied between the positive electrode and the negative electrode of the electrolysis cell to generate hydrogen ions from the gaseous water that diffuses through the proton-conducting membrane and hydrogenates the carbon dioxide at the negative electrode. A carbon dioxide hydrogenation system is also described.

Process for preparing a porous monolith comprising between 10% and 100% by weight of a semiconductor relative to the total weight of the porous monolith, which process comprises the following steps: a) a first aqueous suspension containing polymer particles is prepared; b) a second aqueous suspension containing particles of least one inorganic semiconductor is prepared; c) the two aqueous suspensions prepared in steps a) and b) are mixed in order to obtain a paste; d) a heat treatment of the paste obtained in step c) is carried out in order to obtain the monolith with multimodal porosity.

A process and a device are described for producing high purity and high temperature steam from non-pure water which may be used in a variety of industrial processes that involve high temperature heat applications. The process and device may be used with technologies that generate steam using a variety of heat sources, such as, for example industrial furnaces, petrochemical plants, and emissions from incinerators. Of particular interest is the application in a thermochemical hydrogen production cycle such as the Cu—Cl Cycle. Non-pure water is used as the feed-stock in the thermochemical hydrogen production cycle, with no need to adopt additional and conventional water pre-treatment and purification processes. The non-pure water may be selected from brackish water, saline water, seawater, used water, effluent treated water, tailings water, and other forms of water that is generally believed to be unusable as a direct feed-stock of industrial processes. The direct usage of this water can significantly reduce water supply costs.

The present invention provides an impregnated catalyst composition for production of pure hydrogen comprising: 10 wt %-50 wt % metal oxide; 1 wt %-15 wt % promoter; and 60 wt %-90 wt % support material. Another aspect of the present invention is to provide a method of preparation of an impregnated catalyst for pure hydrogen production (10) and a method for producing pure hydrogen (20) according to the impregnated catalyst of the present invention. The present invention is able to reduce the reaction temperature by 1 to 2 folds and also able to reduce the usage of energy but maintain its good production quality. Besides, selectivity of the present invention is high, hence able to produce high purity of hydrogen.

Disclosed is a hydrogen generation furnace using decomposition of biomass steam, which employs an infrared source and a furnace body with a water-accommodating structure. A steam separation-drying device is cylindrical and provided at an upper part of an interior of the furnace body and a cavity of the steam separation-drying device forms a secondary gasifier. A lattice plate is provided at a bottom of the interior of the furnace body. A lattice combustion grate is provided above a middle of the lattice plate. A steam distributor is provided outside a lower part of the furnace body. The furnace of the invention performs gasified gas separation as well as secondary oxidation and gasification and mixes steam with gas generated from biomass to perform a decomposition reaction for generating hydrogen.

High purity hydrogen is produced by a steam reforming hydrogen production unit with at least one of a bayonet reactor for reforming steam and a hydrocarbon, a recuperative burner, and a regenerative burner such that the steam reforming unit produces little or no steam in excess of the steam reforming process requirements. High purity hydrogen is separated from the syngas exiting the reformer via a pressure swing adsorption unit and combined with high purity nitrogen from an air separation unit as feedstock to a Haber process ammonia synthesis unit. Compressors for the ammonia synthesis unit are driven by higher efficiency drivers than are possible using the low temperature steam conventionally exported from a steam reforming unit. Compression power requirements are reduced.

A device (1) and method are claimed for converting thermal energy into dissociation energy of molecules of a gas medium (3). The device incorporates a reaction vacuum chamber (2), designed to enable a gas medium (3) to be supplied therein, at least one thermal radiator (4), of which at least one emission spectral line of a medium (5), in the temperature range 350° C. to 1500° C., at least partially corresponds to the absorption spectral line of molecules of the gas medium (3). At least part of the volume of the vacuum chamber (2) is positioned in the zone of optical visibility of the radiator (4) and is a reaction volume (7) for the gas medium (3), in which reaction volume, as a result of resonance oscillations of molecules of the gas medium (3), excited by the radiator (4), at least partial dissociation of the gas medium (3) takes place. The device also incorporates a system (8) for drawing off at least one product of dissociation of molecules of the gas medium (3).