The present invention relates to a thermosetting material for use in a 3D printing process comprising: a) at least one epoxy resin A, b) at least one elastomer-modified epoxy resin B, c) at least one resin C with a dynamic viscosity of below 4 Pas at 150° C., d) at least one of a curing agent D capable of reacting with A, B and optionally C, e) and optionally additional compounds,
wherein the glass transition temperature of the uncured material is at least 30° C., preferably at least 40° C. as measured with DSC at a heating rate of 20° C./min.

The invention further relates to a method of producing a cured 3D thermoset object and the use of the above-mentioned thermosetting material in a 3D printing process.

The present invention relates to a thermosetting material for use in additive manufacturing, the material comprising at least one thermosetting resin and at least two curing compounds different from said thermosetting resin that are able to cure this/these thermosetting resin(s), wherein at least one curing compound is provided for curing during the additive manufacturing process and at least one curing compound is provided for curing during a post-curing step. The invention furthermore relates to a method of producing a cured 3D thermoset object comprising at least the steps of subjecting the material according to the present invention to an additive manufacturing process, obtaining a partially cured 3D thermoset object and subsequently subjecting the partially cured 3D thermoset object to a post-curing process to further cure the 3D thermoset object Additionally, the invention relates to the use of the material in an SLS, FFF, CBAM, FGF or powder bed additive manufacturing process.

A composition including an amidoamine curing agent composition or a polyamide curing agent composition are disclosed. The composition includes the reaction products of (1) an amine component including at least one multifunctional amine of structure (I):

##STR00001##

wherein each R is independently H or CH.sub.2CH.sub.2CH.sub.2NH.sub.2; R.sub.1 is H, CH.sub.3CH.sub.2CH.sub.2N—, C1-C21 alkyl, or C1-C21 alkenyl; n is 2; and m is 1 or 2, with (2) a fatty acid or ester component selected from the group consisting of a dimer fatty acid or ester component, a monofunctional fatty acid or ester component, and combinations thereof. The amidoamine curing agent composition remains as liquid at ambient temperature.

To provide a resin composition that is suitable for use as a matrix resin for a fiber-reinforced composite material, the resin composition exhibiting excellent impregnation properties into reinforcing fibers and rapid curing properties, giving a molded product having high heat resistance when cured, and exhibiting excellent productivity in a short time. A two-pack curable resin composition for a fiber-reinforced composite material, including a main agent that includes an epoxy resin (A) and an ester compound (B) represented by general formula (1) below, and a curing agent that includes an amine compound (C):

##STR00001##

(R.sub.1 and R.sub.2 each denote an alkyl group or an aryl group, and R.sub.1 and R.sub.2 may bond together to form a cyclic structure; or R.sub.1 may be an ester-containing group).

A composition including an amidoamine curing agent composition or a polyamide curing agent composition are disclosed. The composition includes the reaction products of (1) an amine component including at least one multifunctional amine of structure (I): ##STR00001##
wherein each R is independently H or CH.sub.2CH.sub.2CH.sub.2NH.sub.2; R.sub.1 is H, CH.sub.3CH.sub.2CH.sub.2N, C1-C21 alkyl, or C1-C21 alkenyl; n is 2; and m is 1 or 2, with (2) a fatty acid or ester component selected from the group consisting of a dimer fatty acid or ester component, a monofunctional fatty acid or ester component, and combinations thereof. The amidoamine curing agent composition remains as liquid at ambient temperature.

A composition including an amidoamine curing agent composition or a polyamide curing agent composition are disclosed. The composition includes the reaction products of (1) an amine component including at least one multifunctional amine of structure (I): ##STR00001##
wherein each R is independently H or CH.sub.2CH.sub.2CH.sub.2NH.sub.2; R.sub.1 is H, CH.sub.3CH.sub.2CH.sub.2N, C1-C21 alkyl, or C1-C21 alkenyl; n is 2; and m is 1 or 2, with (2) a fatty acid or ester component selected from the group consisting of a dimer fatty acid or ester component, a monofunctional fatty acid or ester component, and combinations thereof. The amidoamine curing agent composition remains as liquid at ambient temperature.