A paramagnetic garnet-type transparent ceramic characterized by being a sintered body of a terbium-containing composite oxide represented by formula (1) in which the linear transmittance at a wavelength of 1,064 nm at an optical path length of 15 mm is 83% or higher.
(Tb.sub.1-x-ySc.sub.xCe.sub.y).sub.3(Al.sub.1-zSc.sub.z).sub.5O.sub.12  (1)
(In the formula, 0<x<0.08, 0≤y≤0.01, 0.004<z<0.16.)

Provided is a novel solid electrolyte material of high density and high ionic conductivity, and an all-solid-state lithium ion secondary battery that utilizes the solid electrolyte material. The solid electrolyte material has a chemical composition represented by Li.sub.7-3xGa.sub.xLa.sub.3Zr.sub.2O.sub.12 (0.08≤x<0.5), has a relative density of 99% or higher, belongs to space group I-43d, in the cubic system, and has a garnet-type structure. The lithium ion conductivity of the solid electrolyte material is 2.0×10.sup.−3 S/cm or higher. The solid electrolyte material has a lattice constant a such that 1.29 nm≤a≤1.30 nm, and lithium ions occupy the 12a site, the 12b site and two types of 48e site, and gallium occupies the 12a site and the 12b site, in the crystal structure. The all-solid-state lithium ion secondary battery has a positive electrode, a negative electrode, and a solid electrolyte. The solid electrolyte is made up of the solid electrolyte material of the present invention.

Provided is a novel solid electrolyte material of high density and high ionic conductivity, and an all-solid-state lithium ion secondary battery that utilizes the solid electrolyte material. The solid electrolyte material has a chemical composition represented by Li.sub.7-3xGa.sub.xLa.sub.3Zr.sub.2O.sub.12 (0.08≤x<0.5), has a relative density of 99% or higher, belongs to space group I-43d, in the cubic system, and has a garnet-type structure. The lithium ion conductivity of the solid electrolyte material is 2.0×10.sup.−3 S/cm or higher. The solid electrolyte material has a lattice constant a such that 1.29 nm≤a≤1.30 nm, and lithium ions occupy the 12a site, the 12b site and two types of 48e site, and gallium occupies the 12a site and the 12b site, in the crystal structure. The all-solid-state lithium ion secondary battery has a positive electrode, a negative electrode, and a solid electrolyte. The solid electrolyte is made up of the solid electrolyte material of the present invention.

A bismuth-substituted rare earth iron garnet single crystal suitable for Faraday rotators and optical isolators with reduced insertion loss due to suppressed valence fluctuation of Fe ions is provided. The bismuth-substituted rare earth iron garnet single crystal of the present invention is characterized by the composition formula (Gd.sub.aLn.sub.bBi.sub.cMg.sub.3−(a+b+c))(Fe.sub.dGa.sub.eTi.sub.fPt.sub.5−(d+e+f))O.sub.12. In the composition formula above, 0.02≤f≤0.05, 0.02≤{3−(a+b+c)}≤0.08, and −0.01≤{3−(a+b+c)}−{f+5−(d+e+f)}≤0.01. Ln is a rare earth element and may be selected from Eu, Dy, Gd, Ho, Tm, Yb, Lu, and Y.

A bismuth-substituted rare earth iron garnet single crystal suitable for Faraday rotators and optical isolators with reduced insertion loss due to suppressed valence fluctuation of Fe ions is provided. The bismuth-substituted rare earth iron garnet single crystal of the present invention is characterized by the composition formula (Gd.sub.aLn.sub.bBi.sub.cMg.sub.3−(a+b+c))(Fe.sub.dGa.sub.eTi.sub.fPt.sub.5−(d+e+f))O.sub.12. In the composition formula above, 0.02≤f≤0.05, 0.02≤{3−(a+b+c)}≤0.08, and −0.01≤{3−(a+b+c)}−{f+5−(d+e+f)}≤0.01. Ln is a rare earth element and may be selected from Eu, Dy, Gd, Ho, Tm, Yb, Lu, and Y.

The present invention provides an oxide-base scintillator single crystal having an extremely large energy of light emission, adoptable to X-ray CT and radioactive ray transmission inspection apparatus, and more specifically to provide a Pr-containing, garnet-type oxide single crystal, a Pr-containing perovskite-type oxide single crystal, and a Pr-containing silicate oxide single crystal allowing detection therefrom light emission supposedly ascribable to 5d-4f transition of Pr.

The present invention provides an oxide-base scintillator single crystal having an extremely large energy of light emission, adoptable to X-ray CT and radioactive ray transmission inspection apparatus, and more specifically to provide a Pr-containing, garnet-type oxide single crystal, a Pr-containing perovskite-type oxide single crystal, and a Pr-containing silicate oxide single crystal allowing detection therefrom light emission supposedly ascribable to 5d-4f transition of Pr.

Provided is a crucible including: a melt reservoir that collects a melt that becomes a raw material of a crystal; and a nozzle portion that controls a shape of the crystal. The nozzle portion includes nozzle holes that allow the melt to flow out from the melt reservoir to an end surface of the nozzle portion. Surface roughness of an inner peripheral surface of the nozzle holes is 10 μm or less.

The invention relates to scintillation inorganic oxide single crystals with garnet structure, which comprise cerium and are co-alloyed with titanium and Group 2 elements. The invention makes it possible to increase the scintillation output and to enhance the energy resolution of scintillation detectors during gamma-ray quantum registration. The technical result is achieved by a single crystal with a garnet structure being co-alloyed with cerium, titanium and Group 2 elements. This single crystal is produced by the Czochralski process.

The invention relates to scintillation inorganic oxide single crystals with garnet structure, which comprise cerium and are co-alloyed with titanium and Group 2 elements. The invention makes it possible to increase the scintillation output and to enhance the energy resolution of scintillation detectors during gamma-ray quantum registration. The technical result is achieved by a single crystal with a garnet structure being co-alloyed with cerium, titanium and Group 2 elements. This single crystal is produced by the Czochralski process.