Forming deep airgaps without flop over
09837305 · 2017-12-05
Assignee
Inventors
- Benjamin D. Briggs (Waterford, NY, US)
- Lawrence A. Clevenger (Rhinebeck, NY, US)
- Bartlet H. Deprospo (Goshen, NY, US)
- Huai Huang (Saratoga, NY, US)
- Christopher J. Penny (Saratoga Springs, NY, US)
- Michael Rizzolo (Albany, NY)
Cpc classification
H01L23/5222
ELECTRICITY
H01L21/76808
ELECTRICITY
H01L21/76831
ELECTRICITY
International classification
H01L21/00
ELECTRICITY
H01L21/44
ELECTRICITY
H01L29/04
ELECTRICITY
H01L31/036
ELECTRICITY
H01L21/768
ELECTRICITY
H01L23/522
ELECTRICITY
Abstract
A semiconductor structure that includes: a semiconductor substrate having a semiconductor base and back end of the line (BEOL) wiring layers; a dielectric cap layer on the semiconductor base; trenches on the dielectric cap layer, each of the trenches including dielectric walls, a dielectric bottom in contact with the dielectric cap layer and a metal filling a space between the dielectric walls; air gap openings on the dielectric cap layer and interspersed with the trenches, each air gap opening between the dielectric wall from one metal trench and adjacent to the dielectric wall of a second metal, the dielectric cap layer forming a bottom of the air gap openings; and a second dielectric cap layer formed over the trenches and over the air gap openings, the second dielectric cap layer pinching off each air gap opening.
Claims
1. A method of forming airgaps in a back end of the line (BEOL) wiring layer of a semiconductor device, comprising: providing a semiconductor substrate having a semiconductor base; depositing a sacrificial dielectric layer for a BEOL wiring layer on the semiconductor base; selectively etching the sacrificial dielectric layer to form openings in the sacrificial dielectric layer, each opening having walls and a bottom; conformally forming a dielectric material in the openings, the dielectric material conformally formed on the walls and the bottom of each of the openings; depositing a metal on the conformally formed dielectric material in the openings to form metal-filled openings; removing the sacrificial dielectric layer from at least a portion of the semiconductor substrate to form air gap openings extending to a level equal to the bottom of each of the openings, the air gap openings being adjacent to the metal-filled openings and sharing a common dielectric wall with each adjacent metal-filled opening; and forming a dielectric cap layer over the air gap openings to pinch off the air gap openings.
2. The method of claim 1 wherein after conformally forming the dielectric material in the openings, further comprising etching through the dielectric material in at least one of the openings to form a via opening to an underlying metallic feature and in the step of depositing the metal, further including depositing the metal in the via opening to form a via.
3. The method of claim 1 further comprising removing the sacrificial dielectric layer from all of the semiconductor substrate so that air gap openings replace all of the sacrificial dielectric layer.
4. The method of claim 1 wherein the metal is copper and the metal-filled openings are trenches.
5. The method of claim 1 wherein the conformally formed dielectric material is thicker on the bottom of each of the openings than on the walls of each of the openings.
6. The method of claim 1 wherein the conformally formed dielectric material is conformally deposited.
7. The method of claim 1 wherein conformally forming the dielectric material comprises depositing a flowable dielectric material to completely fill the openings and then selectively etching the flowable dielectric to form the conformally formed dielectric on the walls and the bottom of the openings.
8. The method of claim 1 wherein removing the sacrificial dielectric layer from at least a portion of the semiconductor base comprises forming a partial cap layer over a second portion of the semiconductor substrate where the sacrificial dielectric layer is not to be removed to leave the portion of the semiconductor substrate exposed and in the step of forming the dielectric cap layer, further comprising forming the dielectric cap layer on the partial cap layer.
9. A method of forming airgaps in a back end of the line (BEOL) wiring layer of a semiconductor device, comprising: providing a semiconductor substrate having a semiconductor base and a dielectric cap layer in a BEOL wiring layer; depositing a sacrificial dielectric layer on the dielectric cap layer; selectively etching the sacrificial dielectric layer to form openings in the sacrificial dielectric layer to expose the dielectric cap layer such that the remaining sacrificial dielectric layer forms pillars of the sacrificial dielectric layer, each opening having walls and a bottom; conformally forming a dielectric material in the openings, the dielectric material conformally formed on walls of the opening and the dielectric cap layer exposed in the openings; depositing a metal on the conformally formed dielectric material in the openings to form metal-filled openings; removing the pillars of the sacrificial dielectric layer from at least a portion of the semiconductor substrate to form air gap openings having walls of the dielectric material and exposing the dielectric cap layer, the air gap openings being adjacent to the metal-filled openings and sharing a common dielectric wall with each adjacent metal-filled opening; and forming a second dielectric cap layer over the air gap openings to pinch off the air gap openings.
10. The method of claim 9 wherein after conformally forming the dielectric material in the openings, further comprising etching through the dielectric material and the dielectric cap layer in at least one of the openings to form a via opening to an underlying metallic feature and in the step of depositing the metal, further including depositing the metal in the via opening to form a via.
11. The method of claim 9 further comprising removing the pillars of the sacrificial dielectric layer from all of the semiconductor substrate so that air gap openings replace all of the pillars of the sacrificial dielectric layer.
12. The method of claim 9 wherein the metal is copper and the metal-filled openings are trenches.
13. The method of claim 9 wherein the conformally formed dielectric material is thicker on the bottom of each of the openings than on the walls of each of the openings.
14. The method of claim 9 wherein the conformally formed dielectric material is conformally deposited.
15. The method of claim 9 wherein conformally forming the dielectric material comprises depositing a flowable dielectric material to completely fill the openings and then selectively etching the flowable dielectric to form the conformally formed dielectric on the walls and the bottom of the openings.
16. The method of claim 9 wherein removing the sacrificial dielectric layer from at least a portion of the semiconductor base comprises forming a partial dielectric cap layer over a second portion of the semiconductor substrate where the sacrificial dielectric layer is not to be removed to leave the portion of the semiconductor substrate exposed and in the step of forming the second dielectric cap layer, further comprising forming the second dielectric cap layer on the partial cap layer.
17. A semiconductor structure comprising: a semiconductor substrate having a semiconductor base and a plurality of back end of the line (BEOL) wiring layers; a dielectric cap layer of uniform thickness on the semiconductor base; a plurality of trenches on the dielectric cap layer, each of the trenches including dielectric walls, a dielectric bottom in contact with the dielectric cap layer and a metal filling a space between the dielectric walls; a plurality of air gap openings on the dielectric cap layer and interspersed with the plurality of trenches, each air gap opening between the dielectric wall from one metal trench and adjacent to the dielectric wall of a second metal, the dielectric cap layer forming a bottom of the plurality of air gap openings, such that the plurality of air gap openings are directly exposed to the dielectric cap layer; and a second dielectric cap layer formed over the plurality of trenches and over the plurality of air gap openings, the same second dielectric cap layer pinches off each air gap opening as is formed over the plurality of trenches.
18. The semiconductor structure of claim 17 further comprising a dielectric pillar between at least two adjacent trenches.
19. The semiconductor structure of claim 18 further comprising a third dielectric cap layer on the dielectric pillar, the third dielectric cap layer interposed between the dielectric pillar and the second dielectric cap layer.
20. The semiconductor structure of claim 17 wherein the dielectric walls have a first thickness and the dielectric bottom has a second thickness such that the second thickness is greater than the first thickness.
Description
BRIEF DESCRIPTION OF SEVERAL VIEWS OF THE DRAWINGS
(1) The features of the exemplary embodiments believed to be novel and the elements characteristic of the exemplary embodiments are set forth with particularity in the appended claims. The Figures are for illustration purposes only and are not drawn to scale. The exemplary embodiments, both as to organization and method of operation, may best be understood by reference to the detailed description which follows taken in conjunction with the accompanying drawings in which:
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DETAILED DESCRIPTION
(26) It has been found that currently proposed airgap schemes are limited in how deep an airgap can be created before risking the airgap beginning to undercut the trench. Airgap undercut can lead to trench flopover during airgap formation.
(27) Flopover may occur when the wiring trench or any supporting dielectric has been weakened to the extent that the wiring trench begins to tilt into the airgap, thereby decreasing the effectiveness of the airgap and potentially leading to shorting between the wires.
(28) Accordingly, a solution has been proposed in which a dielectric backfill has been utilized to provide support for trenches and prevent airgap undercut and line flopover. Utilization of a dielectric backfill allows for formation of deeper airgaps without the risk of flopover. The dielectric for the backfill can be chosen to optimize capacitance, damage resistance and mechanical properties. The present solution further utilizes a sacrificial dielectric which may remain in the final structure or be fully removed.
(29) Referring to the Figures in more detail, and particularly referring to
(30) Two BEOL wiring layers 18 are shown in
(31) Second BEOL layer 22 also illustrates a via 36 which extends into wiring trench 24 to provide electrical contact between BEOL layer 20 and BEOL layer 22.
(32) The airgaps 12 may be in all BEOL layers or just in some BEOL layers or even in just parts of the BEOL layers. For example, the airgaps 12 may be in BEOL layer 20 but are not viewable due to the cross sectional view. Alternatively, the airgaps 12 may not be in BEOL layer 20 if not necessary to achieving the desired electrical characteristics of the BEOL layer 20.
(33) The airgaps 12 may extend fully from the cap layer 30, which has pinched off the airgaps 12, to the cap layer 26. The wiring trenches 28 include dielectric walls 32 and a dielectric bottom 34 so that the wiring trenches 28 are essentially encapsulated by the dielectric walls 32 and dielectric bottom 34 which together enable deep airgaps 12 without risking flopover of the wiring trenches 28.
(34) Referring now to
(35) The semiconductor base 14 and MOL portion 16 are not shown in
(36) Referring to
(37) On top of cap layer 26 may be formed, for example by chemical vapor deposition (CVD) a sacrificial dielectric layer 40. The sacrificial dielectric layer 40 may be any dielectric material that is easily etched away and may be, for example, silicon oxide, silicon nitride or a dielectric material that may be made porous such as SiCOH. The sacrificial dielectric layer 40 may have a thickness in the range of 25 to 1000 nm, preferably about 100 nm.
(38) Referring now to
(39) Thereafter, the semiconductor structure 10 undergoes an etching process, for example a dry etching process such as reactive ion etching (RIE), in which the openings 44 in the lithographic material 42 are propagated into the underlying sacrificial dielectric material 40 to form openings 46 in the sacrificial dielectric material 40. After the etching process, the lithographic material 42 may be conventionally stripped. As a result of the etching process, pillars of sacrificial dielectric material 40 are formed which will run parallel to the wiring trenches that will be formed in subsequent processing steps. In one exemplary embodiment, the openings 46 in the sacrificial dielectric material 40 extend all the way to the cap layer 26 so that the cap layer 26 is now exposed. The resulting structure is shown in
(40) Then, as illustrated in
(41) The dielectric material may be deposited in two different ways to result in the conformally formed dielectric material 48. In one exemplary embodiment, the dielectric material 48 may be conformally deposited such as by a CVD process.
(42) In another exemplary embodiment, as illustrated in
(43) Alternatively, a combination of conformally deposited dielectric and a flowable dielectric may be used to achieve the desired thicknesses for the dielectric material 32 on the sidewall and the dielectric material 34 on the bottom.
(44) In one exemplary embodiment, a via may be formed to connect wiring trench 24 in BEOL layer 20 to a wiring trench or another via in a BEOL layer over BEOL layer 20. The process of forming the via is illustrated in
(45) In a next process, the semiconductor structure 10 may be metallized. A liner (not shown), such as TaN/Ta, may be formed in the via opening 56 and openings 46 in the sacrificial dielectric material 40 followed by seed plating (not shown) and then filling with the metal 58 as shown in
(46) After deposition of the fill metal 58, the semiconductor structure 10 may undergo a planarization process, such as chemical mechanical polishing (CMP), to remove the overburden of the metal fill 58 and also remove the horizontal portions of the dielectric material 48 to result in the semiconductor structure 10 shown in
(47) The sacrificial dielectric material 40 may be partially or completely removed. In one exemplary embodiment, as illustrated in
(48) In another exemplary embodiment, as illustrated in
(49) Referring now to
(50) Referring now to
(51) The semiconductor base 14 and MOL portion 16 are not shown in
(52) The process for forming the semiconductor structure 10′ of
(53) Referring to
(54) On top of cap layer 26 may be formed, for example by chemical vapor deposition (CVD) a sacrificial dielectric layer 40 as described previously.
(55) On top of sacrificial dielectric layer 40 is formed hardmask 70.
(56) Referring now to
(57) Thereafter, as shown in
(58) Then, as illustrated in
(59) The dielectric material may be deposited in two different ways to result in the conformally formed dielectric material 48. In one exemplary embodiment, the dielectric material 48 may be conformally deposited such as by a CVD process.
(60) In another exemplary embodiment, as illustrated in
(61) Alternatively, a combination of conformally deposited dielectric and a flowable dielectric may be used to achieve the desired thicknesses for the dielectric material 32 on the sidewall and the dielectric material 34 on the bottom.
(62) In one exemplary embodiment, a via may be formed to connect wiring trench 24 in BEOL layer 20 to a wiring trench or a via in a BEOL layer over BEOL layer 20. The process of forming the via is illustrated in
(63) A particular advantage of semiconductor structure 10′ is that because of the presence of the patterned hardmask 70, the via pattern formed in the lithographic material 54 can be wider than the via opening 56. This allows for more aggressive patterning of vias.
(64) In a next process as shown in
(65) Semiconductor structure 10′ is now identical to semiconductor structure 10 in
(66) It will be apparent to those skilled in the art having regard to this disclosure that other modifications of the exemplary embodiments beyond those embodiments specifically described here may be made without departing from the spirit of the invention. Accordingly, such modifications are considered within the scope of the invention as limited solely by the appended claims.