SEMICONDUCTOR DEVICE WITH SELF-ALIGNED CONDUCTIVE FEATURES
20220359380 · 2022-11-10
Assignee
Inventors
- Tai-I YANG (Hsinchu City, TW)
- Wei-Chen CHU (Taichung City, TW)
- Yung-Hsu Wu (Taipei City, TW)
- Chung-Ju Lee (Hsinchu City, TW)
Cpc classification
H01L21/76885
ELECTRICITY
H01L21/76897
ELECTRICITY
H01L21/76852
ELECTRICITY
H01L23/53252
ELECTRICITY
H01L21/76867
ELECTRICITY
H01L23/5222
ELECTRICITY
H01L23/53238
ELECTRICITY
H01L23/5226
ELECTRICITY
H01L23/53223
ELECTRICITY
H01L23/53266
ELECTRICITY
International classification
H01L23/522
ELECTRICITY
H01L21/768
ELECTRICITY
Abstract
A semiconductor device structure is provided. The semiconductor device structure includes a semiconductor substrate and a conductive line over the semiconductor substrate. The conductive line has a barrier region surrounding an inner portion of the conductive line, and the barrier region has a greater dopant concentration than the inner portion. The semiconductor device structure also includes a conductive via on the conductive line. The semiconductor device structure further includes a dielectric layer over the semiconductor substrate. The dielectric layer surrounds the conductive line and the conductive via.
Claims
1. A semiconductor device structure, comprising: a semiconductor substrate; a conductive line over the semiconductor substrate, wherein the conductive line has a barrier region surrounding an inner portion of the conductive line, and the barrier region has a greater dopant concentration than the inner portion; a conductive via on the conductive line; and a dielectric layer over the semiconductor substrate, wherein the dielectric layer surrounds the conductive line and the conductive via.
2. The semiconductor device structure as claimed in claim 1, wherein the barrier region comprises Co, Ta or Ti.
3. The semiconductor device structure as claimed in claim 1, wherein a bottom of the conductive line is wider than a bottom of the conductive via.
4. The semiconductor device structure as claimed in claim 1, further comprising: an insulating element between the conductive via and the conductive line.
5. The semiconductor device structure as claimed in claim 4, wherein the barrier region is in direct contact with the insulating element.
6. The semiconductor device structure as claimed in claim 4, wherein an outer sidewall of the insulating element protrudes from a sidewall of the conductive via.
7. The semiconductor device structure as claimed in claim 1, further comprising: a second dielectric layer between the conductive line and the semiconductor substrate.
8. The semiconductor device structure as claimed in claim 1, further comprising: a second conductive line on the conductive via, wherein the second conductive line is wider than the conductive line.
9. The semiconductor device structure as claimed in claim 8, wherein the second conductive line is wider than the conductive via.
10. The semiconductor device structure as claimed in claim 8, further comprising: a closed hole in the dielectric layer below the second conductive line.
11. A semiconductor device structure, comprising: a substrate; a first conductive feature over the substrate, wherein the first conductive feature shrinks along a first direction from a bottom portion of the first conductive feature towards a top portion of the first conductive feature; a second conductive feature on the first conductive feature, wherein the second conductive feature has an upper portion and a protruding portion, the protruding portion is between the upper portion and the first conductive feature, wherein the upper portion shrinks along the first direction, and a bottom of the upper portion is narrower than the first conductive feature; and a dielectric layer surrounding the first conductive feature and the second conductive feature.
12. The semiconductor device structure as claimed in claim 11, wherein a height of the first conductive feature is greater than a height of the second conductive feature.
13. The semiconductor device structure as claimed in claim 11, wherein a height of the upper portion of the second conductive feature is greater than a height of the protruding portion of the second conductive feature.
14. The semiconductor device structure as claimed in claim 11, wherein the dielectric layer includes a low-k dielectric material.
15. The semiconductor device structure as claimed in claim 11, wherein an angle between a sidewall of the upper portion of the second conductive feature and the bottom of the upper portion of the second conductive feature is from 75 degrees to 85 degrees.
16. A semiconductor device structure, comprising: a semiconductor substrate; a conductive line over the semiconductor substrate, wherein the conductive line shrinks along a direction from a lower portion of the conductive line towards an upper portion of the conductive line; a first conductive via and a second conductive via on the conductive line, wherein the first conductive via and the second conductive via shrink along a direction from lower portions of the first conductive via and the second conductive via respectively towards upper portions of the first conductive via and the second conductive via; and an insulating element over the conductive line and surrounding the first conductive via and the second conductive via and separating the first conductive via from the second conductive via.
17. The semiconductor device structure as claimed in claim 16, further comprising: a dielectric layer surrounding the conductive line, the first conductive via and the second conductive via.
18. The semiconductor device structure as claimed in claim 17, wherein a portion of the dielectric layer is between the first conductive via and the second conductive via.
19. The semiconductor device structure as claimed in claim 18, wherein a height of the first conductive via is greater than a height of the portion of the dielectric layer.
20. The semiconductor device structure as claimed in claim 17, further comprising: a second conductive line on the dielectric layer and the first conductive via, wherein the second conductive line is connected to the first conductive via; and a third conductive line on the dielectric layer and the second conductive via, wherein the third conductive line is connected to the second conductive via.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
[0005] Aspects of the present disclosure are best understood from the following detailed description when read with the accompanying figures. It should be noted that, in accordance with the standard practice in the industry, various features are not drawn to scale. In fact, the dimensions of the various features may be arbitrarily increased or reduced for clarity of discussion.
[0006]
[0007]
[0008]
DETAILED DESCRIPTION
[0009] The following disclosure provides many different embodiments, or examples, for implementing different features of the provided subject matter. Specific examples of components and arrangements are described below to simplify the present disclosure. These are, of course, merely examples and are not intended to be limiting. For example, the formation of a first feature over or on a second feature in the description that follows may include embodiments in which the first and second features are formed in direct contact, and may also include embodiments in which additional features may be formed between the first and second features, such that the first and second features may not be in direct contact. In addition, the present disclosure may repeat reference numerals and/or letters in the various examples. This repetition is for the purpose of simplicity and clarity and does not in itself dictate a relationship between the various embodiments and/or configurations discussed.
[0010] Further, spatially relative terms, such as “beneath,” “below,” “lower,” “above,” “upper” and the like, may be used herein for ease of description to describe one element or feature's relationship to another element(s) or feature(s) as illustrated in the figures. The spatially relative terms are intended to encompass different orientations of the device in use or operation in addition to the orientation depicted in the figures. The apparatus may be otherwise oriented (rotated 90 degrees or at other orientations) and the spatially relative descriptors used herein may likewise be interpreted accordingly.
[0011] Some embodiments of the disclosure are described. Additional operations can be provided before, during, and/or after the stages described in these embodiments. Some of the stages that are described can be replaced or eliminated for different embodiments. Additional features can be added to the semiconductor device structure. Some of the features described below can be replaced or eliminated for different embodiments. Although some embodiments are discussed with operations performed in a particular order, these operations may be performed in another logical order.
[0012]
[0013] In some embodiments, isolation features (not shown) are formed in the semiconductor substrate 100 to define and isolate various device elements (not shown) formed in the semiconductor substrate 100. The isolation features include, for example, trench isolation (STI) features or local oxidation of silicon (LOCOS) features.
[0014] In some embodiments, various device elements are formed in and/or on the semiconductor substrate 100. Examples of the various device elements that may be formed in the semiconductor substrate 100 include transistors (e.g., metal oxide semiconductor field effect transistors (MOSFET), complementary metal oxide semiconductor (CMOS) transistors, bipolar junction transistors (BJT), high voltage transistors, high frequency transistors, p-channel and/or n-channel field effect transistors (PFETs/NFETs), etc.), diodes, another suitable element, or a combination thereof. Various processes are performed to form the various device elements, such as deposition, etching, implantation, photolithography, annealing, planarization, one or more other applicable processes, or a combination thereof.
[0015] In some embodiments, a dielectric layer 102 is formed on the semiconductor substrate 100, as shown in
[0016] The device elements in and/or on the semiconductor substrate 100 will be interconnected through the interconnection structure to be formed over the semiconductor substrate 100. As a result, integrated circuit devices are formed. The integrated circuit devices may include logic devices, memory devices (e.g., static random access memories, SRAMs), radio frequency (RF) devices, input/output (I/O) devices, system-on-chip (SoC) devices, image sensor devices, one or more other applicable types of devices, or a combination thereof.
[0017] As shown in
[0018] In some embodiments, the conductive material is deposited using a chemical vapor deposition (CVD) process, a physical vapor deposition (PVD) process, an electroplating process, an electrochemical plating process, an electroless plating process, one or more other applicable processes, or a combination thereof. In some embodiments, a thermal operation is applied on the deposited conductive material to complete the formation of the conductive layer 104. The thermal operation may be performed at a temperature in a range from about 300 degrees C. to about 400 degrees C. The operation time may be in a range from about 10 minutes to about 30 minutes.
[0019] As shown in
[0020] As shown in
[0021] As shown in
[0022] In some embodiments, the mask elements 110 are a patterned photoresist layer. In some embodiments, the patterned photoresist layer contains metal. In some embodiments, the mask element 110 is a metal-containing organic-inorganic hybrid. For example, the mask elements 110 are made of a mixture of one or more polymer materials and one or more inorganic materials. The inorganic materials may include zirconium oxide, titanium oxide, one or more other suitable materials, or a combination thereof. A photolithography process may be used to form the mask elements 110. The photolithography process may include photoresist coating (e.g., spin-on coating), soft baking, mask aligning, exposure (e.g., extreme ultra-violet light illumination), post-exposure baking, developing the photoresist, rinsing, drying (e.g., hard baking), one or more other suitable operations, or a combination thereof.
[0023] As shown in
[0024] In some embodiments, the etch stop layer 106 is partially removed to expose the conductive layer 104 using an etching process. The etching process may be performed in-situ in the same processing chamber where the sacrificial layer 108 is etched. Alternatively, the sacrificial layer 108 and the etch stop layer 106 are etched in different processing chambers.
[0025] As shown in
[0026] Instead of filling trenches with high aspect ratio in a dielectric layer, the conductive lines 104L are formed through etching the conductive layer 104. Therefore, the conductive lines 104L have substantially no void formed therein. The quality of the conductive lines 104L is improved.
[0027] In some embodiments, the mask elements 110 are then removed. The mask elements 110 may be removed using an ashing process, a wet striping process, one or more other applicable processes, or a combination thereof.
[0028] As shown in
[0029] Afterwards, mask elements 120 are formed over the planarization layer 118, as shown in
[0030] As shown in
[0031] Afterwards, the mask elements 120 and the planarization layer 118 are removed, in accordance with some embodiments. The mask elements 120 and the planarization layer 118 may be removed using an ashing process, a wet striping process, one or more other applicable processes, or a combination thereof.
[0032] As shown in
[0033] As the density of semiconductor devices increases and the size of circuit elements becomes smaller, the resistance capacitance (RC) delay time increasingly dominates circuit performance. Using a low-k dielectric material as the dielectric layer 104 is helpful for reducing the RC delay.
[0034] In some embodiments, the dielectric layer 126 includes a porous dielectric material, a spin-on inorganic dielectric, a spin-on organic dielectric, an organic polymer, an organic silica glass, SiOF series material, a hydrogen silsesquioxane (HSQ) series material, a methyl silsesquioxane (MSQ) series material, a porous organic series material, another suitable material, or a combination thereof. In some embodiments, the dielectric layer 126 includes a material containing Si, C, O, or H. For example, the dielectric layer 126 includes SiOC, SiO.sub.2, SiON, SiCOH, SiOCN, or a combination thereof. In some embodiments, the dielectric layer 126 is made of or includes carbon-doped silicon oxide. The carbon-doped silicon oxide may also be referred to as organosilicate glass (OSG) or C-oxide. In some embodiments, the dielectric layer 126 is deposited using a CVD process, an atomic layer deposition (ALD) process, a spin-on process, a spray coating process, one or more other applicable processes, or a combination thereof.
[0035] In some embodiments, the thermal operation for forming the conductive lines 104L has been performed before the formation of the dielectric layer 126. The dielectric layer 126 is prevented from suffering the thermal operation. The quality of the dielectric layer 126 is therefore improved.
[0036] In some embodiments, one or more closed holes (or seams) 128 are formed in the dielectric layer 126. The closed holes 128 may be formed between sidewalls of the neighboring conductive lines 104L. The closed holes 128 may be naturally formed during the filling of the dielectric layer 126 since spacing between the neighboring conductive lines 104L is small. The closed holes 128 may further reduce the dielectric constant of the dielectric layer 126. The RC delay issue may therefore be reduced or prevented.
[0037] As shown in
[0038] As shown in
[0039] As shown in
[0040] In some embodiments, materials of the dielectric layer 126 and each of the insulating elements 106′ are different from each other. In some embodiments, each of the insulating elements 106′ has a greater etching resistance than the dielectric layer 126.
[0041]
[0042] However, many variations and/or modifications can be made to embodiments of the disclosure. In some other embodiments, the etch stop layer 106 is completely removed to expose the conductive lines 104L. In these cases, no insulating element is formed on the conductive lines 104L.
[0043] As shown in
[0044] As shown in
[0045] After the planarization process, the top surfaces of the conductive vias 132′ are substantially coplanar with the top surface of the dielectric layer 126. In some embodiments, each of the conductive vias 132′ has a single layer structure. In some embodiments, each of the conductive vias 132′ is in direct contact with the conductive line 104L thereunder. In some embodiments, the materials of the conductive lines 104L and the conductive vias 132′ are different from each other.
[0046] In some embodiments, each of the conductive vias 132′ has an upper portion 134U and a protruding portion 134P, as shown in
[0047] As shown in
[0048] In some embodiments, each of the conductive vias 132′ shrinks from along a direction from a lower portion (such as from the bottom 135S.sub.1) towards an upper portion (such as the top 135S.sub.2). In some embodiments, each of the conductive lines 104L shrinks along a direction from the bottom of the conductive line 104L towards the corresponding conductive via 132′. In some embodiments, each of the insulating elements 106′ is substantially as wide as the top of the conductive line 104L thereunder. Each of the insulating elements 106′ is shorter than the conductive line 104L thereunder since the bottom may be wider than the top of the conductive line 104L.
[0049] In some embodiments, each of the conductive vias 132′ has an inclined sidewall. As shown in
[0050] As shown in
[0051] Afterwards, one or more conductive lines 136 and a dielectric layer 138 are formed over the conductive vias 132′ and the dielectric layer 126, as shown in
[0052] Many variations and/or modifications can be made to embodiments of the disclosure.
[0053] As shown in
[0054] The doping process 302 may include an ion implantation process, a diffusion process, one or more other applicable processes, or a combination thereof. The dopant used in the doping process 302 may include cobalt (Co), tantalum (Ta), titanium (Ti), one or more other suitable dopants, or a combination thereof.
[0055] In some embodiments, each of the barrier regions 304 surrounds an inner portion 105i of the corresponding conductive line 104L. Each of the barrier regions 304 has a greater dopant concentration than the inner portion 105i. In some embodiments, each of the barrier regions 304 does not extend across an entirety of the bottom surface 105b of the inner portion 105i.
[0056] Afterwards, processes the same as or similar to those illustrated in
[0057] Many variations and/or modifications can be made to embodiments of the disclosure. In some other embodiments, the doping process 302 is performed before the dummy elements 124 are formed. For example, the doping process 302 is performed at the stage illustrated in
[0058] Embodiments of the disclosure form a semiconductor device structure with self-aligned conductive lines and conductive vias. Dummy elements with a line pattern are used to assist in the formation of conductive lines under the dummy elements. Afterwards, the dummy elements are modified by etching to have a via pattern. Afterwards, a dielectric layer is formed to surround the conductive lines and the modified dummy elements. The modified dummy elements are removed to leave via holes that are self-aligned with the conductive lines. Conductive vias are then formed in the via holes. The semiconductor device structure with self-aligned conductive features is therefore obtained.
[0059] In accordance with some embodiments, a semiconductor device structure is provided. The semiconductor device structure includes a semiconductor substrate and a conductive line over the semiconductor substrate. The conductive line has a barrier region surrounding an inner portion of the conductive line, and the barrier region has a greater dopant concentration than the inner portion. The semiconductor device structure also includes a conductive via on the conductive line. The semiconductor device structure further includes a dielectric layer over the semiconductor substrate. The dielectric layer surrounds the conductive line and the conductive via.
[0060] In accordance with some embodiments, a semiconductor device structure is provided. The semiconductor device structure includes a substrate and a first conductive feature over the substrate. The first conductive feature shrinks along a first direction from a bottom portion of the first conductive feature towards a top portion of the first conductive feature. The semiconductor device structure also includes a second conductive feature on the first conductive feature. The second conductive feature has an upper portion and a protruding portion, the protruding portion is between the upper portion and the first conductive feature. The upper portion shrinks along the first direction, and a bottom of the upper portion is narrower than the first conductive feature. The semiconductor device structure further includes a dielectric layer surrounding the first conductive feature and the second conductive feature.
[0061] In accordance with some embodiments, a semiconductor device structure is provided. The semiconductor device structure includes a semiconductor substrate and a conductive line over the semiconductor substrate. The conductive line shrinks along a direction from a lower portion of the conductive line towards an upper portion of the conductive line. The semiconductor device structure also includes a first conductive via and a second conductive via on the conductive line. The first conductive via and the second conductive via shrink along a direction from lower portions of the first conductive via and the second conductive via respectively towards upper portions of the first conductive via and the second conductive via. The semiconductor device structure further includes an insulating element over the conductive line and surrounding the first conductive via and the second conductive via and separating the first conductive via from the second conductive via.
[0062] The foregoing outlines features of several embodiments so that those skilled in the art may better understand the aspects of the present disclosure. Those skilled in the art should appreciate that they may readily use the present disclosure as a basis for designing or modifying other processes and structures for carrying out the same purposes and/or achieving the same advantages of the embodiments introduced herein. Those skilled in the art should also realize that such equivalent constructions do not depart from the spirit and scope of the present disclosure, and that they may make various changes, substitutions, and alterations herein without departing from the spirit and scope of the present disclosure.