In a method of forming a two-dimensional material layer, a nucleation pattern is formed over a substrate, and a transition metal dichalcogenide (TMD) layer is formed such that the TMD layer laterally grows from the nucleation pattern. In one or more of the foregoing and following embodiments, the TMD layer is single crystalline.

There is provided a film forming method including: adsorbing fluorine onto a substrate on which a region in which a nitride film is exposed and a region in which an oxide film is exposed are provided adjacent to each other by supplying a fluorine-containing gas to the substrate, and forming a stepped surface on a side surface of the oxide film by selectively etching the nitride film, among the nitride film and the oxide film, so as to cause a surface of the nitride film to be more deeply recessed than a surface of the oxide film; and after the adsorbing the fluorine onto the substrate and forming the stepped surface, selectively forming a semiconductor film on the nitride film, among the nitride film and the oxide film, by supplying a raw material gas including a semiconductor material to the substrate.

The present disclosure relates to a semi-conductor structure and method for co-integrating a III-V device with a group IV device on a Si.sub.xGe.sub.1-x(100) substrate. The method includes: (a) providing a Si.sub.xGe.sub.1-x(100) substrate, where x is from 0 to 1; (b) selecting a first region for forming therein a group IV device and a second region for forming therein a III-V device, the first and the second region each comprising a section of the Si.sub.xGe.sub.1-x(100) substrate; (c) forming a trench isolation for at least the III-V device; (d) providing a Si.sub.yGe.sub.1-y(100) surface in the first region, where y is from 0 to 1; (e) at least partially forming the group IV device on the Si.sub.yGe.sub.1-y(100) surface in the first region; (f) forming a trench in the second region which exposes the Si.sub.xGe.sub.1-x(100) substrate, the trench having a depth of at least 200 nm, at least 500 nm, at least 1 μm, usually at least 2 μm, such as 4 μm, with respect to the Si.sub.yGe.sub.1-y(100) surface in the first region; (g) growing a III-V material in the trench using aspect ratio trapping; and (h) forming the III-V device on the III-V material, the III-V device comprising at least one contact region at a height within 100 nm, 50 nm, 20 nm, usually 10 nm, of a contact region of the group IV device.

A method for forming a doped layer is disclosed. The doped layer may be used in a NMOS or a silicon germanium application. The doped layer may be created using an n-type halide species in a n-type dopant application, for example.

A method of fabricating a hollow wall for controlling directional deposition of material comprises: forming a layer of resist on a substrate; removing a portion of the resist selectively to form a channel in the resist; forming a layer of an amorphous dielectric material in the channel; and removing the resist to form the hollow wall. The channel has a front surface configured to prevent bending of a corresponding front face of the hollow wall. The hollow wall is useful for controlling deposition of material when fabricating semiconductor-superconductor hybrid devices, for example. By configuring the channel appropriately, bending of the hollow wall can be prevented, allowing for more precise deposition of material. Also provided is a further method of fabricating a hollow wall; and a method of fabricating a device using the hollow walls.

The present disclosure describes a semiconductor device and methods for forming the same. The semiconductor device includes nanostructures on a substrate and a source/drain region in contact with the nanostructures. The source/drain region includes epitaxial end caps, where each epitaxial end cap is formed at an end portion of a nanostructure of the nanostructures. The source/drain region also includes an epitaxial body in contact with the epitaxial end caps and an epitaxial top cap formed on the epitaxial body. The semiconductor device further includes gate structure formed on the nanostructures.

A method of generating a germanium structure includes performing an epitaxial depositing process on an assembly of a silicon substrate and an oxide layer, wherein one or more trenches in the oxide layer expose surface portions of the silicon substrate. The epitaxial depositing process includes depositing germanium onto the assembly during a first phase, performing an etch process during a second phase following the first phase in order to remove germanium from the oxide layer, and repeating the first and second phases. A germanium crystal is grown in the trench or trenches. An optical device includes a light-incidence surface formed by a raw textured surface of a germanium structure obtained by an epitaxial depositing process without processing the surface of the germanium structure after the epitaxial process.

A method of depositing a silicon film on a recess formed in a surface of a substrate is provided. The substrate is placed on a rotary table in a vacuum vessel, so as to pass through first, second, and third processing regions in the vacuum vessel. An interior of the vacuum vessel is set to a first temperature capable of breaking an Si—H bond. In the first processing region, Si.sub.2H.sub.6 gas having a temperature less than the first temperature is supplied to form an SiH.sub.3 molecular layer on its surface. In the second processing region, a silicon atomic layer is exposed on the surface of the substrate, by breaking the Si—H bond in the SiH.sub.3 molecular layer. In the third processing region, by anisotropic etching, the silicon atomic layer on an upper portion of an inner wall of the recess is selectively removed.

A method of forming Si or Ge-based and III-V based vertically integrated nanowires on a single substrate and the resulting device are provided. Embodiments include forming first trenches in a Si, Ge, III-V, or Si.sub.xGe.sub.1-x substrate; forming a conformal SiN, SiO.sub.xC.sub.yN.sub.z layer over side and bottom surfaces of the first trenches; filling the first trenches with SiO.sub.x; forming a first mask over portions of the Si, Ge, III-V, or Si.sub.xGe.sub.1-x substrate; removing exposed portions of the Si, Ge, III-V, or Si.sub.xGe.sub.1-x substrate, forming second trenches; forming III-V, III-V.sub.xM.sub.y, or Si nanowires in the second trenches; removing the first mask and forming a second mask over the III-V, III-V.sub.xM.sub.y, or Si nanowires and intervening first trenches; removing the SiO.sub.x layer, forming third trenches; and removing the second mask.

In a semiconductor manufacturing method, a mask is disposed on a semiconductor layer or semiconductor substrate. The semiconductor layer or semiconductor substrate is etched in an area delineated by the mask to form a cavity. With the mask disposed on the semiconductor layer or semiconductor substrate, the cavity is lined to form a containment structure. With the mask disposed on the semiconductor layer or semiconductor substrate, the containment structure is filled with a base semiconductor material. After filling the containment structure with the base semiconductor material, the mask is removed. At least one semiconductor device is fabricated in and/or on the base semiconductor material deposited in the containment structure.