Method for manufacturing semiconductor device by removing carrier after forming re-distribution layer
12593657 ยท 2026-03-31
Inventors
- Hiroaki Matsubara (Tokyo, JP)
- Daisuke Ikeda (Tokyo, JP)
- Keisuke Okawara (Tokyo, JP)
- Shogo Sobue (Tokyo, JP)
- Saeko Ogawa (Tokyo, JP)
Cpc classification
H10P72/7432
ELECTRICITY
H10W72/07204
ELECTRICITY
International classification
Abstract
A method for manufacturing a semiconductor device includes preparing a temporary fixing structure body in which semiconductor elements each including a first surface on which a connection terminal is formed and a second surface are attached to a temporary fixing material, forming a curable bonding adhesive layer on the second surface of each of the semiconductor elements, attaching a carrier to one surface of the curable bonding adhesive layer opposite to the semiconductor elements, fixing the semiconductor elements to the carrier by curing the curable bonding adhesive layer, and removing the temporary fixing material. The semiconductor elements are attached onto the temporary fixing material such that the first surface of each of the semiconductor elements is directed toward the temporary fixing material, and are encapsulated with an encapsulant material such that the second surface of each of the semiconductor elements is exposed from an encapsulant material layer.
Claims
1. A method for manufacturing a semiconductor device, comprising: preparing a temporary fixing structure body in which a plurality of semiconductor elements each including a first surface on which a connection terminal is formed and a second surface on a side opposite to the first surface are attached to a temporary fixing material, in the temporary fixing structure body, the plurality of semiconductor elements being attached onto the temporary fixing material such that the first surface of each of the plurality of semiconductor elements is directed toward the temporary fixing material, and the plurality of semiconductor elements being encapsulated with an encapsulant material such that the second surface of each of the plurality of semiconductor elements is exposed from an encapsulant material layer, forming a curable bonding adhesive layer on the second surface of each of the plurality of semiconductor elements; attaching a carrier to one surface of the curable bonding adhesive layer on a side opposite to the plurality of semiconductor elements; fixing the plurality of semiconductor elements to the carrier by curing the curable bonding adhesive layer through the cured curable bonding adhesive layer; removing the temporary fixing material; forming a re-distribution layer on the first surface of each of the plurality of semiconductor elements in a state in which the plurality of semiconductor elements are fixed to the carrier; and removing the carrier after forming the re-distribution layer, wherein the carrier is removed from the cured curable bonding adhesive layer.
2. The method for manufacturing a semiconductor device according to claim 1, wherein the carrier is a glass substrate, and wherein a bonding adhesive strength of the curable bonding adhesive layer to the glass substrate is 1 MPa or more when the curable bonding adhesive layer is cured, and is 5 MPa or less when the curable bonding adhesive layer is irradiated with laser.
3. The method for manufacturing a semiconductor device according to claim 1, wherein the curable bonding adhesive layer includes a resin composition containing a thermoplastic resin and an epoxy curing agent, and a glass transition temperature of the thermoplastic resin is 40 C. or higher and 40 C. or lower.
4. The method for manufacturing a semiconductor device according to claim 1, wherein a thickness of the curable bonding adhesive layer is 1 m or more and 400 m or less after curing.
5. The method for manufacturing a semiconductor device according to claim 1, wherein the carrier is a glass substrate or a transparent resin substrate, and a thickness thereof is 0.1 mm or more and 2.0 mm or less.
6. The method for manufacturing a semiconductor device according to claim 1, further comprising: attaching a solder ball to the connection terminal of each of the plurality of semiconductor elements or the re-distribution layer in a state in which the plurality of semiconductor elements are fixed to the carrier.
7. The method for manufacturing a semiconductor device according to claim 1, wherein the carrier is a light transmissive substrate, and wherein, in the removing of the carrier, the carrier is removed by irradiating the cured curable bonding adhesive layer with laser light from the carrier side.
8. The method for manufacturing a semiconductor device according to claim 1, wherein, in the removing of the carrier, the carrier is removed by applying laser light such that peeling energy for peeling off the carrier is 1 kW/cm.sup.2 or more and 200 kW/cm.sup.2 or less.
9. The method for manufacturing a semiconductor device according to claim 1, wherein, in the removing of the carrier, the carrier is removed by scraping or melting the carrier.
10. The method for manufacturing a semiconductor device according to claim 1, further comprising: cleaning an exposed surface of either the cured curable bonding adhesive layer or the encapsulant material layer of the encapsulant material after the removing of the carrier.
11. The method for manufacturing a semiconductor device according to claim 1, further comprising: singulating the plurality of semiconductor elements after the removing of the carrier.
12. The method for manufacturing a semiconductor device according to claim 11, wherein, in the singulating of the plurality of semiconductor elements, the cured curable bonding adhesive layer is singulated together with the plurality of semiconductor elements, and wherein, the semiconductor device is acquired from each of the plurality of semiconductor elements in which the second surface is protected with the curable bonding adhesive layer.
13. The method for manufacturing a semiconductor device according to claim 1, wherein the preparing of the temporary fixing structure body includes; preparing the temporary fixing material; attaching the plurality of semiconductor elements to the temporary fixing material such that the first surface of each of the plurality of semiconductor elements is directed toward the temporary fixing material; and encapsulating the plurality of semiconductor elements with the encapsulant material such that the second surface of each of the plurality of semiconductor elements attached to the temporary fixing material is exposed from the encapsulant material layer.
14. The method for manufacturing a semiconductor device according to claim 1, wherein, in the preparing of the temporary fixing structure body, the temporary fixing structure body in which a plurality of electronic components are attached to the temporary fixing material together with the plurality of semiconductor elements is prepared, and wherein, in the fixing of the plurality of semiconductor elements, the plurality of electronic components are fixed to the carrier by curing the curable bonding adhesive layer.
15. The method for manufacturing a semiconductor device according to claim 1, wherein a bonding adhesive strength between the cured curable bonding adhesive layer and the encapsulant material is 4.0 MPa or more.
16. The method for manufacturing a semiconductor device according to claim 1, wherein the bonding adhesive strength between the cured curable bonding adhesive layer and the encapsulant material is 8.0 MPa or less.
17. The method for manufacturing a semiconductor device according to claim 1, wherein a bonding adhesive strength between the cured curable bonding adhesive layer and the encapsulant material is 20 MPa or more.
18. The method for manufacturing a semiconductor device according to claim 1, wherein a bonding adhesive strength between the cured curable bonding adhesive layer and the plurality of semiconductor elements is 4.0 MPa or more.
19. The method for manufacturing a semiconductor device according to claim 1, wherein the semiconductor device in a state in which the cured curable bonding adhesive layer protects the second surface of each of the plurality of semiconductor elements is acquired.
Description
BRIEF DESCRIPTION OF DRAWINGS
(1)
(2)
(3)
(4)
(5)
(6)
(7)
DESCRIPTION OF EMBODIMENTS
(8) Hereinafter, several embodiments of the present disclosure will be described in detail, with reference to the drawings, as necessary. The present disclosure is not limited to the following embodiments. In the following description, the same reference numerals will be applied to the same or corresponding parts, and the repeated description will be omitted. A positional relationship such as the left, right, top, and bottom is based on a positional relationship illustrated in the drawings, unless otherwise specified. A dimension ratio in the drawings is not limited to the illustrated ratio.
(9) In this specification, the term layer includes not only a structure in which a layer is formed on the entire surface but also a structure in which a layer is formed on a part of the surface when observed as a plan view. In this specification, the term step includes not only an independent step but also a step that is not explicitly distinguishable from other steps insofar as a desired function of the step is attained.
(10) In this specification, a numerical range represented by using to indicates a range including numerical values described before and after to as the minimum value and the maximum value, respectively. In a numerical range described in a stepwise manner in this specification, the upper limit value or the lower limit value of the numerical range in a certain step may be replaced with the upper limit value or the lower limit value of the numerical range in another step. In the numerical range described in this specification, the upper limit value or the lower limit value of the numerical range may be replaced with a value described in Examples.
(11) (Configuration of Semiconductor Device)
(12)
(13) (Method for Manufacturing Semiconductor Device)
(14) Next, a method for manufacturing the semiconductor device 1 will be described with reference to
(15) As illustrated in
(16) Subsequently, in a case where the temporary fixing structure body 22 is formed (prepared), as illustrated in
(17) The curable bonding adhesive layer 26, for example, can include a member (a curable resin film) in which a resin composition that is a curable bonding adhesive agent is formed into the shape of a film, and can be a member for fixing the plurality of semiconductor elements 10 and the encapsulant material layer 24 to the carrier 28 by being attached to the encapsulant material layer 24, and then, by being cured. The curable bonding adhesive agent configuring the curable bonding adhesive layer 26 is a bonding adhesive agent cured by at least one of heat and light, and for example, is a resin composition containing a thermoplastic resin and an epoxy curing agent. The thermoplastic resin contained in the curable bonding adhesive agent has a glass transition temperature of 40 C. or higher and 40 C. or lower. Such a curable bonding adhesive layer 26 may be configured in advance such that the thickness after curing, for example, is 1 m or more and 400 m or more. The curable resin film configuring the curable bonding adhesive layer 26 may have tackiness at 25 C., and more specifically, may have tackiness to the extent of being attached to the glass substrate in the environment of 25 C. A bonding adhesive strength of the curable bonding adhesive layer 26 to the carrier 28 may be 1 MPa or more in a case where the curable bonding adhesive layer 26 is cured, and may be 5 MPa or less in a case where the curable bonding adhesive layer 26 is irradiated with laser.
(18) It is preferable that the curable bonding adhesive layer 26 is a portion to be heated by laser irradiation in a laser peeling step described below (refer to
(19) The thermoplastic resin configuring the curable bonding adhesive layer 26 may have a reactive group. The reactive group of the thermoplastic resin, for example, may be an epoxy group. The thermoplastic resin may be a (meth)acrylic copolymer, or may be a (meth)acrylic copolymer having a reactive group. In this specification, (meth)acryl is used as the term indicating acryl or methacryl. The same applies to other similar expressions.
(20) The (meth)acrylic copolymer is a copolymer containing a (meth)acrylic monomer having a (meth)acryloyl group, as a monomer unit. The (meth)acrylic copolymer may be a copolymer containing a (meth)acrylic monomer forming a homopolymer with a glass transition temperature of 50 C. or higher, a (meth)acrylic monomer forming a homopolymer with a glass transition temperature of 0 C. or lower, and a (meth)acrylic monomer having an epoxy group, as a monomer unit. A glass transition temperature of a homopolymer formed by the (meth)acrylic monomer having an epoxy group is not limited. The (meth)acrylic monomer forming the homopolymer with the glass transition temperature of 50 C. or higher and the (meth)acrylic monomer forming the homopolymer with the glass transition temperature of 0 C. or lower can be a monomer not having an epoxy group.
(21) A weight average molecular weight of the thermoplastic resin configuring the curable bonding adhesive layer 26 may be 200000 or more and 1000000 or less. Here, the weight average molecular weight can be a value in terms of standard polystyrene, which is measured by gel permeation chromatography. The content of the thermoplastic resin may be 10% by mass or more and 80% by mass or less, on the basis of the mass of the film configuring the curable bonding adhesive layer 26.
(22) The curable resin film configuring the curable bonding adhesive layer 26 may further contain a curable resin that is a compound having a reactive group. The curable resin may be an epoxy resin having two or more epoxy groups, and examples thereof include a bisphenol A-type epoxy resin, a bisphenol F-type epoxy resin, a phenol novolac-type epoxy resin, and a cresol novolac-type epoxy resin. A molecular weight of the curable resin may be 3000 or less. The curable bonding adhesive layer 26 containing the curable resin is likely to have curing properties and suitable tackiness. The content of the curable resin may be 1% by mass or more and 50% by mass or less, on the basis of the mass of the curable resin film configuring the curable bonding adhesive layer 26.
(23) The curable bonding adhesive layer 26 may further contain a silica filler. The content of the silica filler may be 1% by mass or more and 60% by mass or less, or 5% by mass or more and 60% by mass or less, on the basis of the mass of the film configuring the curable bonding adhesive layer 26.
(24) The curable bonding adhesive layer 26 may further contain a curing agent reacting with any one or both of the reactive group of the thermoplastic resin and the reactive group of the curable resin. The curing agent, for example, may be a phenolic resin. In a case where the curable bonding adhesive layer 26 contains the curing agent, the curable bonding adhesive layer 26 may further contain a curing accelerator accelerating the reaction of the curing agent. For example, in a case where the curing agent is the phenolic resin, the curing accelerator may be an imidazole compound.
(25) Subsequently, in a case where the attaching of the carrier 28 is ended, as illustrated in
(26) Subsequently, in a case where the temporary fixing material 20 is removed, as illustrated in
(27) Subsequently, in a case where the re-distribution layer is formed, as illustrated in
(28) Subsequently, in a case where the attaching of the solder ball 32 is performed, laser marking is performed with respect to the cured layer 26a by irradiating the cured layer 26a with laser light from the carrier 28 side to write necessary information such as a product name, and as illustrated in
(29) When the carrier 28 is removed from the cured layer 26a, the carrier 28 may be removed by applying the laser light such that peeling energy for peeling off the carrier 28 is 1 kW/cm.sup.2 or more and 200 kW/cm.sup.2 or less. In this case, since the carrier can be removed with low energy, it is possible to minimally suppress a heat damage to the semiconductor element 10 or the like, and to minimally suppress the dust generated after the laser irradiation. In addition, since the laser to be applied has low energy, it is possible to shorten the time for removing the carrier.
(30) In the carrier removing step described above, a method for peeling off the carrier by the laser light is used, but a method for removing the carrier is not limited thereto. For example, the carrier 28 may be scraped from the cured layer 26a, or the carrier 28 or the like may be dissolved (melted) in a predetermined solvent. In such a removing step, the cured layer 26a may be removed together. After such a removing step, the exposed surface of the cured layer 26a, or the exposed surface of the encapsulant material layer 24 of the encapsulant material in a case where the cured layer 26a is removed may be cleaned by a predetermined method. Accordingly, it is possible to make the surface side of the semiconductor device 1 that is the final product cleaner. In a case where the carrier 28 is removed by such a method, the carrier 28 may be a light transmissive substrate, and the curable bonding adhesive layer 26 may not contain the light absorbing agent.
(31) Subsequently, in a case where the removing of the carrier 28 is ended, as illustrated in
(32) Here, a function effect of the method for manufacturing the semiconductor device 1 according to this embodiment will be described in contrast to a method of Comparative Example.
(33) As illustrated in
(34) Subsequently, as illustrated in
(35) Subsequently, in a case where the solder balls 128 are formed, as illustrated in
(36) As described above, in the method according to Comparative Example, the temporary fixing material 120 does not have heat resistance and chemical resistance, and thus, as illustrated in
(37) In the method of Comparative Example, as illustrated in
(38) In the method of Comparative Example, as illustrated in
(39) In the method of Comparative Example, as illustrated in
(40) In the method of Comparative Example, as illustrated in
(41) As described above, in the manufacturing method according to this embodiment, it is possible to simplify the steps of manufacturing the semiconductor device 1 having a fan-out structure, compared to the method of Comparative Example. In addition, by suppressing the warpage or the distortion of the encapsulant material layer 24 in which the semiconductor elements 10 are encapsulated, it is possible to improve the flatness, and to construct the fine re-distribution layer 30. Further, the fine re-distribution layer 30 can be constructed, and thus it is also possible to reduce the height of the semiconductor device 1.
(42) In the manufacturing method according to this embodiment, a bonding adhesive strength between the cured curable bonding adhesive layer (the cured layer 26a) and the encapsulant material layer 24 may be 4.0 MPa or more. In this case, it is possible to keep the bonding adhesive strength between the cured layer 26a and the encapsulant material layer 24 strong, to prevent peeling after package assembly, and to allow the cured layer 26a to function as it is as a part (the protective layer 12) of the final product of the semiconductor device 1. In this case, the bonding adhesive strength between the cured layer 26a and the encapsulant material layer 24 may be 8.0 MPa or less. The bonding adhesive strength between the cured layer 26a and the encapsulant material layer 24 may be 20 MPa or more. In this case, it is possible to keep the bonding adhesive strength between the cured layer 26a and the encapsulant material layer 24 stronger, to prevent the peeling after the package assembly, and to allow the cured layer 26a to function as it is as a part (the protective layer 12) of the final product of the semiconductor device 1.
(43) In the manufacturing method according to this embodiment, a bonding adhesive strength between the cured curable bonding adhesive layer (the cured layer 26a) and the plurality of semiconductor elements 10 may be 4.0 MPa or more. In this case, it is possible to keep the bonding adhesive strength between cured layer 26a and the plurality of semiconductor elements 10 (for example, silicon chips) strong, to prevent the peeling after the package assembly, and to allow the cured layer 26a to function as it is as a part of the final product of the semiconductor device 1.
(44) In the manufacturing method according to this embodiment, the semiconductor device 1 in a state where the cured curable bonding adhesive layer (the cured layer 26a) protects the second surface 10b of each of the plurality of semiconductor elements 10 may be acquired. In this case, it is possible to allow the cured layer 26a used in the manufacturing to function as it is as a part (the protective layer 12) of the final product of the semiconductor device 1.
(45) The embodiment of the present disclosure has been described in detail, but the present disclosure is not limited to the embodiment described above, and can be applied to various embodiments. For example, in the embodiment described above, the method for manufacturing the semiconductor device 1 including the semiconductor element 10 is described, but the present disclosure may be applied to a method for manufacturing a semiconductor device or a device including a plurality of electronic components in addition to or instead of the semiconductor elements 10. In this case, in the attaching step illustrated in
Examples
(46) Hereinafter, the present invention will be described in more detail by using Examples. Here, the present invention is not limited to such examples. In the following examples, the bonding adhesive strength between the curable bonding adhesive layer 26 (the cured layer 26a after curing, and the protective layer 12) and the encapsulant material layer 24, used in the method for manufacturing a semiconductor device according to the embodiment described above, and the peeling energy for the glass substrate (the carrier 28) from the cured layer 26a will be described. The bonding adhesive strength between the cured layer 26a and the encapsulant material layer 24 can be applied to the bonding adhesive strength between the cured layer 26a and the semiconductor elements 10.
(47) As raw materials for the curable bonding adhesive layer, the followings were prepared.
(48) [Thermoplastic Resin]
(49) Acrylic polymer having epoxy group: (Glass transition temperature: 12 C.)
[Epoxy Resin] Bisphenol F-Type liquid epoxy resin: YDF-8170C (Product name, manufactured by NIPPON STEEL Chemical & Material Co., Ltd.) Cresol novolac-type epoxy resin: N-500P-10 (Product name, manufactured by DIC Corporation)
[Curing Agent] Phenolic resin: PSM-4326 (Product name, manufactured by Gun Ei Chemical Industry Co., Ltd.) Phenolic resin: MEH-7800M (Product name, manufactured by Meiwa Plastic Industries, Ltd.)
[Silica Filler] SC2050-HLG (Product name, manufactured by ADMATECHS COMPANY LIMITED) R972 (Product name, manufactured by NIPPON AEROSIL CO., LTD.)
[Light Absorbing Agent] Carbon black: FP-Black (Product name, manufactured by SANYO COLOR WORKS, Ltd.)
[Coupling Agent] (3-mercaptopropyl) trimethoxysilane: A-189 (Product name, manufactured by Momentive Performance Materials) 3-ureidopropyl triethoxysilane: A-1160 (Product name, manufactured by Momentive Performance Materials)
[Curing Accelerator] 1-cyanoethyl-2-phenylimidazole: 2PZ-CN (Product name, manufactured by SHIKOKU CHEMICALS CORPORATION)
(50) Subsequently, as a material used in the curable bonding adhesive layer, a resin varnish containing each raw material at a compound ratio shown in Table 1 described below, and cyclohexanone as a solvent was prepared. The total concentration of components other than the solvent in the resin varnish was 40% by mass, on the basis of the mass of the varnish.
(51) TABLE-US-00001 TABLE 1 Curable resin film Raw material A B Thermoplastic resin (Glass 15 65 transition temperature: 12 C.) Epoxy resin YDF-8170C 15 N-500P-10 5 15 Curing agent PSM-4326 15 MEH-7800M 10 Silica filler SC2050-HLG 50 R972 10 Light absorbing FP-Black 3 3 agent Coupling agent A-189 0.1 0.4 A-1160 0.3 1.1 Curing 2PZ-CN 0.05 0.03 accelerator
(52) A support film was coated with each varnish, and the coated film was dried to form a curable resin film on the support film. A protective film was placed on the curable resin film, and a film A or B including the support film, the curable resin film, and the protective film was obtained. The thickness of the curable resin film when cured was 20 m.
(53) [Evaluation of Adhesiveness to Encapsulant Material]
(54) A glass substrate having a 12-inch size (a thickness of 700 m) was cut out into a 9 mm9 mm size by using a blade dicer (Product Name, DAD3360, manufactured by DISCO Corporation). The protective film was peeled off from the film A or the film B, and the exposed curable resin film of the film A or B was placed on the glass substrate having a 9 mm9 mm size, and the curable resin film and the glass substrate were attached by using a vacuum laminator (Product Name, V-130, manufactured by Nikko-Materials Co., Ltd.). The condition of the vacuum laminator was set to an upper platen temperature of 90 C., a lower platen temperature of 40 C., a pressure of 0.5 MPa, and a pressurization time of 60 seconds.
(55) Subsequently, in a case where the attaching was ended, the curable resin film was cured in each condition by using an atmospheric oven (Product Name, PHH-202, manufactured by ESPEC CORP.) or a nitrogen oven (Product Name, CLH-21CD, manufactured by KOYO THERMO SYSTEMS CO., LTD.). An encapsulating body (the encapsulant material layer) was formed on the protective layer that is the cured curable resin film by using an encapsulant material (Product Name, CEL-400ZHF40, manufactured by Showa Denko Materials Co., Ltd.) and a molding device (Product Name, ADM-12, manufactured by MEMO CO., LTD.). A bonding adhesive area between the encapsulating body and the protective layer was 10 mm.sup.2. The condition of the molding device was set to an encapsulating temperature of 130 C. and a curing time of 600 seconds. The encapsulating body formed by using the oven was heated to 175 C. for 4 hours such that the encapsulating body was further cured. Accordingly, a laminated body for evaluation including the glass substrate, the protective layer, and the encapsulating body was obtained.
(56) Next, a shear jig was scanned in parallel to the main surface of the glass substrate by using a bond tester (Product Name, System650, manufactured by Royce Instruments, Inc.), and a shear stress obtained by cutting off the formed encapsulating body was measured as a bonding adhesive strength between the encapsulating body and the protective layer. The bonding adhesive area between the encapsulating body and the protective layer was set to 10 mm.sup.2, a manipulation rate of the shear jig was set to 50 m/s, and clearance was set to 100 m on the basis of the protective layer formed on the glass substrate. The results of the bonding adhesive strength in a curing condition of the protective layer of each example are shown in Table 2 and Table 3. The bonding adhesive strength to the encapsulating body shown in Table 2 and Table 3 described below indicates the average value obtained by performing a test 10 times for each example. The temperature at the time of measuring the bonding adhesive strength was a room temperature (25 C.). The bonding adhesive strength in this specification is measured by the method described above.
(57) TABLE-US-00002 TABLE 2 Item Example 1 Example 2 Example 3 Example 4 Type of A A A A protective layer Curing 130 C. for 170 C. for 170 C. for 200 C. for condition of 30 minutes 60 minutes 60 minutes 60 minutes protective 170 C. for Under Under nitrogen Under nitrogen layer 60 minutes atmosphere atmosphere atmosphere Under atmosphere Bonding 4.9 6.0 6.9 7.5 adhesive strength to encapsulating body [MPa]
(58) TABLE-US-00003 TABLE 3 Item Example 5 Example 6 Example 7 Example 8 Type of B B B B protective layer Curing 130 C. for 170 C. for 170 C. for 200 C. for condition of 30 minutes 60 minutes 60 minutes 60 minutes protective 170 C. for Under Under nitrogen Under nitrogen layer 60 minutes atmosphere atmosphere atmosphere Under atmosphere Bonding 25.3 25.4 24.0 26.0 adhesive strength to encapsulating body [MPa]
(59) As shown in Table 2 and Table 3 described above, by setting the curing condition of the protective layer to a predetermined range, it was possible to confirm that the cured layer to be the protective layer was capable of adhering to the encapsulant material layer at 4.0 MPa or more. Similarly, it was possible to confirm that the cured layer to be the protective layer was capable of adhering to the encapsulant material layer at 20 MPa or more.
(60) [Laser Peeling Test]
(61) Next, the same film A and film B as those in the tests of Examples 1 to 8 described above were prepared, the curable resin film exposed by peeling off the protective film from the film A or the film B was placed on a glass substrate (60 mm60 mm, a thickness of 700 m), and the curable resin film and the glass substrate were attached by a vacuum laminator (Product Name, V-130, manufactured by Nikko-Materials Co., Ltd.). The condition of the vacuum laminator was set to an upper platen temperature of 90 C., a lower platen temperature of 40 C., a pressure of MPa, and a pressurization time of 60 seconds. The curable resin film was cured by heating at 130 C. for 20 minutes, and then, heating at 170 C. for 2 hours using the oven. The encapsulant material layer was formed on the protective layer that is the cured curable resin film in the condition of 150 C. for 300 seconds by using an encapsulant material containing an epoxy resin and a molding device (Product Name, CPM1080, manufactured by TOWA CORPORATION). The formed encapsulant material layer was further cured by heating at 150 C. for 6 hours. Accordingly, a laminated body for evaluation having a three-layer structure, including the glass substrate, the protective layer, and the encapsulant material layer, was obtained.
(62) The laminated body for evaluation was irradiated with UV laser light at a wavelength of 355 nm in a direction perpendicular to the glass substrate to peel off the glass substrate. After the irradiation, a case where the encapsulant material layer with the protective layer and the glass substrate were easily peeled off was evaluated as A, a case where the encapsulant material layer with the protective layer and the glass substrate were peeled off by making a notch with a cutter was evaluated as B, and peeling results in each irradiation condition of the UV laser light were shown in Table 4 and Table 5. By applying the laser light, there was no decrease in the bonding adhesive strength between the protective layer and the encapsulant material layer.
(63) TABLE-US-00004 TABLE 4 Example Example Example Example Item 9 10 11 12 Type of protective layer A A A A Laser Peeling 18.5 46.8 73.9 100.6 peeling test energy [kw/cm.sup.2] Output [mW] 58 147 232 316 Repetition 76 65 59 55 frequency [KHz] Scanning 760 650 590 550 rate [mm/s] Pitch [m] 9 9 9 9 Overlap [%] 50 50 50 50 Peeling B A A A properties
(64) TABLE-US-00005 TABLE 5 Item Example 13 Example 14 Example 15 Type of protective layer B B B Laser peeling Peeling energy 18.5 100.6 166.6 test [kw/cm.sup.2] Output [mW] 58 316 523 Repetition 76 55 47 frequency [KHz] Scanning rate 760 550 470 [mm/s] Pitch [m] 9 9 9 Overlap [%] 50 50 50 Peeling B B A properties
(65) As shown in Table 4 and Table 5 described above, it was possible to check that peeling was available by setting the peeling energy when peeling off the glass substrate to be the carrier from the encapsulant material layer with the protective layer to 1 kW/cm.sup.2 or more and 200 kW/cm.sup.2 or less.
REFERENCE SIGNS LIST
(66) 1: semiconductor device, 10: semiconductor element, 10a: first surface, 10b: second surface, 10c: connection terminal, 20: temporary fixing material, 22: temporary fixing structure body, 24: encapsulant material layer, 26: curable bonding adhesive layer, 26a: cured layer, 28: carrier, 30: re-distribution layer, 32: solder ball, 34: dicing tape.