An epitaxial structure and a manufacturing method thereof, and a light-emitting diode (LED) device are provided. The epitaxial structure includes an N-type semiconductor layer, a multiple quantum well (MQW) active layer, and a P-type semiconductor layer sequentially stacked in a growth direction. The MQW active layer includes a front MQW active layer and a back MQW active layer sequentially stacked in the growth direction. The front MQW active layer includes at least two groups of first quantum barrier layers and first quantum well layers alternately stacked. The back MQW active layer includes at least two groups of second quantum barrier layers and second quantum well layers alternately stacked. A content of an aluminum (Al) component in each second quantum well layer is gradually increased in the growth direction, and a content of a gallium (Ga) component in each second quantum well layer is gradually decreased in the growth direction.

A method of forming Si or Ge-based and III-V based vertically integrated nanowires on a single substrate and the resulting device are provided. Embodiments include forming first trenches in a Si, Ge, III-V, or Si.sub.xGe.sub.1-x substrate; forming a conformal SiN, SiO.sub.xC.sub.yN.sub.z layer over side and bottom surfaces of the first trenches; filling the first trenches with SiO.sub.x; forming a first mask over portions of the Si, Ge, III-V, or Si.sub.xGe.sub.1-x substrate; removing exposed portions of the Si, Ge, III-V, or Si.sub.xGe.sub.1-x substrate, forming second trenches; forming III-V, III-V.sub.xM.sub.y, or Si nanowires in the second trenches; removing the first mask and forming a second mask over the III-V, III-V.sub.xM.sub.y, or Si nanowires and intervening first trenches; removing the SiO.sub.x layer, forming third trenches; and removing the second mask.

A recess and a recess are formed at places where a threading dislocation and a threading dislocation reach a surface of a third semiconductor layer. A through-hole and a through-hole are formed in a second semiconductor layer under places of the recess and the recess, the through-hole and the through-hole extending through the second semiconductor layer. A first semiconductor layer is oxidized through the recess, the recess, the through-hole, and the through-hole to form an insulation film that covers a lower surface of the second semiconductor layer. The third semiconductor layer is subjected to crystal regrowth.

A method for forming a material having a Perovskite single crystal structure includes alternately growing, on a substrate, each of a plurality of first layers and each of a plurality of second layers having compositions different from the plurality of first layers and forming a material having a Perovskite single crystal structure by annealing the plurality of first layers and the plurality of second layers.

A method of performing heteroepitaxy comprises exposing a substrate to a carrier gas, a first precursor gas, a Group II/III element, and a second precursor gas, to form a heteroepitaxial growth of one of GaAs, AlAs, InAs, GaP, InP, ZnSe, GaSe, CdSe, InSe, ZnTe, CdTe, GaTe, HgTe, GaSb, InSb, AlSb, CdS, GaN, and AlN on the substrate; wherein the substrate comprises one of GaAs, AlAs, InAs, GaP, InP, ZnSe, GaSe, CdSe, InSe, ZnTe, CdTe, GaTe, HgTe, GaSb, InSb, AlSb, CdS, GaN, and AlN; wherein the carrier gas is Hz, wherein the first precursor is HCl, the Group II/III element comprises at least one of Zn, Cd, Hg, Al, Ga, and In; and wherein the second precursor is one of AsH.sub.3 (arsine), PH.sub.3 (phosphine), H.sub.2Se (hydrogen selenide), H.sub.2Te (hydrogen telluride), SbH.sub.3 (hydrogen antimonide), H.sub.2S (hydrogen sulfide), and NH.sub.3 (ammonia). The process may be an HVPE (hydride vapor phase epitaxy) process.

A wafer includes a substrate and at least one intermediate layer formed on a surface of the substrate. The at least one intermediate layer covers the surface of the substrate at least partially. An outer surface of the at least one intermediate layer is directed away from the surface of the substrate. The wafer further includes nanostructures grown on the outer surface of the at least one intermediate layer. The at least one intermediate layer is formed in such a way that positions of growth of the nanostructures are predetermined on the outer surface of the at least one intermediate layer. At least one nanostructure material of the nanostructures is assembled at the positions of growth of the nanostructures.

According to a first aspect of the disclosure, there is provided a device comprising: a substrate comprising a III-V semiconductor having a crystalline surface; and a kagome lattice formed from atoms of an element with atomic number Z greater than or equal to 14, deposited on said surface of the semiconductor. According to a second aspect there is provided a fabrication method for forming a kagome lattice or other lattice structure such as a honeycomb or Moiré super lattice.

A method for manufacturing a nanowire includes providing a sacrificial substrate, providing a patterned mask layer on the sacrificial substrate, providing a nanowire on the sacrificial substrate through an opening in the patterned mask layer, and removing the sacrificial substrate. Because the sacrificial substrate is used for growing the nanowire and later removed, the material of the sacrificial substrate can be chosen to be lattice matched with the material of the nanowire without regard to the electrical properties thereof. Accordingly, a high-quality nanowire can be grown and operated without the degradation in performance normally experienced when using a lattice matched substrate.

Disclosed herein is the controlled epitaxy of Al.sub.xGa.sub.1-xAs, Al.sub.xIn.sub.1-xP, and Al.sub.xGa.sub.yIn.sub.1-x-yP by hydride vapor phase epitaxy (HVPE) through use of an external AlCl.sub.3 generator.

Epitaxial growth of materials, and related systems and articles, are generally described.